Engineering Commons^™

Optimization And Enhancement Of Co2 Sequestration In Industrial Wastes For Environmental Applications, Maisa El Gamal, Ameera F. Mohammad

All Works

This paper explores carbon capture and storage (CCS) through carbide lime waste (CLW), a by-product of acetylene production, under different conditions. This process is specifically designed to provide an onsite waste management solution for several industries that can easily be integrated into existing systems. In addition, the effect of the carbonation process on collected solids morphology and average particle size was studied. The structural and chemical characteristics of the carbonated carbide lime samples were investigated using X-ray diffraction, scanning electron microscopy, TGA analysis, and Raman spectroscopy. The effect of carbonation conditions on the total dissolved solids and change in pH …

Carbonised Fluidised Fly Ash (Cffa); A New Product For Mining Engineering Purposes (Discussion Of Possible Applications), Marian Jacek Łączny, Przemysław Rompalski

Journal of Sustainable Mining

The article presents and summarises the current state of research and laboratory results on the carbonation of fly ash with carbon dioxide in the context of its use in mining engineering. Based on previous publications and patent applications, the possibilities of using carbonated fly ash from fluidised bed boilers for the following applications were discussed: securing excavations particularly susceptible to fire hazards, shotcreting and securing longwalls and supports, constructing cases, securing decommissioned shafts, and others, which means wherever the use of cement is required. It was pointed out that the removal of excess free calcium oxide makes it possible to …

Sensory Comparison Of Beer Carbonated Using Forced Carbonation And The Carbo Rock-It, Michala Smith

Biological and Agricultural Engineering Undergraduate Honors Theses

Craft brewing is a growing market which represents over 12% of beer produced in the United States. Dr. G Scott Osborn, PE invented the Carbo Rock-It™ to improve the carbonation process for craft breweries. The invention allows for shorter carbonation time and uses less CO₂, saving companies money and time. Because of the lack of gas losses through bubbling, Osborn theorized that the Carbo Rock-It could also prevent the “stripping of the nose” that can occur in traditional forced carbonation. Existing research supports the mechanism, as beer flavor and aroma volatiles have been detected during the release of …

Development Of An Equation To Correlate Brite Tank Temperature And Pressure To Beverage Carbonation Concentration, Devyn Meyer

Biological and Agricultural Engineering Undergraduate Honors Theses

The Carbo Rock-It™ is an invention created to carbonate beverages at craft breweries. One of the Carbo Rock-It’s main features is that it does not add a significant volume of undissolved gas bubbles to the brite tank in which the beverage is carbonated. This may allow temperature and pressure readings from the brite tank to be used to determine the concentration of dissolved carbon dioxide in the beverage continuously in real time. This eliminates the need for manual samplings, which could save breweries time and allow for more controlled, accurate carbonation. The goal of this project was to develop an …

An Engineering And Economic Analysis Of The Implementation Of The Carbo Rock-It, Lydia Huck

Graduate Theses and Dissertations

The patented Carbo Rock-It system was developed to carbonate beverages for the craft brewing industry with the goal of reducing time, cost, and environmental impacts of the carbonation process. This research field tests, models, analyzes and optimizes the engineering and economic performance of a commercial-scale Carbo Rock-It placed in production at an operating brewery (Core Brewing and Distilling Co., Springdale, AR). Field tests indicated that the Carbo Rock-It was able to successfully carbonate twelve 120 BBL batches of Scarlet Letter Seltzer to 3.0 vol/vol while meeting all beverage quality and safety requirements. The Carbo Rock-It was able to reduce carbonation …

Effect Of In-Situ Formed Nano-Calcite Particles On Hydration And Properties Of Cement-Based Materials, Bowen Tan

Masters Theses

The in-situ preparation of nano-calcite via bubbling method and the effects of the nano-calcite on the hydration process and properties of the cement-based materials are investigated in this research. The nano-calcite is synthesized under different conditions and added into Portland cement to prepare test samples. The bubbling method is then introduced in upcycling the municipal solid waste incineration (MSWI) ashes, and the effects of the upcycled MSWI ashes on the hydration of Portland cement is investigated. Experimental results illustrate that the COâ‚‚ bubbling method can produce nanometer-to-sub- micron-sized calcite particles, and the synthesis rate and the morphology of the nano-calcite …

Carbon Dioxide Uptakes By Acetylene By-Products Through Gas–Solid And Gas–Solid–Liquid Reactions, Maisa El Gamal, Ameera Mohammad, Suhaib Hameedi, Hadeel Alzawahreh

