Engineering Commons^™

Parametric And Design Analysis On Thermoelectric Generators, Shouyuan Huang

Open Access Theses

In facing the limited energy source reserves and environmental problems, thermoelectric generators (TEGs) are one of the promising waste heat recovery systems. The modern TEGs for exhaust stream (e.g. from automobiles) can improve the fuel economy by around 5%, taking advantage of the recent developed thermoelectric (TE) materials.

In this work, we aimed at designing a TEG as an add-on module for a gas-phase heat exchanger with maximized power output, and without negative impact (e.g. maintaining a minimum heat dissipation rate from the hot side). We first developed a parametric optimization algorithm using response surface method (RSM) and genetic algorithm …

Development Of A Novel Polymer-Garnet Solid State Composite Electrolyte Incorporating Li-La-Zr-Bi-O And Polyethylene Oxide, Muhammed Ramazan Oduncu

Open Access Theses

Current lithium ion batteries are comprised of organic liquid electrolytes - a mixture of lithium salts and binary solvents such as ethylene carbonate (EC) and dimethyl carbonate (DMC). The main drawbacks of this liquid mixture related to safety are flammability of the organic solvents and chemical instability with the electrode materials. To date, various ceramic and polymer materials have been considered which overcome safety issues. However, a common problem of these solid state materials is that they are not able to provide high ionic conductivity at ambient temperatures. Garnet-type cubic Li7La 3Zr2O12 ceramic material has attracted much interest because of …

Overcoming Fundamental Barriers In Photovoltaic And Terahertz Generation, Chao Zhou

Open Access Theses

Several fundamental barriers limit the performance of opto-electronic conversion processes below 100%. Two specific examples of current technological interest include photovoltaic conversion of sunlight into electricity (i.e., solar cells), and terahertz generation from optical sources. In particular, solar cells are limited not only by the Carnot limit associated with the second law (approximately 86% at room temperature), but also by radiative recombination, non-reciprocity, carrier thermalization, and sub-bandgap losses. In the case of terahertz generation, the typical process of difference frequency generation relies on two input optical waves with only a small difference between them to generate the desired output; however, …

Waste Heat Recovery Options In A Large Gas-Turbine Combined Power Plant, Ularee Upathumchard

Open Access Theses

This study focuses on power plant heat loss and how to utilize the waste heat in energy recovery systems in order to increase the overall power plant efficiency. The case study of this research is a 700-MW natural gas combined cycle power plant, located in a suburban area of Thailand. An analysis of the heat loss of the combustion process, power generation process, lubrication system, and cooling system has been conducted to evaluate waste heat recovery options. The design of the waste heat recovery options depends to the amount of heat loss from each system and its temperature. Feasible waste …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Design And Use Of An Adjustable Clearance Flailing Knife Biomass Shredder To Mechanically Increase Particle Surface Area, Shawn Gregory Ehlers

Open Access Theses

A flailing knife shredder was designed and tested as an alternative to a hammermill for processing biomass. The machine was comprised of two cylinders with four rungs, each with five free-swinging blades. Each of the two cylinders had adjustable clearance hoods and variable speed drives. Energy usage, output characteristics and device capacities were compared with corn stover processed at moisture contents (MC) of 10%, 35% and 50% wet basis (WB). The hammermill produced a more uniform particle size distribution in comparison to the shredder. Accessibility, indicated by conductivity index, to plant constituents, revealed that the method of treatment was not-significant …