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Articles 61 - 90 of 259

Full-Text Articles in Engineering

Numerical Modeling Of Size Effect In Micro Hydromechanical Deep Drawing, Hideki Sato, Ken-Ichi Manabe, Dongbin Wei, Zhengyi Jiang Jan 2014

Numerical Modeling Of Size Effect In Micro Hydromechanical Deep Drawing, Hideki Sato, Ken-Ichi Manabe, Dongbin Wei, Zhengyi Jiang

Faculty of Engineering and Information Sciences - Papers: Part A

A modeling of tribological size effects in micro deep drawing (MDD) and micro hydromechanical deep drawing (MHDD) is a main focus in this study. The inner and outer pockets in which the different friction coefficients can be applied at different lubrication conditions are considered on the blank surface. The ratio of the area of outer pockets to inner pockets is changed with the decrease in the size. The low friction coefficient at the outer pockets is assumed in MHDD by considering the lubrication effect of fluid medium. The numerical analysis is performed under six lubrication conditions. The analytical results of …


Effect Of Austenite Deformation Temperature On Nb Clustering And Precipitation In Microalloyed Steel, E V Pereloma, A G Kostryzhev, A Alshahrani, C Zhu, J M. Cairney, C R. Killmore, S P. Ringer Jan 2014

Effect Of Austenite Deformation Temperature On Nb Clustering And Precipitation In Microalloyed Steel, E V Pereloma, A G Kostryzhev, A Alshahrani, C Zhu, J M. Cairney, C R. Killmore, S P. Ringer

Faculty of Engineering and Information Sciences - Papers: Part A

The effect of thermomechanical processing conditions on Nb clustering and precipitation in both austenite and ferrite in a Nb-Ti microalloyed steel was studied using electron microscopy and atom probe tomography. A decrease in the deformation temperature increased the Nb-rich precipitation in austenite and decreased the extent of precipitation in ferrite. Microstructural mechanisms that explain this variation are discussed. 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.


Effect Of Holding Temperature And Time On Ferrite Formation In Dual Phase Steel Produced By Strip Casting, Zhiping Xiong, Andrii Kostryzhev, Nicole Stanford, Elena V. Pereloma Jan 2014

Effect Of Holding Temperature And Time On Ferrite Formation In Dual Phase Steel Produced By Strip Casting, Zhiping Xiong, Andrii Kostryzhev, Nicole Stanford, Elena V. Pereloma

Faculty of Engineering and Information Sciences - Papers: Part A

Conventional dual phase (DP) steel (0.08C-0.81Si-1.47Mn-0.03Al, wt. %) was manufactured by the laboratory simulation of strip casting. The effect of holding temperature and time on microstructure evolution was studied using a quench-deformation dilatometer. Microstructures were observed using optical and scanning electron microscopy. The results showed that the nose temperature of ferrite phase field is around 650 °C. The kinetics of ferrite formation is fast within the first 100 s of holding at this temperature, and then formation of ferrite continues at a slower rate until it reaches the fraction corresponding to that defined by the lever rule. 70~80 % ferrite …


Enhancement Of Trace Organic Contaminant Degradation By Crude Enzyme Extract From Trametes Versicolor Culture: Effect Of Mediator Type And Concentration, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, Frederic Leusch, Felicity Roddick, S Faraj Magram, William Price, Long Nghiem Jan 2014

Enhancement Of Trace Organic Contaminant Degradation By Crude Enzyme Extract From Trametes Versicolor Culture: Effect Of Mediator Type And Concentration, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, Frederic Leusch, Felicity Roddick, S Faraj Magram, William Price, Long Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

The performance of two redox mediating compounds, namely 1-hydroxybenzotriazole (HBT) and syringaldehyde (SA), was compared in terms of enhancement of enzymatic degradation of a diverse set of 14 phenolic and 16 non-phenolic trace organic contaminants (TrOCs) and the toxicity of the treated media. Extracellular enzyme extract (predominantly containing laccase) from Trametes versicolor culture achieved efficient degradation (70-95%) of nine phenolic and one non-phenolic TrOCs. Mediator dosing extended the spectrum of efficiently degraded TrOCs to 13 phenolic and three non-phenolic compounds, with moderate improvements in removal of a few other non-phenolic compounds. TrOC removal efficiency improved significantly as the HBT dose …