All Works

In this work, carbon dioxide uptake value by acetylene by-products was evaluated through two types of carbonation reactions. In the first reaction, solid acetylene by-products were reacted with a simulated effluent CO2 gas (10% CO2 and 90% air) and the maximum uptake value of carbon dioxide per unit mass of reacted solids was calculated. In the second reaction, the mixed solid acetylene by-product with distilled water at a specific mass to volume ratio was reacted with the same effluent CO2 gas to compare the maximum CO2 uptake value with the first reaction. It was found that a superior CO2 uptake …

Effect Of Membrane Properties On The Carbonation Of Anion Exchange Membrane Fuel Cells, Yiwei Zheng, Lyzmarie Nicole Irizarry, Noor Ui Hassan, Eric R. Williams, Morgan Stefik, Jacob M. Lamanna, Daniel S. Hussey, Mustain E William

Faculty Publications

Anion exchange membrane fuel cells (AEMFC) are potentially very low-cost replacements for proton exchange membrane fuel cells. However, AEMFCs suffer from one very serious drawback: significant performance loss when CO2 is present in the reacting oxidant gas (e.g., air) due to carbonation. Although the chemical mechanisms for how carbonation leads to voltage loss in operating AEMFCs are known, the way those mechanisms are affected by the properties of the anion exchange membrane (AEM) has not been elucidated. Therefore, this work studies AEMFC carbonation using numerous high-functioning AEMs from the literature and it was found that the ionic conductivity of the …

Investigation Into The Effects Of Supercritical Carbon Dioxide Exposure On Well-Bore Cement Integrity, Claude Boiteau

Graduate Theses & Non-Theses

Current subterranean injection of anthropogenic Carbon Dioxide (CO₂), or CO₂ resulting from human activity, is occurring at multiple locations in both the domestic United States and abroad. It involves the capture of CO₂ from stationary industrial sources such as power plants and processing facilities, and subsequent injection into suitable subsurface environments. Injection is an alternative to the release of CO₂ and reduces the environmental impact of increased atmospheric carbon levels. The three scenarios for CO₂ injection are: the sequestration of captured anthropogenic CO₂, the re-injection of produced CO₂, and the …

Comparing Economics Of Traditional Carbonation Method And A Novel Carbonation Invention For Craft Beer, Kira Simonson

Biological and Agricultural Engineering Undergraduate Honors Theses

The traditional method for the carbonation of beer includes bubbling CO₂ through a pressurized brite tank until the desired level of carbonation concentration is reached. The gas either dissolves in the liquid volume or passes through the beer into the gas headspace above the bulk volume of beer. The gas that passes through the liquid can strip the beer of flavors, and this undissolved gas is vented to the atmosphere. To reduce the gas lost to the atmosphere, the CO₂ is dissolved into the beer slowly over a long period of time, which increases gas-use efficiency but sacrifices …

Utilization Of Low-Lime Calcium Silicate In Hydrated And Carbonated Cementitious Materials, Mohammad Rakibul Islam Khan

Electronic Theses and Dissertations

This study investigated the potential application of wollastonite as a cementitious material in both hydrated and carbonated binder systems. Wollastonite is naturally occurring low-lime calcium silicate (CaO.SiO₂) mineral with a substantially lower carbon footprint compared to the ordinary Portland cement (OPC). The first part of this work presented the application of wollastonite as partial replacement of OPC in traditional hydrated cement-concrete system. Second part of this work evaluated the properties of carbonation activated binder produced using wollastonite as the primary ingredient.

For the first part of the thesis, ground wollastonite with 3.5 µm and 9 µm mean particle …

Micro-Mechanical Analysis Of Corrosion Products Formed During Long-Term Carbonation Induced Corrosion Of Steel, Marijana Serdar, Dubravka Bjegovic, Valérie L’Hostis, Stéphane Poyet, Damien Féron

International Conference on Durability of Concrete Structures

During corrosion distinct types of corrosion products form, composed of different ratios of ferrous ions and oxide, hydroxides. Corrosion products have different physical and mechanical properties, mainly density, resistivity, volume and modulus of elasticity compared to iron. Knowing properties of corrosion products is indispensable for service life modelling of structures and can give valuable insight into the long-term corrosion propagation process. In this study micro-indentation method was used to evaluate mechanical properties of different layers formed during long-term carbonation induced corrosion of steel in concrete. Investigation was performed on three sets of reinforced concrete samples, that underwent corrosion during 50, …

