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Emerging contaminants

Articles 1 - 11 of 11

Full-Text Articles in Engineering

Wetland Treatment Systems For Municipal Wastewater At A Bourbon Distillery And Potential Value Of Incorporating Stillage For Water Treatment Enhancement, Katherine J. Ristola Jan 2024

Wetland Treatment Systems For Municipal Wastewater At A Bourbon Distillery And Potential Value Of Incorporating Stillage For Water Treatment Enhancement, Katherine J. Ristola

Theses and Dissertations--Biosystems and Agricultural Engineering

The use of constructed treatment wetlands, as a secondary treatment method for wastewater effluent from package treatment plants and distillery stillage has potential to be an innovative, sustainable method for improving water quality in the Central Kentucky region. However, the use of constructed wetlands to treat stillage and wastewater treatment plant effluent has been limited. Therefore, the objectives of this study were to: 1) quantify constructed wetland removal as a secondary treatment method for distillery’s wastewater; 2) explore the potential to utilize constructed treatment wetlands to remove nutrients from bourbon stillage; and 3) optimize treatment design to meet wastewater effluent …

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Fate And Transport Of Nanopesticides In Agricultural Field Plots In Central Kentucky, William D. Rud Jan 2023

Fate And Transport Of Nanopesticides In Agricultural Field Plots In Central Kentucky, William D. Rud

Theses and Dissertations--Biosystems and Agricultural Engineering

Due to a growing world population, pesticide applications are necessary part to increasing agricultural production on the same arable land, but this has created environmental contamination, human toxicity, and endangerment to non-target species (i.e, honeybees, monarch butterflies) from bulk pesticide application. Nanoengineered particles or ENP are a potential solution with increased efficiency, longer duration, and enhanced stability of pesticides due to their unique formulations at smaller sizes. However, the potential long-term impact to agroecosystems is still unknown. Therefore, the goal of this project was to evaluate the fate, transport, impact, and persistence of two commercially available nanopesticides (copper hydroxide and …

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Physical, Chemical, And Mineralogical Controls On Retardation Of Anatoxin-A Migration By Sorption To Natural Soils With Implications For Groundwater Protection, Justin L. Hobart, Andrew M. O’Reilly, Jennifer N. Gifford Sep 2022

Physical, Chemical, And Mineralogical Controls On Retardation Of Anatoxin-A Migration By Sorption To Natural Soils With Implications For Groundwater Protection, Justin L. Hobart, Andrew M. O’Reilly, Jennifer N. Gifford

Faculty and Student Publications

Increasing prevalence of cyanotoxins in surface water bodies worldwide threatens groundwater quality when contaminated water recharges an aquifer through natural or artificial means. The subsurface fate of anatoxin-a (ATX) is not well studied. Laboratory batch experiments were performed to expand the current knowledge of ATX sorption affinities to geologic media, with a focus on natural soil (Vertisol, Ultisol, Alfisol, and Inceptisol) and physical, chemical, and mineralogical characteristics. For a range of aqueous ATX concentrations (0.3–14 μg/L), linear, Freundlich, and Langmuir isotherms fit observed data well (r2 = 0.92–1.00, RMSE = 0.4–6.3 μg/kg). Distribution coefficient (Kd) and retardation factor (Rf) values …

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Degradation Of Emerging Contaminants By Advanced Oxidation Using Multi-Walled Carbon Nanotubes And Continuous Ozone Injection, Emily N. Miller Jun 2019

Degradation Of Emerging Contaminants By Advanced Oxidation Using Multi-Walled Carbon Nanotubes And Continuous Ozone Injection, Emily N. Miller

Master's Theses

With a growing population and continuous accumulation of pollutants, water resources worldwide are quickly being depleted. Drastic improvements need to be made in both water conservation and treatment. Advanced oxidation processes (AOPs) have been developed to go above and beyond the capabilities of traditional wastewater treatment facilities to eliminate emerging contaminants from our water systems. AOPs increase the generation of hydroxyl radicals (•OH) in oxidation reactions, which are less selective and more reactive than other oxidants, such as ozone, so they are more effective at degrading persistent compounds. This study explored an AOP that utilizes ozonated multi-walled carbon nanotubes (MWCNTs) …

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Adsorption Of Organic Micropollutants Onto Biochar: A Review Of Relevant Kinetics, Mechanisms And Equilibrium, Yiran Tong, Patrick J. Mcnamara, Brooke K. Mayer Mar 2019

Adsorption Of Organic Micropollutants Onto Biochar: A Review Of Relevant Kinetics, Mechanisms And Equilibrium, Yiran Tong, Patrick J. Mcnamara, Brooke K. Mayer

Civil and Environmental Engineering Faculty Research and Publications

As an alternative to activated carbon, biochar has been considered for removal of organic micropollutants from water and wastewater via adsorption. This review elaborates on the fundamental basis of adsorption kinetics, mechanisms, and equilibrium with respect to biochar-based adsorption of micropollutants. The objectives include: 1) linking biochar surface properties with adsorption abilities, 2) categorizing the kinetics of adsorption of aqueous-phase organic compounds onto biochar, 3) categorizing the molecular-scale interactions between organic micropollutants and biochar, and 4) reviewing existing quantitative methods for characterizing adsorption equilibrium of organic micropollutants from water onto an adsorbent surface. To fulfill these goals, the relationships among …