The Effect Of Ageing On Microstructure And Mechanical Properties Of Powder Ti-5al-5mo-5v-1cr-1fe Alloy, Mansur Ahmed, Dmytro Savvakin, Orest M. Ivasishin, E V. Pereloma Jan 2014

The Effect Of Ageing On Microstructure And Mechanical Properties Of Powder Ti-5al-5mo-5v-1cr-1fe Alloy, Mansur Ahmed, Dmytro Savvakin, Orest M. Ivasishin, E V. Pereloma

Faculty of Engineering and Information Sciences - Papers: Part A

The thermo-mechanically processed powder Ti-5Al-5V-5Mo-1Cr-1Fe alloy was aged at 9.23 K for 1-8 h in order to investigate the effect of ageing time on the microstructure-mechanical properties relationships. The microstructures of the alloy after ageing cosist of the both primary and secondary alpha phases with retained B matrix phase. The shift of B peaks in X-ray pattern with ageing time indicates an increase in lattice parameter distorition due to diffusion into the retained B phase of more B stabilisers with smaller atomic radius compared to the elemental Ti. The tensile test results indicate that the sample aged for 1 h …


The Effect Of Processing Parameters On The Microstructure And Mechanical Properties Of Low-Si Transformation-Induced Plasticity Steels, Fayez Alharbi, Azdiar A. Gazder, Andrii Kostryzhev, Bruno C. De Cooman, Elena Pereloma Jan 2014

The Effect Of Processing Parameters On The Microstructure And Mechanical Properties Of Low-Si Transformation-Induced Plasticity Steels, Fayez Alharbi, Azdiar A. Gazder, Andrii Kostryzhev, Bruno C. De Cooman, Elena Pereloma

Faculty of Engineering and Information Sciences - Papers: Part A

A base low Si, high-A1 transformation-induced plasticity (TRIP) steel and one with 0.03Nb and 0.002Ti (wt percent) additions were subjected to thermo-mechanical processing (TMP) and galvanising simulations. T


Magnetic Transitions And The Magnetocaloric Effect In The Pr 1-Xyxmn2ge2 System, Jianli Wang, S J. Campbell, M F. Md Din, S J. Kennedy, M Hofmann Jan 2014

Magnetic Transitions And The Magnetocaloric Effect In The Pr 1-Xyxmn2ge2 System, Jianli Wang, S J. Campbell, M F. Md Din, S J. Kennedy, M Hofmann

Australian Institute for Innovative Materials - Papers

Layered rare earth compounds in the RMn2X2 series (R = rare-earth; X = Ge, Si) are of interest for potential cooling applications at lower temperatures as they enable the structural and magnetic behavior to be controlled via substitution of R, Mn, and X atoms on the 2a, 4d, and 4e sites respectively. We continue investigations of the Pr1−xYxMn2Ge2 magnetic phase diagram as functions of both composition and Mn-Mn spacing using X-ray and neutron diffraction, magnetization and differential scanning calorimetry measurements. Pr1−xYxMn2Ge2 exhibits an extended region of re-entrant ferromagnetism around x ∼ 0.5 with re-entrant ferromagnetism at inline image for Pr0.5Y0.5Mn2Ge2. …


Electronic Coupling And Catalytic Effect On H2 Evolution Of Mos2/Graphene Nanocatalyst, Ting Liao, Ziqi Sun, Chenghua Sun, S X. Dou, Debra J. Searles Jan 2014

Electronic Coupling And Catalytic Effect On H2 Evolution Of Mos2/Graphene Nanocatalyst, Ting Liao, Ziqi Sun, Chenghua Sun, S X. Dou, Debra J. Searles

Australian Institute for Innovative Materials - Papers

Inorganic nano-graphene hybrid materials that are strongly coupled via chemical bonding usually present superior electrochemical performance. However, how the chemical bond forms and the synergistic catalytic mechanism remain fundamental questions. In this study, the chemical bonding of the MoS 2 nanolayer supported on vacancy mediated graphene and the hydrogen evolution reaction of this nanocatalyst system were investigated. An obvious reduction of the metallic state of the MoS 2 nanolayer is noticed as electrons are transferred to form a strong contact with the reduced graphene support. The missing metallic state associated with the unsaturated atoms at the peripheral sites in turn …


Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou Jan 2014

Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of the NdMn1.9Ti0.1Si2 compund have been studied by high-intensity x-ray and high-resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range of 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9Ti0.1Si2 are indicated as TC ~ 22 K and TN ~ 374 K respectively. The first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc] around TC is found in layered NdMn1.9Ti0.1Si2 and is …


The Effects Of Low-Level Ethanol Blends In 4-Stroke Small Non-Road Engines, Chris Reek Jan 2014

The Effects Of Low-Level Ethanol Blends In 4-Stroke Small Non-Road Engines, Chris Reek

All Graduate Theses, Dissertations, and Other Capstone Projects

Small Non-Road Engines (SNRE's) abound in numbers and are used daily by consumers and businesses alike. Considering the atmosphere of change looming in the air regarding alternative fuels, this particular engine classification will also be affected by any change in standardization of fuels. This body of research attempts to address possible ways SNRE's can change their operational characteristics after being fueled by specific yet differing fuels. These characteristics will be contrasted against blends of ethanol with gasoline, from 0% ethanol to 20% ethanol, run on test engines to determine patterns, if any, of these characteristics. Topics include: materials compatibility, engine …


The Synergistic Effect Between Wo3 And G-C3n4 Towards Efficient Visible-Light-Driven Photocatalytic Performance, Imran Aslam, Chuanbao Cao, M Tanveer, Waheed S. Khan, Muhammad Nawaz Tahir, Muhammad Abid, Faryal Idrees, Faheem K. Butt, Zulfiqar Ali, Nasir Mahmood Jan 2014

The Synergistic Effect Between Wo3 And G-C3n4 Towards Efficient Visible-Light-Driven Photocatalytic Performance, Imran Aslam, Chuanbao Cao, M Tanveer, Waheed S. Khan, Muhammad Nawaz Tahir, Muhammad Abid, Faryal Idrees, Faheem K. Butt, Zulfiqar Ali, Nasir Mahmood

Australian Institute for Innovative Materials - Papers

We have developed a facile, scaled up, efficient and morphology-based novel WO3-g-C3N4 photocatalyst with different mass ratios of WO3 and g-C3N4. It was used for the photodegradation of rhodamine B (RhB) under visible light irradiation and it showed excellent enhanced photocatalytic efficiency as compared to pure g-C3N4 and WO3. The apparent performance of the composite/hybrid was 3.65 times greater than pure WO3 and 3.72 times greater than pure g-C3N4 respectively, and it was also found to be much higher than the previously reported ones. Furthermore, the optical properties of composite samples were evaluated. The bandgap of composite samples lies in …


Electrostrictive Effect In Ferroelectrics: An Alternative Approach To Improve Piezoelectricity, Fei Li, Li Jin, Zhuo Xu, Shujun Zhang Jan 2014

Electrostrictive Effect In Ferroelectrics: An Alternative Approach To Improve Piezoelectricity, Fei Li, Li Jin, Zhuo Xu, Shujun Zhang

Australian Institute for Innovative Materials - Papers

Electrostriction plays an important role in the electromechanical behavior of ferroelectrics and describes a phenomenon in dielectrics where the strain varies proportional to the square of the electric field/polarization. Perovskite ferroelectrics demonstrating high piezoelectric performance, including BaTiO3, Pb(Zr1-xTix)O3, and relaxor-PbTiO3 materials, have been widely used in various electromechanical devices. To improve the piezoelectric activity of these materials, efforts have been focused on the ferroelectric phase transition regions, including shift the composition to the morphotropic phase boundary or shift polymorphic phase transition to room temperature. However, there is not much room left to further enhance the piezoelectric response in perovskite solid …


Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou Jan 2014

Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou

Australian Institute for Innovative Materials - Papers

Structural and magnetic properties of NdMn2−x Cu xSi2 compounds (x = 0-1.0) have been investigated by high intensity x-ray and resolution neutron diffraction (3-450 K), specific heat, dc magnetization, and differential scanning calorimetry measurements. Substitution of Cu for Mn leads to an increase in the lattice parameter a but a decrease in c at room temperature. Two magnetic phase transitions have been found for NdMn2−x Cu xSi2 compounds with TN for the antiferromagnetic ordering of Mn-sublatttice and TC for the Nd-sublattice ferromagnetic ordering, respectively. TC increases significantly with increasing Cu content from 36 K at x = 0 to 100 …


Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou Jan 2014

Magnetic Properties And Magnetocaloric Effect In Layered Ndmn 1.9v0.1si2, M F. Md Din, Jianli Wang, R Zeng, Shane Kennedy, S J. Campbell, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of the compounds NdMn2-xVxSi2 have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9V0.1Si2 are been indicate at TC ~ 24 K and TN ~ 376 K respectively. The giant magnetocaloric effect (GMCE) around TC is found in layered NdMn1.9V0.1Si2 associated with first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc]. This behaviorhas been confirmed as contribution of the magnetostructural coupling by using neutron powder diffraction. The magnetic entropy …


Magneto-Radiotherapy: Effect Of Magnetic Field On Dose Distribution And Rbe, Heidi Nettelbeck, Anatoly Rosenfeld, George Takacs, Michael Lerch Nov 2013

Magneto-Radiotherapy: Effect Of Magnetic Field On Dose Distribution And Rbe, Heidi Nettelbeck, Anatoly Rosenfeld, George Takacs, Michael Lerch

Michael L.F. Lerch

Magneto-radiotherapy is the application of magnetic fields during radiotherapy procedures. It aims to improve the quality of cancer treatment by altering the dose deposition of charged particles in the tissue volume being targeted. Our research has focused on applying the concept of magneto-radiotherapy to conventional linac treatment and MRT (Microbeam Radiation Therapy) oncology modalities.


Verification Of The Plan Dosimetry For High Dose Rate Brachytherapy Using Metal-Oxide-Semiconductor Field Effect Transistor Detectors, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Jie Lu, Michael Lerch, Dean Cutajar, Anatoly Rosenfeld Nov 2013

Verification Of The Plan Dosimetry For High Dose Rate Brachytherapy Using Metal-Oxide-Semiconductor Field Effect Transistor Detectors, Zhen-Yu Qi, Xiao-Wu Deng, Shao-Min Huang, Jie Lu, Michael Lerch, Dean Cutajar, Anatoly Rosenfeld

Michael L.F. Lerch

The feasibility of a recently designed metal–oxide–semiconductor field effect transistor (MOSFET) dosimetry system for dose verification of high dose rate (HDR) brachytherapy treatment planning was investigated. MOSFET detectors were calibrated with a 0.6 cm3 NE-2571 Farmer-type ionization chamber in water. Key characteristics of the MOSFET detectors, such as the energy dependence, that will affect phantom measurements with HDR 192Ir sources were measured. The MOSFET detector was then applied to verify the dosimetric accuracy of HDR brachytherapy treatments in a custom-made water phantom. Three MOSFET detectors were calibrated independently, with the calibration factors ranging from 0.187 to 0.215 cGy∕mV. A distance …


Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou Oct 2013

Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect …


Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou Oct 2013

Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou

Josip Horvat

The effect of processing temperature on structural and superconducting properties of 10 wt.% sugar- and 10 wt.% PCS-doped MgB2 wires is systematically investigated. It is demonstrated that these dopants significantly enhance the electromagnetic performance of Fe-clad MgB2 superconductor and increase its potential for practical application. The enhancement of in-field critical current density (Jc(Ba)) and upper critical field (Bc2) is due to formation of a large amount of lattice defects caused by impurities and C substitution into the MgB2 crystal lattice. High temperature sintering of sugar-doped sample results in as high Bc2 value as 37 T (at 5 K), which correlates …


Effect Of Ti And N Concentrations On Microstructure And Mechanical Properties Of Microalloyed High Strength Line Pipe Steel Welds, Leigh Fletcher, Zhixiong Zhu, Marimuthu Murugananth, Lei Zheng, Mingzhuo Bai, Huijun Li, F Barbaro Jul 2013

