Engineering Commons^™

Exploring Soil Microbial Dynamics In Southern Appalachian Forests: A Systems Biology Approach To Prescribed Fire Impacts, Saad Abd Ar Rafie

Doctoral Dissertations

Prescribed fires in Southern Appalachian forests are vital in ecosystem management and wildfire risk mitigation. However, understanding the intricate dynamics between these fires, soil microbial communities, and overall ecosystem health remains challenging. This dissertation addresses this knowledge gap by exploring selected aspects of this complex relationship across three interconnected chapters.

The first chapter investigates the immediate effects of prescribed fires on soil microbial communities. It reveals subtle shifts in porewater chemistry and significant increases in microbial species richness. These findings offer valuable insights into the interplay between soil properties and microbial responses during the early stages following a prescribed fire. …

Upgraded Carbon Ores To Products, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet on the Energy & Environmental Research Center (EERC) project to develop domestic battery materials from upgraded carbon ores. Includes information on upgraded carbon ores to products (UCOP) technology and a timeline for development.

Prove Primary Battery Structure, John D. Burkhart, Andy Mccormick, Ryan Yu, Soren Barclay

Mechanical Engineering

In conjunction with Prototype Vehicle (PROVE) Laboratory, our group designed, manufactured, and tested a prototype structure to house the battery boxes for PROVE’s endurance vehicle. Our structure was designed to support the batteries during normal use, and in the event of a front crash. Our design is comprised of a secondary composite box to house the battery boxes, a bottom plate to affix the secondary box to the chassis floor, a horizontal plate fastened to the chassis, and a brace structure welded to the chassis. From the outset, we chose to use a secondary box, the primary battery boxes must …

The Effects Of Carbon Coating On The Electrochemical Performance Of Metal-Oxide Short Fiber Anodes For Lithium-Ion Batteries, David A. Sanchez

Theses and Dissertations

This thesis focuses on the process of oxidizing centrifugally spun precursor fibers and the subsequent process of carbon coating via chemical vapor deposition (CVD) for use as anode material in lithium-ion batteries (LIBs). Metal oxides have been studied as a potential replacement for graphite as they have been shown to have high theoretical capacities, good electronic conductivity, and can be synthesized using low-cost, scalable methods. However, metal oxides with high theoretical capacities also have low cycle life. To avoid this, metal oxides have been integrated with carbon to expand their life cycle. The work in this thesis shows the synthesis …

Battery Design, Construction, And Characterization For Small Motor Use Focusing On Anodic Zinc For Electron Flow, Amber Veach

Chemical Engineering Undergraduate Honors Theses

This thesis explores the construction, characterization, and application of anodic zinc batteries for powering a small electric motor for the ChemE Car competition. Two zinc galvanic cell batteries were studied: zinc-carbon and zinc-air batteries. Prototype batteries were constructed and tested for voltage, amperage, and power production. In the zinc-carbon trials, a 3:1 mixture of manganese dioxide and graphite was determined to be the best cathode for power production. The size which allowed for sufficient power while maintaining the smallest footprint on the car was a zinc can six cm tall and two cm in diameter. Analysis of paper zinc-air battery …

Direct Air Capture: Catalyzing A Carbon Negative Future, Tagg K. Lee

Civil and Environmental Engineering Publications

Direct Air Capture (DAC) technology has emerged as a promising means to address the escalating challenges of atmospheric carbon dioxide (CO₂) levels and mitigate climate change. This paper provides an elementary overview of DAC, encompassing its underlying principles, technological advancements, and associated challenges. Point Source Carbon Capture is compared against Direct Air Capture with a solid or liquid sorbent, and physisorbents/chemisorbents are outlined. The past decade has seen a steep rise in the usage of chemical sorbents in particular, which are explored alongside their regeneration processes. This review provides an introductory explanation for the mechanisms of common DAC …

Joining Methods For Continuous Fiber Reinforced Thermoplastic Composites In Structural Applications, Andrew Moran

Electronic Theses and Dissertations

Continuous fiber reinforced thermoplastic (CFRTP) composites have been proposed as an alternative to metals in structural applications. CFRTP composites can be used to create structures that are lighter weight, have better resistance to environmental factors, and have the potential to be recycled. However, one of the main challenges to CFRTP composites is connections between structural members. The goal of this thesis is to investigate the feasibility of joining CFRTP composites to both similar and dissimilar materials through literature review, coupon testing, design of a structural joint, and a small scale laboratory prototype of the joint. To achieve this goal the …

