Engineering Commons^™

Paper Mill Sludge Biochar To Enhance Energy Recovery From Pyrolysis: A Comprehensive Evaluation And Comparison, Zhongzhe Liu, Matthew Hughes, Yiran Tong, William Kreutter, Hugo Cortes Lopez, Simcha L. Singer, Daniel Zitomer, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Bio-oil and pyrolysis gas (py-gas) are two pyrolysis products available for potential energy recovery. Crude bio-oil, however, is typically corrosive and unstable, requiring special combustion equipment or catalytic upgrading to produce drop-in-grade fuel. In contrast, py-gas is readily useable in standard equipment for energy recovery. Previous research revealed that Ca-impregnated biochar catalyst improved bio-oil to py-gas conversion. Biochar produced from paper mill sludge (p-sludge) has very high Ca content. In this study, the catalytic ability of p-sludge biochar was systematically evaluated for the first time in pyrolysis. P-sludge biochar resulted in higher py-gas yield (40 wt% of total pyrolysis products) …

Effects Of The Inclusion Of Rice Hull Derived Bio-Oil On Wood Pellet Production, Tyler E. Lowe

Theses and Dissertations

Wood pellet production has become an advancing industry for the sake of reducing greenhouse emissions into the atmosphere especially, in European Union countries. Researchers and industry executives seek new methods and materials to improve the pelletization process. Rice hulls or husks has the potential to aid in wood pelletization as they possess high calorific values. This study focuses on using rice hull derived bio-oil from pyrolysis, which will also decrease ash content, as an additive to aid in the wood pelletization process. Using two groups of rice hull derived bio-oil as an additive in wood pelletization: Group 1 uses heavy …

A Review Of Characteristics Of Bio-Oils And Their Utilization As Additives Of Asphalts, Ran Zhang, Zhanping You, Jie Ji, Qingwen Shi, Zhi Suo

Michigan Tech Publications

Transforming waste biomass materials into bio-oils in order to partially substitute petroleum asphalt can reduce environmental pollution and fossil energy consumption and has economic benefits. The characteristics of bio-oils and their utilization as additives of asphalts are the focus of this review. First, physicochemical properties of various bio-oils are characterized. Then, conventional, rheological, and chemical properties of bio-oil modified asphalt binders are synthetically reviewed, as well as road performance of bio-oil modified asphalt mixtures. Finally, performance optimization is discussed for bio-asphalt binders and mixtures. This review indicates that bio-oils are highly complex materials that contain various compounds. Moreover, bio-oils are …

Laboratory Evaluation Of The Impact Of Additives On Asphalt Binders Used In Cold Regions, Neirouz Bouhrira

Theses and Dissertations

The objective of this research study is to evaluate the effect of additives (polymers, nanomaterials, and softening agents) on rutting, cracking, and fatigue performance of asphalt binders commonly used in cold regions (PG 52-34 and PG 64E-40). In this study, the first phase consisted of using polymers (Styrene-Butadiene-Styrene, Ground-Tire-Rubber) and nanomaterials (TiO2 and SiO2) to modify two asphalt binders used in cold regions (PG52-34 and PG64E-40). The second phase of the study consisted of adding a combination of softening agents (Corn oil or Sylvaroad) with polymers (SBR, Epoxy, and SBS) to PG52-34 asphalt binder. The performance evaluation was conducted using …

Rheological Behavior And Sensitivity Of Wood-Derived Bio-Oil Modified Asphalt Binders, Junfeng Gao, Hainian Wang, Zhanping You, Mohd Rosli Mohd Hasan, Yong Lei, Muhammad Irfan

Michigan Tech Publications

The demand for bituminous materials is continuously growing; crude oil-based asphalt binders are non-renewable, and are facing rapid depletion. With the increase of petroleum-based asphalt prices, seeking an alternative, renewable material such as bio-asphalt has become a hot research topic. However, shortcomings in this research area have been identified, notably concerning the high-temperature performance of bio-asphalt at present. This research aims to comprehensively apply conventional tests to, and study the rheological behavior of, the high-temperature performances of bio-asphalt binders, i.e., by temperature and frequency sweeps, using a dynamic shear rheometer (DSR). It will also assess the chemical functional groups of …

Anaerobic Co-Digestion Of Aqueous Liquid From Biosolids Pyrolysis, Seyedfatemeh Seyedi

Master's Theses (2009 -)

Pyrolysis is a process to treat biosolids and recover energy. During pyrolysis, conversion of organic matter to energy-rich products yields biochar, py-gas, and pyrolysis liquids (aqueous phase and non-aqueous bio-oil). The aqueous pyrolysis liquid (APL), is a high-COD liquid with no apparent use that contains polycyclic aromatic hydrocarbons and nitrogen-containing compounds. One potential beneficial use of APL is as a co-digestate to produce more biogas for renewable energy from anaerobic digesters at municipal water resource recovery facilities. Some of the organics in APL may be converted to biomethane via anaerobic digestion under proper conditions. However, some APL organics are known …

Value Added Products From Lignin And Biomass Derivatives, Chen Li

Civil & Environmental Engineering Theses & Dissertations

Pyrolysis is one of the traditional lignin and biomass utilization methods. The liquid products bio-oil and solid products bio-char are the main value-added products from lignin pyrolysis. Due to the narrow application and low quality, using the pyrolysis method to produce bio-oil and bio-char cannot bring sufficient economic benefits. In this dissertation, two methods were investigated to improve the quality of lignin bio-products.

Instead of direct pyrolysis, chemical activation (pyrolysis) was introduced in this dissertation. Compared to bio-char, the lignin chemical activation product lignin-activated-carbon has better economic value. With the best activation conditions, the lignin-activated-carbon produced a surface area of …

Pyrolysis Of Dried Wastewater Biosolids Can Be Energy Positive, Patrick J. Mcnamara, Jon Koch, Zhongzhe Liu, Daniel Zitomer

Civil and Environmental Engineering Faculty Research and Publications

Pyrolysis is a thermal process that converts biosolids into biochar (a soil amendment), py-oil and py-gas, which can be energy sources. The objectives of this research were to determine the product yield of dried biosolids during pyrolysis and the energy requirements of pyrolysis. Bench-scale experiments revealed that temperature increases up to 500 °C substantially decreased the fraction of biochar and increased the fraction of py-oil. Py-gas yield increased above 500 °C. The energy required for pyrolysis was approximately 5-fold less than the energy required to dry biosolids (depending on biosolids moisture content), indicating that, if a utility already uses energy …

The Laboratory Evaluation Of Bio Oil Derived From Waste Resources As Extender For Asphalt Binder, Xu Yang

Dissertations, Master's Theses and Master's Reports - Open

A shortage of petroleum asphalt is creating opportunities for engineers to utilize alternative pavement materials. Three types of bio oils, original bio oil (OB), dewatered bio oil (DWB) and polymer-modified bio oil (PMB) were used to modify and partially replace petroleum asphalt in this research. The research investigated the procedure of producing bio oil, the rheological properties of asphalt binders modified and partially replaced by bio oil, and the mechanical performances of asphalt mixtures modified by bio oil. The analysis of variance (ANOVA) is conducted on the test results for the significance analysis. The main finding of the study includes: …