Effect Of Ti And N Concentrations On Microstructure And Mechanical Properties Of Microalloyed High Strength Line Pipe Steel Welds, Leigh Fletcher, Zhixiong Zhu, Marimuthu Murugananth, Lei Zheng, Mingzhuo Bai, Huijun Li, F Barbaro

Muruganant Marimuthu

A selection of nine heats of line pipe steel from the same project with different Ti and N content were used to evaluate the effects of Ti/N ratio on weld zone microstructure, hardness and prior austenite grain size (PAGS) in the coarse grained heat-affected zone (CGHAZ). It was shown that the microstructure of the base metal (BM) mainly consisted of fine grained polygonal ferrite with fine islands of pearlite. The weld metal (WM) microstructure was predominantly acicular ferrite with a small volume fraction of pro-eutectoid ferrite. The CGHAZ consisted of bainitic ferrite and islands of martensite-austenite. The inside region of …


Re-Entrant Ferromagnet Prmn2ge0.8si1.2: Magnetocaloric Effect, S X. Dou, Jianli Wang, Rong Zeng, Chung-Kiak Poh, Stewart J. Campbell, S J. Kennedy Jul 2013

Re-Entrant Ferromagnet Prmn2ge0.8si1.2: Magnetocaloric Effect, S X. Dou, Jianli Wang, Rong Zeng, Chung-Kiak Poh, Stewart J. Campbell, S J. Kennedy

Jianli Wang

The structural and magnetic properties of the re-entrant ferromagnet PrMn2Ge0.8Si1.2 have been investigated by various experimental methods. Similar to the canonical re-entrant ferromagnet SmMn2Ge2, multiple magnetic phase transitions have been detected in PrMn2Ge0.8Si1.2 over the temperature range from 10 to 550 K with re-entrant ferromagnetism occurring around ∼ 54 K. The magnetocaloric effect has been measured in terms of the isothermal magnetocaloric entropy change and found to be positive at the re-entrant ferromagnetic transition with a maximum value of around 1.9 J/kg K at 58 K for a magnetic field change of 0–3 T. On the other hand, the entropy …


Abnormal Magnetic Behaviors And Large Magnetocaloric Effect In Mnps3 Nanoparticles, R Zeng, S Q. Wang, G D. Du, Jianli Wang, J C. Debnath, Precious Shamba, Z Y. Fang, S. X. Dou Jul 2013

Abnormal Magnetic Behaviors And Large Magnetocaloric Effect In Mnps3 Nanoparticles, R Zeng, S Q. Wang, G D. Du, Jianli Wang, J C. Debnath, Precious Shamba, Z Y. Fang, S. X. Dou

Jianli Wang

A nanostructured honeycomb lattice consisting of MnPS3 nanoparticles synthesized via the ion-exchange technique was found to have restacked molecular layers stabilized by H2O insertion between the layers. Susceptibility (χ) and heat capacity measurements showed the absence of long range magnetic ordering, at least down to 2 K. However, the χ data showed that the system possesses a high effective Curie temperature, suggesting that the system is in a high spin lattice disordered state. Evaluation of the magnetocaloric effect indicates that the system has a large reversible magnetic-entropy change (−ΔSm) of 6.8 and 12.8 J/kg K and an adiabatic temperature change …


Magnetocaloric Effect In Layered Ndmn2ge0.4si1.6, Jianli Wang, S.J Campbell, J.M Cadogan, A J Studer, Rong Zeng, S. X. Dou Jul 2013

Magnetocaloric Effect In Layered Ndmn2ge0.4si1.6, Jianli Wang, S.J Campbell, J.M Cadogan, A J Studer, Rong Zeng, S. X. Dou

Jianli Wang

A giant magnetocaloric effect has been observed in NdMn2Ge0.4Si1.6 associated with the first-order magnetic phase transition from antiferromagnetism to ferromagnetism around TC = 36 K. The magnetic entropy change –ΔSM and adiabatic temperature change ΔTad have been determined from magnetization and specific heat measurements (B = 0–5 T) with –ΔSM calculated by the Maxwell relation and Clausius–Clapeyron method. The values –ΔSMmax = 12.3 J kg−1 K−1 and refrigerant capacity ∼ 95 J/kg for ΔB = 0–2 T as derived from the Maxwell relation, together with the small hysteresis (thermal 2Ge0.4Si1.6 for refrigeration applications.