Pressureless Sintering Of Zirconium Diboride With Carbon And Boron Carbide Nanopowder, Eric W. Neuman, Gregory E. Hilmas, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

Zirconium diboride ceramics with and without carbon and boron carbide nano powder additives were prepared by ball milling with ZrB2 grinding media and pressureless sintering. Additions of up to 1 wt% nano-B4C and 0.5 wt% C were made to the ZrB2 powder. The materials were then sintered between 1800 and 2300 °C for between 90 and 360 min in an Ar/10H2 atmosphere. After sintering at 2200 °C for 90 min, densities ranged from 88.3 to 90.7% for the ZrB2 with 0–1.0% nano-B4C addition. Carbon additions of 0.5 wt% and nano-B4C additions from 0 to 1.0 wt% resulted in densities ranging …

Characterization Of Biochar As A Carbon Regulator In Manure And Environmental Management Applications, Josephine Getz

Doctoral

Biochar is a product of pyrolysis, which is the thermal decomposition of materials at elevated temperatures (300 - 900 °C) in an oxygen-limited atmosphere. Biochar has been recognized as a potentially vital tool to help reduce the climate change impact. It has been used in the agricultural sector as an addition to reduce greenhouse gas emissions in several animal husbandry settings. The application in the animal sector is an important point to reduce the overall amount of greenhouse gases released as this sector produces many greenhouse gases. Though not in every case a reduction of emissions was the result of …

Carbon Fiber Recycling: Delamination System, Aaron Eastman

All Undergraduate Projects

The production of composite wings at Boeing causes carbon fiber waste and CWU Mechanical Engineering Technology students have been tasked in designing a carbon fiber recycling system. This project was brought forth and funded by the Joint Center for Aerospace Technology Innovation (JCATI). There are three subsystems that make up the carbon fiber recycling system, the delamination system, shredding system, and the oven. The purpose of this project was to increase the efficiency and effectiveness of the delamination system of the carbon fiber recycling system. The old system reached approximately 30-40 percent delamination with one pass through the system, and …

Crystal Structure Prediction Of Materials At Extreme Conditions, Ashley S. Williams

USF Tampa Graduate Theses and Dissertations

The prediction of the structure of a crystal given only the constituent elements is one of the greatest challenges in both materials science and computational science alike. If one were to try to predict a novel crystal by brute force, meaning by arranging the atoms in every possible position of the unit cell and optimizing the geometry to find the energy minima of the potential energy surface, the amount of computer resources required to complete the calculation on the timescale of a few years would vastly exceed the currently installed computational capacity of the entire world. Fortunately, several methods have …

Strengthening Of Concrete Deep Beams Using Carbon Fabric Reinforced Cementitious/Geopolymeric Matrix, Nour Mohamed Muhsen Khir Allah

Theses

This research aimed to examine the effectiveness of using carbon fabric-reinforced matrix (C-FRM) composites to improve the shear response of reinforced concrete (RC) deep beams. Ten RC deep beams with a/h of 1.6 were tested, where a is the shear span and his is the beam depth. Test parameters included the presence of internal shear reinforcement (no shear reinforcement and minimum shear reinforcement), number of C-FRM composite layers (one and two layers), angle of inclination of the second layer of CFRM (90o and 0o with respect to the longitudinal direction of the beam), and type of matrix (cementitious and geopolymer). …

Investigation Of Carbon-Based Label-Free Electrochemical Aptasensors For Point-Of-Care Cancer Biomarker Detection, Shahrzad Forouzanfar

FIU Electronic Theses and Dissertations

Cancer is the second cause of death, with millions of fatalities every year. The early detection of cancer can tremendously increase the survival chances of the patients. An effective approach for early detection of cancer is developing reliable and relatively cheap biosensors that can quantify the cancer biomarkers from blood samples. These classes of the biosensor are commonly referred to as point-of-care (POC) cancer biomarker biosensors. The label-free electrochemical biosensors based on carbon dravite materials can be feasible for POC cancer biomarker biosensors. The present dissertation aims to design, develop, and optimize carbon-based biosensors for label-free detection of lactic acid …

