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Biodiesel Forming Reactions Using Heterogneous Catalysis, Yijun Liu Aug 2007

Biodiesel Forming Reactions Using Heterogneous Catalysis, Yijun Liu

All Dissertations

Biodiesel synthesis from biomass provides a means for utilizing effectively renewable resources, a way to convert waste vegetable oils and animal fats to a useful product, a way to recycle carbon dioxide for a combustion fuel, and production of a fuel that is biodegradable, non-toxic, and has a lower emission profile than petroleum-diesel. Free fatty acid (FFA) esterification and triglyceride (TG) transesterification with low molecular weight alcohols constitute the synthetic routes to prepare biodiesel from lipid feedstocks. This project was aimed at developing a better understanding of important fundamental issues involved in heterogeneous catalyzed biodiesel forming reactions using mainly model …


Heterogeneous Catalysis And Biodiesel Forming Reactions, Dora Lopez Aug 2007

Heterogeneous Catalysis And Biodiesel Forming Reactions, Dora Lopez

All Dissertations

Biodiesel, defined as 'a fuel comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oils or animal fats', is finding favor commercially worldwide. The objective of this study is to evaluate the use of solid catalysts for triglyceride transesterification and carboxylic acid esterification to produce biodiesel fuel.
Processes using mainly homogeneous alkali catalysts (such as NaOH, KOH, and methoxides) have been shown to be effective for biodiesel synthesis when dealing with virgin oil feedstocks. Use of acid catalysts (e.g., H2SO4) becomes important when processing low quality feedstocks that contain appreciable amounts of free fatty acids, such as …


Reviewing The Effects Of Alternative Fuels, Average Speed And Idling Time On Emissions From Orange County School Bus Fleet, Ali Bayat Jan 2007

Reviewing The Effects Of Alternative Fuels, Average Speed And Idling Time On Emissions From Orange County School Bus Fleet, Ali Bayat

Electronic Theses and Dissertations

Orange County, FL has been experiencing ozone concentrations in the past several years which in some cases exceeded the national and state standards. The high concentration of ground level ozone can cause a variety of health problems including chest pain, coughing, throat irritation, and congestion or it can worsen bronchitis, emphysema, and asthma. Other effects include reduction of agricultural crop and commercial forest yields, lower growth and survivability of tree seedlings, and higher susceptibility of plant to diseases, pests and other stresses such as harsh weather. The ozone generation rate is directly related to the ambient concentration of nitrogen oxides …