Load-Bearing Capacity Of Corroded Reinforced Concrete Structures Caused By Carbonation And Exposed To Xc4, Esko Sistonen

International Conference on Durability of Concrete Structures

Concrete corrosion can be visualized as a combination of chemical reaction on concrete and electrochemical reaction on steel reinforcement. Failure of steel reinforcement due to corrosion can inflict significant stress on concrete during load distribution. As such, it is necessary to analyse the long-term effects of corrosion on the load bearing capacity and bending strength of steel reinforcement. This research investigated the mechanical and electrochemical properties of concrete exposed to long-term corrosion for a period of 16 years. Non-destructive testing like crack width measurements, visual examination, electrochemical measurements using Galva Pulse and determination of average chloride content were undertaken to …

Influence Of Cracks On The Carbonation Resistance Of Concrete Structures, Abbas Al-Ameeri Mr., Muhammed Imran Rafiq Dr., Orania Tsioulo Dr.

International Conference on Durability of Concrete Structures

Carbonation-induced corrosion of steel rebar embedded in concrete is one of the major issues influencing durability of reinforced concrete structures. It has been acknowledged that structural cracks in concrete influences the carbon dioxide (CO₂) diffusivity and accelerates the carbonation-induced reinforcement corrosion, however most of the previous studies on the carbonation induced corrosion have concentrated on the un-cracked / unloaded concrete. This study investigates the impact of cracks caused by loading on the depth of carbonation into concrete. Concrete prisms (100x100x500 mm) were subjected to four different crack widths (0, 0.05-0.15 mm, 0.15-0.25 mm and 0.25-0.35 mm) and the …

Climate Resilient Concrete Structures In Marine Environment Of Bangladesh, Sudarshan Srinivasan, Ian Gibb

International Conference on Durability of Concrete Structures

Bangladesh has a vast coastal infrastructure seriously affected by climate change and associated extreme environmental conditions. The rural construction sector in Bangladesh will be undergoing rapid growth in the next 10 years through rural infrastructure development programmes funded by the Asian Development Bank and the World Bank. The Local Government Engineering Department (LGED in Bangladesh), owns the rural concrete infrastructure, maintains around 380, 000 linear metres of concrete bridges or culverts in the rural coastal areas and are planning to build more than 200,000 linear metres during the next ten years. In order to design and construct durable concrete structures …

New Model For Natural Carbonation Prediction In Reinforced Concrete – Concept And Validation On Chemical Admixtures, Stephen O. Ekolu, M Raats

International Conference on Durability of Concrete Structures

A new model for prediction of natural carbonation in reinforced concrete structures has recently been developed and presented in (Ekolu, 2018). For brevity, the model is referred to as ESS model. It employs concrete strength as the primary property depicting core carbonation behaviour of any given concrete while other factors induce secondary influence. Chemical admixtures in concrete significantly influence concrete behaviour. Using experimental data from the literature (Dan-Herrera et al., 2015), the model behaviour is verified under use of various types of chemical admixtures of concrete including internal curing, shrinkage reducing, viscosity modifying, and high range water reducing admixtures. Class …

Performance Of Concrete Made With A Calcined Clay – Limestone-Portland Cement Exposed To Natural Conditions, Fernando Martirena, Ernesto Díaz, Dayran Rocha, Hamed Maraghechi, Karen Louise Scrivener

International Conference on Durability of Concrete Structures

This work presents the results of an investigation carried out to assess durability of concrete made with a calcined clay- limestone-Portland cement with 47% of clinker, hereafter named LC3, produced during an industrial trial in 2013. LC3 was used to cast concrete blocks and later expose them at a natural location at the northern coast of Cuba. Reference concrete was cast with Cuban Portland cement having 88% of clinker. Throughout three years (2015, 2016, 2017) concrete cores were systematically taken and the specimens were subjected to a testing program that included Formation factor, chloride profiling, surface resistivity, air permeability and …

Preformed Partial Gel Injection Chased By Low-Salinity Waterflooding In Fractured Carbonate Cores, Ali K. Alhuraishawy, Baojun Bai, Mingzhen Wei, Abdullah Almansour