Equations Of State For Warm Dense Carbon From Quantum Espresso, Derek J. Schauss

Theses and Dissertations

Warm dense plasma is the matter that exists, roughly, in the range of 10,000 to 10,000,000 Kelvin and has solid-like densities, typically between 0.1 and 10 grams per centimeter. Warm dense fluids like hydrogen, helium, and carbon are believed to make up the interiors of many planets, white dwarfs, and other stars in our universe. The existence of warm dense matter (WDM) on Earth, however, is very rare, as it can only be created with high-energy sources like a nuclear explosion. In such an event, theoretical and computational models that accurately predict the response of certain materials are thus very …

Jcati Pyrolysis System, Jack Dutton

All Undergraduate Projects

The Joint Center for Aerospace Technology Innovation (JCATI) project is designed to recycle carbon fiber pieces for use in manufacturing. Part of the system requires the removal of resin from the carbon fibers to facilitate the recycling of carbon fiber. To accomplish this task the pyrolysis process is implemented using a commercial grade oven with a conveyor system. Argon gas is injected into the shroud and over the oven to purge the interior of oxygen. The conveyor system enables this to be a batch process. A ramp is used to allow simple addition of material to the conveyor system and …

Modeling And Effects Of Non-Homogeneous Infiltration On Material Properties Of Carbon-Infiltrated Carbon Nanotube Forests, Daniel Owens Snow

Theses and Dissertations

This work investigates the material properties and production parameters of carbon infiltrated carbon nanotube structures (CI-CNT's). The impact of non homogeneous infiltration and the porosity of cross section regions, coupled with changes in designed geometry, in this case beam width, on the density and modulus of elasticity are compared. Three potential geometric models of beam cross section are proposed and evaluated. 3-point bending, SEM images, and numerical optimization are used to assess the validity of each model and the implications they have for future CI-CNT material applications. Carbon capping near exterior beam surfaces is observed and determined to be a …

Fabrication Of Multifunctional Carbon Coated Cobalt Ferrite Core/Shell Nanostructures By Pulsed Laser Ablation, Joy Roy

MSU Graduate Theses

Considerable research work is going on worldwide among the therapeutic scientific communities to use magnetic nanoparticles (NPs) as a controlled drug delivery system. Challenges to use those NPs for such in-vivo applications successfully are mainly biocompatibility and the functionality of those NPs. Addressing the needs, in this project, we synthesized carbon-coated cobalt ferrite (CFO) core-shell nanoparticles (CSNPS) by ablating a solution of toluene and CFO NPs with varying number of pulsed laser shots. The structure of the CSNPs then investigated through X-ray diffraction (XRD), Raman spectroscopy, and also with the high-resolution transmission electron microscopy (HRTEM). The XRD analysis shows that …

Investigation Of Oxidized Carbon Supported Au Catalysts Synthesized Via Strong Electrostatic Adsorption Of Au(En)2Cl3 For The Hydrochlorination Of Acetylene To Vinyl Chloride Monomer, Sean Reginald Noble

Theses and Dissertations

Over 20 million tons of vinyl chloride monomer (VCM) is produced every year using acetylene hydrochlorination using a supported mercuric chloride catalyst. During this process mercury is reduced and sublimes into the environment harming all living animals and humans, so carbon-supported Au catalysts have been developed in attempts to replace it. Various techniques have been used to make these catalysts including several variations of dry impregnation. In this study we investigate the ability of Strong Electrostatic Adsorption (SEA) of Au(en)₂Cl₃ onto various supports to demonstrate the ability to rationally and consistently synthesize gold catalysts with ultra-small particle …

Brominated Carbon Materials As Positive Electrodes For Nonaqueous Secondary Lithium-Bromine Batteries, Benjamin Beau Peterson

LSU Doctoral Dissertations

Secondary lithium-bromine (Li-Br₂) batteries have theoretical potentials near 4.1 V vs Li/Li⁺ and capacities more than 2 times greater than conventional Li-ion batteries. Herein, secondary, non-aqueous Li-Br₂ half-cell batteries are reported using a Li metal anode, carbon-coated glass fiber separator, non-aqueous Li-based electrolytes with and without the addition of lithium bromine (LiBr) salt, and positive electrodes consisting of either chemically brominated non-graphitic carbon or carbon derived from the carbonization of metal-organic frameworks (MOFs) with LiBr embedded into the micro- and mesopores of the carbon matrix. The separator is effective in mitigating the transport of Br_{2 …}