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Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray Jan 2019

Irrigation Water Quality—A Contemporary Perspective, Arindam Malakar, Daniel D. Snow, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

In the race to enhance agricultural productivity, irrigation will become more dependent on poorly characterized and virtually unmonitored sources of water. Increased use of irrigation water has led to impaired water and soil quality in many areas. Historically, soil salinization and reduced crop productivity have been the primary focus of irrigation water quality. Recently, there is increasing evidence for the occurrence of geogenic contaminants in water. The appearance of trace elements and an increase in the use of wastewater has highlighted the vulnerability and complexities of the composition of irrigation water and its role in ensuring proper crop growth, and …

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Spread Of Emerging Contaminants In Water Distribution Systems, Danielle Pilarski Jan 2019

Spread Of Emerging Contaminants In Water Distribution Systems, Danielle Pilarski

Dissertations, Master's Theses and Master's Reports

Emerging contaminants are a growing concern to humans and the environment. Studies have shown these contaminants are present in the environment through continuous release into surface waters from wastewater treatment effluent, manufacturing processes, and agricultural use. The effects of these contaminants have been observed in ecological studies, but they have not yet been well studied for long term exposure in humans. These emerging contaminants have also not been well studied to determine the rates at which they decay or how they move through distribution systems. This study aims to determine the importance of decay rate on concentration throughout a distribution …

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Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick Jul 2013

Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick

Civil and Environmental Engineering Faculty Research and Publications

Triclosan is an antimicrobial agent that is discharged to soils with land-applied wastewater biosolids, is persistent under anaerobic conditions, and yet its impact on anaerobic microbial communities in soils is largely unknown. We hypothesized that triclosan enriches for Dehalococcoides-like Chloroflexi because these bacteria respire organochlorides and are likely less sensitive, relative to other bacteria, to the antimicrobial effects of triclosan. Triplicate anaerobic soil microcosms were seeded with agricultural soil, which was not previously exposed to triclosan, and were amended with 1 mg kg−1 of triclosan. Triplicate control microcosms did not receive triclosan, and the experiment was run for …

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Evaluating Chemical Toxicity: A Novel Behavioral Assay Using Daphnia, Maya A. Zein Jan 2013

Evaluating Chemical Toxicity: A Novel Behavioral Assay Using Daphnia, Maya A. Zein

Wayne State University Dissertations

Pharmaceuticals, and personal care products (PPCPs), and other emerging contaminants, such as pesticides, are increasingly being detected in the environment. Important sources of these contaminants are waste water treatment plants and agriculture. Many of these contaminants are biologically active at low concentrations, and may impair physiological processes in exposed organisms, alter reproductive, endocrine or immune system function, and ultimately affect fitness and survival. These chemicals are often found in the environment as complex mixtures, and this complicates their evaluation of their toxicity. There is a need for high-throughput assays to rapidly assess the toxicity of these emerging contaminants. A behavioral …

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Mobilization Of Endocrine‐Disrupting Chemicals And Estrogenic Activity In Simulated Rainfall Runoff From Land‐Applied Biosolids, Ben D. Giudice, Thomas M. Young Jul 2011

Mobilization Of Endocrine‐Disrupting Chemicals And Estrogenic Activity In Simulated Rainfall Runoff From Land‐Applied Biosolids, Ben D. Giudice, Thomas M. Young

Faculty Publications - Biomedical, Mechanical, and Civil Engineering

Municipal biosolids are commonly applied to land as soil amendment or fertilizer as a form of beneficial reuse of what could otherwise be viewed as waste. Balanced against this benefit are potential risks to groundwater and surface water quality from constituents that may be mobilized during storm events. The objective of the present study was to characterize the mobilization of selected endocrinedisrupting compounds, heavy metals, and total estrogenic activity in rainfall runoff from land-applied biosolids. Rainfall simulations were conducted on soil plots amended with biosolids. Surface runoff and leachate was collected and analyzed for the endocrinedisrupting compounds bisphenol A, 17a-ethynylestradiol, …

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The Antimicrobial Triclocarban Stimulates Embryo Production In The Freshwater Mudsnail Potamopyrgus Antipodarum, Ben D. Giudice, Thomas M. Young Dec 2009

The Antimicrobial Triclocarban Stimulates Embryo Production In The Freshwater Mudsnail Potamopyrgus Antipodarum, Ben D. Giudice, Thomas M. Young

Faculty Publications - Biomedical, Mechanical, and Civil Engineering

Recent research has indicated that the antimicrobial chemical triclocarban (TCC) represents a new type of endocrine disruptor, amplifying the transcriptional activity of steroid hormones and their receptors while itself exhibiting little affinity for these receptors. The effects of TCC were studied in the freshwater mudsnail Potamopyrgus antipodarum. Specimens were exposed to concentrations ranging from 0.05 to 10.5 mg/L dissolved TCC and were removed and dissected, and embryos contained within the brood pouch were counted and classified as shelled or unshelled after two and four weeks of exposure. After four weeks, environmentally relevant TCC concentrations of 1.6 to 10.5 mg/L resulted …

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