Engineering Commons^™

Measurements Of Methyl Radicals And Temperatures By Using Coherent Microwave Rayleigh Scattering From Resonance Enhanced Multiphoton Ionization, Yue Wu

Doctoral Dissertations

This thesis includes two main parts: (I) The CH₃[methyl radical] detection in methane/air flames and (II) the rotational temperature measurement of O₂[molecular oxygen] in a variety of environments by using coherent microwave Rayleigh scattering from resonance enhanced multiphoton ionization (Radar REMPI).

In first the part, from Chapter I to Chapter III, the methyl radical detection and quantitative measurements have been conducted in hydrocarbon flame with one-dimensional and two-dimensional spatial-resolved concentration distribution. Due to the proximity of the argon resonance state (4+1 REMPI by 332.5 nm) with the CH₃ state (2+1 REMPI by 333.6 nm), in …

Temperature And Alloying Effects On The Mechanical Properties Of Equiatomic Fcc Solid Solution Alloys, Zhenggang Wu

Doctoral Dissertations

Compared to decades-old theories of strengthening in dilute solid solutions, the mechanical behavior of concentrated solid solutions is relatively poorly understood. A special subset of these materials includes alloys in which the constituent elements are present in equal atomic proportions, including the high-entropy alloys of recent interest. A unique characteristic of equiatomic alloys is the absence of “solvent” and “solute” atoms, resulting in a breakdown of the textbook picture of dislocations moving through a solvent lattice and encountering discrete solute obstacles. To clarify the mechanical behavior of this interesting new class of materials, we investigate here a family of equiatomic …

Synthetic Turf Surface Temperature Reduction And Performance Characteristics As Affected By Calcined Clay Modified Infill, Eric Hall Reasor

Masters Theses

Synthetic turf research plots containing crumb rubber (CR) infill were established in Knoxville, TN in 2012 and 2013. Calcined clay (CC) was amended to CR in several ratios: a 50:50 (vol vol-1) blend; a 50:50 blend with a polymer coating on CC (50 CR:50 CCC); a 15 mm layer of CC under 15 mm of CR (CR over CC); and a 15 mm layer of CC over 15 mm of CR (CC over CR). A 100% CR and a 70:30 blend of CR to sand (70 CR:30 S) were included for comparison. Surface temperature was measured in the summer of …

Formulation And Experimental Verification Of Alternate Calibration Techniques Of The Temperature Dependent Response Of Phosphor Fluorescence, Kelsey Michele Winstead

Masters Theses

The overall goal of this work is to provide an alternative approach to the thermographic phosphor (TP) time constant calibration method for temperature recovery. In this work two techniques are proposed that retain the pulsed source input used in the standard TP time constant calibration approach but reinterpret the phosphor response taken a fixed distance such that the single-exponential decay assumption is removed. The methods do not require knowledge of key parameters prior to data processing, nor do they involve complicated numerical schemes that attempt to fit data in the low signal-to-noise region of the phosphor response. The approaches do …

Label-Free Mapping Of Near-Field Transport Properties Of Micro/Nano-Fluidic Phenomena Using Surface Plasmon Resonance (Spr) Reflectance Imaging, Iltai Kim

Doctoral Dissertations

My doctoral research has focused on the development of surface plasmon resonance (SPR) reflectance imaging technique to detect near-field transport properties such as concentration, temperature, and salinity in micro/nano fluidic phenomena in label-free, real-time, and full-field manner. A label-free visualization technique based on surface plasmon resonance (SPR) reflectance sensing is presented for real-time and full-field mapping of microscale concentration and temperature fields. The key idea is that the SPR reflectance sensitivity varies with the refractive index of the near-wall region of the test mixture fluid. The Fresnel equation, based on Kretschmann’s theory, correlates the SPR reflectance with the refractive index …