Novel Methods For Composites Recycling Via Pyrolysis, Matt Jacobs

Undergraduate Honors Theses

Composites are unique materials in many respects. When fabric woven from carbon fibers is joined with a thermoset resin in a controlled environment, it results in a very strong material, especially evaluated on a pound-for-pound basis against metals and ceramics. One aspect of this construction that provides great strength lies in the fiber-matrix adhesion which facilitates load transfer to the reinforcement of the composite. This fiber-matrix adhesion is promoted by the polarity of the usual thermoset matrices, and properly designed sizing materials coating the fibers. It’s a two-edged sword, though. Although the resin and the fibers are quite strong together, …

Carbon-Based Artificial Sei Layers For Aqueous Lithium-Ion Battery Anodes, Usha Subramanya, Charleston Chua, Victor Gin He Leong, Ryan Robinson, Gwenlyn Cruz Cabiltes, Prakirti Singh, Bonnie Yip, Anuja Bokare, Folarin Erogbogbo, Dahyun Oh

Faculty Publications

Replacing flammable organic electrolytes with aqueous electrolytes in lithium-ion batteries (LIB) can greatly enhance the safety of next-generation energy storage systems. With the extended electrochemical stability window of electrolytes, 'water-in-salt' (WIS) electrolytes containing LIB presented significant performance improvements. However, the solubility limits of lithium salts in water restrain the extent of kinetic protection offered by the high salt concentration. Here, we report design strategies of anode structure to improve the cycle life of LIB with WIS electrolytes. We introduced partially graphitic protective carbon layers on anode particles using a versatile coating method. This protective layer not only improved charge transfer …

Economic Efficiency And Carbon Emissions In Mes With Flexible Buildings, Zach Lawrence Hurwitz

Graduate College Dissertations and Theses

Multi-energy systems offer an opportunity to leverage energy conversion processes and temporary energy storage mechanisms to reduce costs and emissions during operation of campuses, cities, and buildings. With increasing options for flexibility in demand-side resources it is possible to meet demand without sacrificing comfort and convenience of MES occupants.

This Thesis develops a multi-period, linear optimization model of an MES with flexible buildings that captures nonlinearities in the efficiency of energy conversion processes. The flexible buildings are parametrized, in part, based on historical data from a college campus in Vermont, USA. The idea of the MES model is to investigate …

S/N-Doped Carbon Nanofibers Affording Fe7s8 Particles With Superior Sodium Storage, Xiu Li, Tao Liu, Yunxiao Wang, Shulei Chou, Xun Xu, Anmin Cao, Libao Chen

Australian Institute for Innovative Materials - Papers

2020 Iron sulfides draw much attention as electrode candidates for sodium-ion batteries (SIBs) due to the rich chemical stoichiometries and high capacity. However, they usually exhibit poor cycling performance due to the large volume change during sodiation/desodiation process. In this work, we embed Fe7S8 nanoparticles into sulfur, nitrogen-doped carbon (S/N-C) nanofibers through electrospinning/sulfurization processes. The heteroatom doped carbon matrixes could effectively protect the Fe7S8 from structural collapse, obtaining a stable cycling performance. Moreover, the conductive matrixes with 1D structure can facilitate the diffusion of electrons, leading to good rate capability. As results, the as-designed Fe7S8@S/N-C nanofibers present a discharge capacity …

Carbon Oxidation At The Atomic Level: A Computational Study On Oxidative Graphene Etching And Pitting Of Graphitic Carbon Surfaces, Simon Schmitt

Theses and Dissertations--Mechanical Engineering

In order to understand the oxidation of solid carbon materials by oxygen-containing gases, carbon oxidation has to be studied on the atomic level where the surface reactions occur. Graphene and graphite are etched by oxygen to form characteristic pits that are scattered across the material surface, and pitting in turn leads to microstructural changes that determine the macroscopic oxidation behavior. While this is a well-documented phenomenon, it is heretofore poorly understood due to the notorious difficulty of experiments and a lack of comprehensive computational studies. The main objective of the present work is the development of a computational framework from …