Magnetovolume Effect And Magnetic Properties Of Dy2fe17-Xmnx, Jianli Wang, Stewart J. Campbell, O Tegus, C Marquina, M R. Ibarra Jul 2013

Magnetovolume Effect And Magnetic Properties Of Dy2fe17-Xmnx, Jianli Wang, Stewart J. Campbell, O Tegus, C Marquina, M R. Ibarra

Jianli Wang

The structural and magnetic properties of Dy2Fe17−xMnx (x=0–5) compounds have been investigated using x-ray diffraction, linear thermal expansion, magnetization measurements, and 57Fe Mössbauer spectroscopy. Compared with Dy2Co17−xMnx compounds for which a linear increase of the unit-cell volume V with increasing Mn fraction is found, the compositional dependence of the lattice parameters of Dy2Fe17−xMnx first exhibits a slight maximum around x=0.5 before increasing monotonically with further increase in x; this behavior can be ascribed to a spontaneous magnetostriction as confirmed by linear-thermal-expansion measurements. The Curie temperature TC remains essentially unchanged for Mn contents up to x=1 [TC=370(4) K for x=0.0, TC=373(4) …


Magnetic Properties And Magnetocaloric Effect Of (Mn1-Xnix)3sn2(X=0-0.5) Compounds, Rong Zeng, Lin Lu, Jung Ho Kim, Dongqi Shi, Hua-Kun Liu, S. X. Dou, Jianli Wang, Stewart J. Campbell, Zhaoxiang Wang, Y Li, Wenxian Li, M Y. Zhu, Chuanqi Feng Jul 2013

Magnetic Properties And Magnetocaloric Effect Of (Mn1-Xnix)3sn2(X=0-0.5) Compounds, Rong Zeng, Lin Lu, Jung Ho Kim, Dongqi Shi, Hua-Kun Liu, S. X. Dou, Jianli Wang, Stewart J. Campbell, Zhaoxiang Wang, Y Li, Wenxian Li, M Y. Zhu, Chuanqi Feng

Jianli Wang

The effects of Ni substitution on the magnetic properties and magnetocaloric effect (MCE) of (Mn1−xNix)3Sn2 compounds (x = 0–0.5) have been investigated by x-ray diffraction and magnetization measurements. It was found that Ni substitution decreases the crystal cell volume and the magnetic transition temperatures compared with pure Mn3Sn2. The MCE for all samples has been calculated from the magnetization data in terms of the isothermal magnetic entropy change ΔSM. The maximum values of ΔSMmax at the magnetic phase transition temperatures resulting from a change in magnetic field of ΔH = 5 T were found to be 28.2 mJ/cm3 K for …


The Magnetocaloric Effect And Critical Behaviour Of The Mn0.94ti0.06coge Alloy, P Shamba, Jianli Wang, J C. Debnath, S J. Kennedy, Rong Zeng, M F Md Din, F Hong, Z X. Cheng, A J. Studer, S X. Dou Jul 2013

The Magnetocaloric Effect And Critical Behaviour Of The Mn0.94ti0.06coge Alloy, P Shamba, Jianli Wang, J C. Debnath, S J. Kennedy, Rong Zeng, M F Md Din, F Hong, Z X. Cheng, A J. Studer, S X. Dou

Jianli Wang

Structural, magnetic and magnetocaloric properties of the Mn0.94Ti0.06CoGe alloy have been investigated using x-ray diffraction, DC magnetization and neutron diffraction measurements. Two phase transitions have been detected, at T-str = 235 K and T-C = 270 K. A giant magnetocaloric effect has been obtained at around Tstr associated with a structural phase transition from the low temperature orthorhombic TiNiSi-type structure to the high temperature hexagonal Ni2In-type structure, which is confirmed by neutron study. In the vicinity of the structural transition, at T-str, the magnetic entropy change, -Delta S-M reached a maximum value of 14.8 J kg(-1) K-1 under a magnetic …


Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou Jul 2013

Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou

Jianli Wang

YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …


Large Magnetocaloric Effect In Re-Entrant Ferromagnet Prmn 1.4fe0.6ge2, Rong Zeng, S Dou, Jianli Wang, Stewart Campbell Jul 2013

Large Magnetocaloric Effect In Re-Entrant Ferromagnet Prmn 1.4fe0.6ge2, Rong Zeng, S Dou, Jianli Wang, Stewart Campbell

Jianli Wang

Magnetocaloric effects (MCE) at multiple magnetic phase transition temperatures in PrMn1.4Fe0.6Ge2 were investigated by heat capacity and magnetization measurements. PrMn1.4Fe0.6Ge2 is of a re-entrant ferromagnet and performs multiple magnetic phase transitions in the temperature range from 5 to 340 K. A large magnetic entropy change (−ΔSM) 8.2 J/kg K and adiabatic temperature change (ΔTad) 4.8 K are observed for a field change of 0–1.5 T around 25.5 K, associated with the field-induced first order magnetic phase transition (FOMT) from the antiferromagnetic to the ferromagnetic state with an additional Pr magnetic contribution. These results suggest that a re-entrant ferromagnet is probably …


Magnetovolume Effect In Ho2fe17-Xmnx Compounds, Jianli Wang, A Studer, S Kennedy, R Zeng, S. Dou, S Campbell Jul 2013

Magnetovolume Effect In Ho2fe17-Xmnx Compounds, Jianli Wang, A Studer, S Kennedy, R Zeng, S. Dou, S Campbell

Jianli Wang

The structural and magnetic properties of seven compounds in the Ho2Fe17-xMnx series (x = 0-5) have been investigated. The spontaneous magnetization Ms at 10 K exhibits a minimum at x ≈ 3.8 while the 3d-sublattice magnetization MT is found to decrease at ∼ −3.4 μB/per Mn atom compared with the rate of ∼−2.0 μB/per Mn atom expected from a simple dilution model. All of the Ho2Fe17-xMnx compounds exhibit anisotropic thermal expansion below their Curie temperatures leading to the presence of strong magnetovolume effects and Invar-type behavior below TC. An approximately zero volume thermal expansion has been detected between 10 K …


The Effect Of Slag Basicity On Spinal Inclusion Wettability, Hamed Abdeyazdan, Brian J. Monaghan, Neslihan Dogan, M Akbar Rhamdhani Jun 2013

The Effect Of Slag Basicity On Spinal Inclusion Wettability, Hamed Abdeyazdan, Brian J. Monaghan, Neslihan Dogan, M Akbar Rhamdhani

Brian Monaghan

Steel cleanness is an important and growing research area driven by the demands to produce high quality steel. Inclusion content in steel is an important criterion to assess clean steel. MgO.Ah03 spinel inclusions cause problems in steel processing and are generally deleterious to steel products due to their high melting point and high hardness. Jnclusions are generally r· moved by rea ting with slag. This is primarily achieved by optimizing lhe PI' 'ess omliLions to promote contact and reaction between the inclusion and S,l,lg '. or efticient rem val from the steel the inclusions must attach to and dissolve in …


The Effect Of Sulfur Concentration In Liquid Iron On Mineral Layer Formation During Coke Dissolution, Michael W. Chapman, Brian J. Monaghan, Sharon Nightingale, John G. Mathieson, Robert J. Nightingale Jun 2013

The Effect Of Sulfur Concentration In Liquid Iron On Mineral Layer Formation During Coke Dissolution, Michael W. Chapman, Brian J. Monaghan, Sharon Nightingale, John G. Mathieson, Robert J. Nightingale

Brian Monaghan

The effects of sulfur concentration in liquid iron on mineral layer development between coke and iron as coke dissolves in a 2 mass % carbon-iron liquid have been investigated at 1500°C. Initial sulfur in iron concentrations used ranged from 0.006 to 0.049 mass %. Key findings include that the two stage dissolution behavior exhibited in the carbon transfer from coke to iron as reported in a previous study by the authors, at low initial sulfur in iron contents, was also apparent at the higher values used in this study. This two stage behavior was attributed to a change in the …