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Fractures and oil-wet conditions significantly limit oil recovery in carbonate reservoirs. Gel treatment has been applied in injector wells to modify the prevailing reservoir streamlines and significantly reduce fracture permeability, whereas low-salinity waterflooding has been applied experimentally to modify rock wettability toward water-wet for improved oil recovery. However, both processes have limitations that cannot be resolved using a single method. The objective of this study was to test whether low-salinity water could enable gel particles to move deeply into fractures to efficiently increase oil recovery and control water production. A semitransparent fracture model of carbonate cores and acrylic plates was …

Carbon Sequestering Bio Concrete As A Solution To Growing Atmospheric Concentrations Of Co2, Connor Cech, Jackson Walker

Construction Management

High levels of anthropogenic carbon dioxide (CO₂) emissions into the atmosphere are propelling climate change, which has been proven to be highly detrimental to the planet. Cement production for the construction industry is a leading cause of these harmful carbon emissions. This project introduces a potential solution to this issue in the form of a new biological concrete that is treated with carbon sequestering bacteria of the Bacillus family to remove CO₂ from the atmosphere. The consolidated research presented in this project will explain the biology behind this process, and how it can be implemented in construction …

Aluminosilicate Dissolution And Silicate Carbonation During Geologic Co2 Sequestration, Yujia Min

McKelvey School of Engineering Theses & Dissertations

Geologic CO2 sequestration (GCS) is considered a promising method to reduce anthropogenic CO2 emission. Assessing the supercritical CO2 (scCO2)¬–gas or liquid phase water (g, l)–mineral interactions is critical to evaluating the viability of GCS processes. This work contributes to our understanding of geochemical reactions at CO2¬–water (g, l)–mineral interfaces, by investigating the dissolution of aluminosilicates in CO2-acidified water (l). Plagioclase and biotite were chosen as model minerals in reservoir rock and caprock, respectively. To elucidate the effects of brine chemistry, first, the influences of cations in brine including Na, Ca, and K, have been investigated. In addition to the cations, …

Progress Of Carbonation In Chloride Contaminated Concretes, Yaocheng Wang, P. A.M. Basheer, S. Nanukuttan, Y. Bai

International Conference on Durability of Concrete Structures

Concretes used in marine environment are generally under the cyclic effect of CO₂ and chloride ions (Cl^-). To date, the influence of carbonation on ingress of chloride ions in concretes has been widely studied; in comparison, study on the influence of Cl^- on the progress of carbonation is limited. During the study, concretes were exposed to independent and combined mechanisms of carbonation and chloride ingress regimes. Profiles of apparent pH and chloride concentration were used to indicate the progress of carbonation and ingress of Cl^- in concretes. From the apparent pH profile, a carbonation front …

Corrosion Of Steel In Concrete And Its Prevention In Aggressive Chloride-Bearing Environments, Luca Bertolini, Maddalena Carsana, Matteo Gastaldi, Federica Lollini, Elena Redaelli

International Conference on Durability of Concrete Structures

This keynote paper deals with the durability of reinforced concrete (RC) structures exposed to aggressive environments characterized by high concentration of chloride ions, namely, marine environments or the use of de-icing salts. The mechanism of chloride-induced corrosion of steel in concrete is introduced, and its influence on the service life of RC structures is analyzed. Factors affecting the time to corrosion initiation are described with regard to both concrete properties and environmental exposure conditions. Design approaches available for achieving durability targets associated with the design service life are analyzed, focusing on studies carried out by the authors in recent years …

Carbonation Resistance Of Concrete With Mortar Coating, Wen-Hu Tsao, Ming-Te Liang, Nai-Ming Huang, Ke-Hung Liao

Journal of Marine Science and Technology

The principal purpose of this paper was theoretically to study the carbonation resistance of a semi-infinite medium which concrete has a mortar coating having diffusion properties different from those of the rest of the medium. The analytical solution of a semi-infinite composite medium was used to predict the time required for subsidence due to concrete with mortar coating. The inaccurate analytical solution was published in previous books. Thus, the analytical solution of a semi-infinite composite medium is re-derived in this article. The governing equations without initial and boundary conditions in the previous books are also pointed out. In order to …

Corrosion Of Rebar Under Carbonation And Salt Environment, Wei-Chung Yeih, Jiang-Jhy Chang, Yu-Ping Huang, Ran Huang

Journal of Marine Science and Technology

In this study, the behavior of reinforced concrete under carbonation and in a salt environment was investigated. Three types of cements- Type I cement, Type II cement and highalumina cement (HAC) - were used to study the influence of cement on reinforced concrete behavior. To simulate chloridecontaminated concrete, 1% NaCl (by cement weight) was added to some groups of specimens. Results revealed that the carbonation released chloride ions from Friedel's salt, which increased the chloride content near the carbonation front. The carbonation rate of HAC concrete was higher than that of Type I and Type II cement concrete. The corrosion …

