Engineering Commons^™

Investigations Of Thermal Treatment Of Softwood Kraft Lignin Under Fractional And Ablative Pyrolytic Conditions, Dideolu J. Daniel

LSU Master's Theses

Lignin is second to cellulose in abundance among polymers in nature. Research studies on the development of new products and material combinations in which lignin degradation/conversion products are involved are still in their infancy, because fundamental knowledge about its structure, reactivity, and material and polymer behavior, is still lacking.

The objective of this research study was to investigate the complex thermal deconstruction and mechanistic behavior of a type of technical lignin, known as Kraft lignin, under depolymerization and to develop operating conditions for parameters influencing resulting product yields and operation of pyrolysis reactors.

Softwood Kraft lignin (s-KL) and methanol-fractionated (ex-KL) …

Pyrolysis Of Miscanthus And Products Characterization, Arshdeep Singh

Electronic Thesis and Dissertation Repository

Miscanthus, an invasive crop, has recently gained attention as an emerging energy crop because of certain features such as adaptability to lower temperature, efficient use of water and nutrients, low or no need of nitrogen fertilizers, high biomass yield, fast growing cycle and less intensive agricultural cultivation practices than other energy crops, such as corn.

The literature review is focused on the value-added applications and conversion of Miscanthus for bioenergy and biomaterial applications. The thermochemical conversion technologies reviewed in this chapter include pyrolysis, liquefaction, torrefaction and gasification, whereas biochemical conversion technologies include enzymatic saccharification and fermentation.

In this work, …

Evaluation Of The Antifungal Activity Of Cattle Manure Bio-Oil, Matheus Pinheiro Carvalho, Alberto Wisnievski Junior, Ingred Suellen Carvalho Carregosa, Wyllian Winckler Sartori, Maria Lucileide Nogueira Santos Ramos

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

Plant diseases are a threat to the health and functionality of both natural and man-made ecosystems. Diverse methods and strategies are being employed to prevent, ameliorate or control plant diseases. Unsustainable practices such as use and misuse of synthetic fungicides have caused severe harm to human health, wildlife and the environment (1). Fungal cause the most destructive plant diseases and impose major losses to both natural and production systems, and one of it is the fungi. Botanical fungicides are particularly sought after because they are abundant, selective, readily degraded, and are not toxic to mammals (2).

Bio-oils produced by rotatory …

Upgrading Of Wheat/Barley And Miscanthus Bio-Oil Over A Sulphided Catalyst, Bogdan Shumeiko, Miloš Auersvald, David Kubička, Petr Straka, Pavel Šimáček, Dan Vrtiška

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

In recent years, the production of biofuels from non-food crops wastes and harvesting residues plays an important role in the improvement of the global environment and in the replacement of declining oil reserves¹. Hydrogenation of lignocellulosic bio-oil is attracting much attention as a suitable way to produce petroleum-refinery compatible feedstock. Primarily, hydrogenation of bio-oil is carried out under severe reaction conditions in two-stage fixed-bed reactors, filled with a noble metal catalyst in the first zone and with a sulphided catalyst in the second zone². This setup allows producing low-oxygen upgraded bio-oil, however, it is economically unviable …

Challenges And Opportunities For The Synthesis Of Novel Pyrolysis Oil Refineries, Manuel Garcia-Perez, Anamaria Pp Pires

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

Bio-oil derived from fast pyrolysis of lingo-cellulosic materials is among the most complex and inexpensive raw oils that can be produced today. Although commercial or demonstration scale fast pyrolysis units can readily produce this oil, this industry has not grown to significant commercial impact due to the lack of bio-oil market pull. In this presentation we will review the challenges and opportunities for bio-oil upgrading and refining. Pyrolysis oil consists of six major fractions. (water 15-30 wt.%, light oxygenates, 8-26 wt. %, mono-phenols, 2-7 wt.%, water insoluble oligomers derived from lignin 15-25wt.%, and water soluble heavy molecules 10-30 wt.%). The …

Ablative Fast Pyrolysis Of Biomass: A New Demonstration Project In California, Usa, Dietrich Meier, Christoph Eusterbrock, Brian Gannon

Pyroliq 2019: Pyrolysis and Liquefaction of Biomass and Wastes

California is the fifth largest economy in the world and has about 40 million inhabitants. The California federal government has decided to stick to the Paris climate change agreement by 2030. For many years, California has been feeling the effects of global warming caused by the largest tree extinction in modern history, a five-year dry spell and resulting bark beetle plague, and severe forest fires coupled with heavy winds, heavy rains, and rising sea levels. California is therefore promoting the use of biogenic fuels in the transport sector. In spring 2017, there was a grant funding opportunity from the California …