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Full-Text Articles in Biomedical Engineering and Bioengineering

Nanoenabled Microelectromechanical Sensor For Volatile Organic Chemical Detection, Chiara Zuniga, Matteo Rinaldi, Samuel M. Khamis, A. T. Johnson, Gianluca Piazza Jun 2009

Nanoenabled Microelectromechanical Sensor For Volatile Organic Chemical Detection, Chiara Zuniga, Matteo Rinaldi, Samuel M. Khamis, A. T. Johnson, Gianluca Piazza

Matteo Rinaldi

A nanoenabled gravimetric chemical sensor prototype based on the large scale integration of single-stranded DNA (ss-DNA) decorated single-walled carbon nanotubes (SWNTs) as nanofunctionalization layer for aluminum nitride contour-mode resonant microelectromechanical (MEM) gravimetric sensors has been demonstrated. The capability of two distinct single strands of DNA bound to SWNTs to enhance differently the adsorption of volatile organic compounds such as dinitroluene (simulant for explosive vapor) and dymethyl-methylphosphonate (simulant for nerve agent sarin) has been verified experimentally. Different levels of sensitivity (17.3 and 28 KHz µm^2/fg) due to separate frequencies of operation (287 and 450 MHz) on the same die have also …


Influence Of The Graphitisation Of Hollow Carbon Nanofibers On Their Functionalisation And Subsequent Filling With Metal Nanoparticles, Jean-Philippe Tessonnier, Dirk Rosenthal, Frank Girgsdies, Julien Amadou, Dominique Begin, Cuong Pham-Huu, Dang Sheng Su, Robert Schlogl Jan 2009

Influence Of The Graphitisation Of Hollow Carbon Nanofibers On Their Functionalisation And Subsequent Filling With Metal Nanoparticles, Jean-Philippe Tessonnier, Dirk Rosenthal, Frank Girgsdies, Julien Amadou, Dominique Begin, Cuong Pham-Huu, Dang Sheng Su, Robert Schlogl

Jean-Philippe Tessonnier

The functionalisation of carbon nanomaterials with the standard nitric acid treatment is greatly influenced by their graphitic character. The structural order directs the density as well as the nature of the created functional groups and, as a consequence, influences the efficiency of their filling with metal nanoparticles.


Amino-Functionalized Carbon Nanotubes As Solid Basic Catalysts For The Transesterification Of Triglycerides, Alberto Villa, Jean-Philippe Tessonnier, Olivier Majoulet, Dang Shen Su, Robert Schlogl Jan 2009

Amino-Functionalized Carbon Nanotubes As Solid Basic Catalysts For The Transesterification Of Triglycerides, Alberto Villa, Jean-Philippe Tessonnier, Olivier Majoulet, Dang Shen Su, Robert Schlogl

Jean-Philippe Tessonnier

Multiwalled carbon nanotubes grafted with various amino groups show high activity and stability when used as basic catalysts for the transesterification of triglycerides.


Selective Deposition Of Metal Nanoparticles Inside Or Outside Multiwalled Carbon Nanotubes, Jean-Philippe Tessonnier, Ovidiu Ersen, Gisela Weinberg, Cuong Pham-Huu, Dang Sheng Su, Robert Schlogl Jan 2009

Selective Deposition Of Metal Nanoparticles Inside Or Outside Multiwalled Carbon Nanotubes, Jean-Philippe Tessonnier, Ovidiu Ersen, Gisela Weinberg, Cuong Pham-Huu, Dang Sheng Su, Robert Schlogl

Jean-Philippe Tessonnier

A general method is described for the deposition of metal nanoparticles selectively either inside or outside of carbon nanotubes (CNTs). The method is based on the difference in the interface energies of organic and aqueous solutions with the CNT surface. Because of their lipophilic character, the organic solvent better wets the surface of the nanotubes compared to water and penetrates into the inner volume. The precise control of the volume of each phase allows filling the CNT with the organic phase and covering its outer surface with the aqueous one. Hence, metal nanoparticles can be put with high selectivity either …


Dna Assembler, An In Vivo Genetic Method For Rapid Construction Of Biochemical Pathways, Zengyi Shao, Hua Zhao, Huimin Zhao Jan 2009

Dna Assembler, An In Vivo Genetic Method For Rapid Construction Of Biochemical Pathways, Zengyi Shao, Hua Zhao, Huimin Zhao

Zengyi Shao

The assembly of large recombinant DNA encoding a whole biochemical pathway or genome represents a significant challenge. Here, we report a new method, DNA assembler, which allows the assembly of an entire biochemical pathway in a single step via in vivo homologous recombination in Saccharomyces cerevisiae. We show that DNA assembler can rapidly assemble a functional d-xylose utilization pathway (∼9 kb DNA consisting of three genes), a functional zeaxanthin biosynthesis pathway (∼11 kb DNA consisting of five genes) and a functional combined d-xylose utilization and zeaxanthin biosynthesis pathway (∼19 kb consisting of eight genes) with high efficiencies (70 - 100%) …