Laser-Spark Multicharged Ion Implantation System ‒ Application In Ion Implantation And Neural Deposition Of Carbon In Nickel (111), Oguzhan Balki

Electrical & Computer Engineering Theses & Dissertations

Carbon ions generated by ablation of a carbon target using an Nd:YAG laser pulse (wavelength λ = 1064 nm, pulse width τ = 7 ns, and laser fluence of 10-110 J/cm²) are characterized. Time-of-flight analyzer, a three-mesh retarding field analyzer, and an electrostatic ion energy analyzer are used to study the charge and energy of carbon ions generated by laser ablation. The dependencies of the ion signal on the laser fluence, laser focal point position relative to target surface, and the acceleration voltage are described. Up to C⁴⁺ are observed. When no acceleration voltage is applied between …

Evaluation And Enhancement Of Carbon Sequestration Potential Of Existing Vegetation Along Roadsides, Vikram Kapoor, Jeffrey Hutchinson, Samer Dessouky

Data

Corresponding data set for Tran-SET Project No. 18HSTSA01. Abstract of the final report is stated below for reference:

"The objectives of this study were to evaluate the vegetative composition and carbon sequestration potential of vegetation along a major roadway in Texas. Soil and vegetation were evaluated along IH-35 within Bexar County for composition and carbon content. Three 20 m transects were placed at each site and percent vegetative cover was estimated and above ground plant biomass, and soil was collected from three 0.25 m2 subplots along each transect. Plant and soil samples were analyzed for carbon content. Two non-native grasses, …

Evaluation And Enhancement Of Carbon Sequestration Potential Of Existing Vegetation Along Roadsides, Vikram Kapoor, Jeffrey Hutchinson, Samer Dessouky

Publications

The objectives of this study were to evaluate the vegetative composition and carbon sequestration potential of vegetation along a major roadway in Texas. Soil and vegetation were evaluated along IH-35 within Bexar County for composition and carbon content. Three 20 m transects were placed at each site and percent vegetative cover was estimated and above ground plant biomass, and soil was collected from three 0.25 m2 subplots along each transect. Plant and soil samples were analyzed for carbon content. Two non-native grasses, bermudagrass and King Ranch bluestem, were the dominant cover at all sites accounting for > 90% coverage at several …

Prototyping A Conductive Polymer Steering Pad For Rail Freight Service, Anthony A. Villarreal, Constantine Tarawneh, Miguel Ontiveros, James Aranda, Robert Jones

Mechanical Engineering Faculty Publications and Presentations

The AdapterPlus™ steering pad is a polymer component on a railcar that helps to reduce stresses on the axle as a railcar rounds a curve. One railway application requires a minimum of 240 mA to be passed through the steering pad to the rail, which activates air valves that control automated cargo gates. Currently, two copper studs are inserted into the pad to provide a conductive path. However, after continuous cyclic loading caused by normal service operation, the copper studs deform, wear, and eventually lose contact between the two surfaces rendering the pad nonconductive. One proposed solution to this problem …

Effects Of Corrugations On Stiffness Properties Of Composite Beams For Structural Applications, Jane Xiao

Master's Theses

Composites have high strength-to-weight ratios, which is particularly desired for applications with weight restrictions. Common composite materials such as carbon fiber reinforced plastic (CF) and fiber glass reinforced plastic (FG) were used in this research. While composite materials possess high stiffness and strength properties, the stiffness of composite laminates may be maximized by changing the geometry. By adding corrugations, the flexural stiffness is increased in one direction compared to the stiffness of a flat part with the same amount of material. Thus, stiffness increases without a change in weight. The primary goal of this research was to investigate the stiffness …

Exploring The Electrical Properties Of Twisted Bilayer Graphene, William Shannon

Senior Theses

Two-dimensional materials exhibit properties unlike anything else seen in conventional substances. Electrons in these materials are confined to move only in the plane. In order to explore the effects of these materials, we have built apparatus and refined procedures with which to create two-dimensional structures. Two-dimensional devices have been made using exfoliated graphene and placed on gold contacts. Their topography has been observed using Atomic Force Microscopy (AFM) confirming samples with monolayer, bilayer, and twisted bilayer structure. Relative work functions of each have been measured using Kelvin Probe Force Microscopy (KPFM) showing that twisted bilayer graphene has a surface potential …