Preliminary Investigation Into The Rate Of Carbonation Of Concrete Blocks Under Normal Production Yard Conditions, Aimee Byrne, Eanna Nolan

Conference papers

The release of CO2 from calcination during the manufacture of cement can be partially or fully offset by the CO2 it naturally absorbs during its lifetime. This paper reports results from a preliminary investigation into the rate of carbonation in concrete blocks stacked in a production yard over a period of 6 months. The blocks were stacked in a normal manner under natural exposure conditions. Carbonation progress was determined by splitting the blocks and spraying the freshly exposed surface with a phenolphthalein solution at intervals over the test period. It was found that the rate of the carbonation front progression …

Evaluation Of Deterioration Of Structural Concrete Due To Chloride Intrusion And Other Damaging Mechanisms, Sudhir Palle, Brian K. Howell, Theodore Hopwood Ii, Bobby W. Meade

Kentucky Transportation Center Research Report

Kentucky's bridges continue to age and experience distress. The intrusion of chlorides into concrete remains the primary mechanism for deterioration. It leads to reinforcing steel corrosion that damages the adjoining concrete structure. This study found problematic chloride concentrations in Kentucky concrete bridge elements (decks, pier caps, abutments). Chloride levels have been found at concentrations sufficient to initiate reinforcing steel corrosion. In some cases, chloride concentrations were sufficient to cause accelerated corrosion and produce major section loss of reinforcing steel. Advanced stages of corrosion such as these typically require costly repairs and maintenance to extend the service life of bridges.

Field …

Effect Of Mortar Coating On Concrete Carbonation, Wen-Hu Tsao, Ming-Te Liang, Jiang-Jhy Chang, Nai-Ming Huang

Journal of Marine Science and Technology

The mechanism of the effect of mortar coating on carbonation of concrete is investigated. Theoretical methods of Fick's first and second laws of linear diffusion are used to calculate the carbonation depth of concrete without and with mortar coating, respectively. Theoretical analyses are also done to obtain the carbonation retard coefficients of mortar coating on concrete with surface coatings. A great deal of well organized experimental tests are carried out to verify the values of calculation. The results of present study indicate that the suitable mortar coating on concrete can effectively delay carbonation of concrete. The carbonation depth is inversely …

Experimental Study On Carbonation Of Steel Fiber Reinforced Concrete, Yan Wang, Ditao Niu, Zhenping Dong

International Conference on Durability of Concrete Structures

With the steel fiber reinforced concrete (SFRC) used more and more widely in some large-span structures, large tunnel linings, dam structures, military engineering, and some other major projects, its durability arouses more and more concerns. In this paper carbonation test of SFRC was conducted. The rule for the mixing amount of steel fiber (0, 0.5, 1.0, 1.5, and 2.0%) to affect the carbonation depth of concrete and the strength developing rule of SFRC after carbonation test were researched. To analyze the property change rules from micro perspective of SFRC after carbonation, the pore structure of SFRC after carbonation was tested. …

Co2 Sequestration In Cement-Based Materials During Mixing Process Using Carbonated Water And Gaseous Co2, Jacek Kwasny, P. A. Muhammed Basheer, Mark I. Russell, William Doherty, Kieran Owens, Neil Ward

International Conference on Durability of Concrete Structures

This paper presents selected findings from a recently completed research project, aimed at the investigation of CO₂ sequestration in cement-based materials during the early stages of hydration when the cement paste is being mixed. Portland cement pastes were carbonated during the mixing process, using both carbonated water and gaseous CO₂, and their properties were compared to the control non-carbonated mix. All mixes were prepared in a purpose-designed chamber that permitted carbonated water and gaseous CO₂ to be mixed with the cementbased materials during the mixing process, without losses of CO₂ to the external environment. Temperature …

Crystal Habit Of Caco3 Under Different Carbonation Methods, J Ariyaprayoon, U Leela-Adisorn, A Supsakulchai

Journal of Metals, Materials and Minerals

The saturated solutions of Ca(OH)2 were carbonated by CO2 in air under static and turbulent conditions. The saturation state of starting solution and carbonation methods had effect on the crystal habit. The phase of CaCO3 precipitated from saturated solution is calcite. No metastable phase of CaCO3 was found.