Open Access. Powered by Scholars. Published by Universities.®
Bioresource and Agricultural Engineering Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Bioresource and Agricultural Engineering
Copper Sorption Mechanisms On Smectites, Daniel G. Strawn, Noel E. Palmer, Luca J. Furnare, Carmen Goodell, James E. Amonette, Ravi K. Kukkadapu
Copper Sorption Mechanisms On Smectites, Daniel G. Strawn, Noel E. Palmer, Luca J. Furnare, Carmen Goodell, James E. Amonette, Ravi K. Kukkadapu
US Department of Energy Publications
Due to the importance of clay minerals in metal sorption, many studies have attempted to derive mechanistic models that describe adsorption processes. These models often include several different types of adsorption sites, including permanent charge sites and silanol and aluminol functional groups on the edges of clay minerals. To provide a basis for development of adsorption models it is critical that molecular-level studies be done to characterize sorption processes. In this study we conducted X-ray absorption fine structure (XAFS) and electron paramagnetic resonance (EPR) spectroscopic experiments on copper (II) sorbed on smectite clays using suspension pH and ionic strength as …
The Influence Of Uranyl Hydrolysis And Multiple Site-Binding Reactions On Adsorption Of U(Vi) To Montmorillonite, James P. Mckinley, John M. Zachara, Steven C. Smith, Gary D. Turner
The Influence Of Uranyl Hydrolysis And Multiple Site-Binding Reactions On Adsorption Of U(Vi) To Montmorillonite, James P. Mckinley, John M. Zachara, Steven C. Smith, Gary D. Turner
US Department of Energy Publications
Adsorption of uranyl to SWy- 1 montmorillonite was evaluated experimentally and results were modeled to identify likely surface complexation reactions responsible for removal ofuranyl from solution. Uranyl was contacted with SWy- 1 montmorillonite in a NaC104 electrolyte solution at three ionic strengths (I = 0.001, 0.01, 0.1), at pH 4 to 8.5, in a N2(g) atmosphere. At low ionic strength, adsorption decreased from 95% at pH 4 to 75% at pH 6.8. At higher ionic strength, adsorption increased with pH from initial values less than 75%; adsorption edges for all ionic strengths coalesced above a pH of 7. A …
Quinoline Sorption On Na-Montmorillonite: Contributions Of The Protonated And Neutral Species, Calvin C. Ainsworth, John M. Zachara, Ron L. Schmidt
Quinoline Sorption On Na-Montmorillonite: Contributions Of The Protonated And Neutral Species, Calvin C. Ainsworth, John M. Zachara, Ron L. Schmidt
US Department of Energy Publications
Dilute aqueous solutions of quinoline were contacted with Na-montmorillonite to elucidate the sorption process of the neutral and protonated species. Sorption occurs via a combination of ion exchange and molecular adsorption and yields S-type isotherms. Exchange between the quinolinium ion (QH+ and Na can be described by means of Vanselow selectivity coefficients and a thermodynamic exchange constant (Kex). Due to the apparent adsorption of the neutral species at high mole fractions (x) of the solid phase, the thermodynamic standard state was defined as 0.5 mole fraction. The selectivity at pH ~4.95 of the QH+ species over …