Engineering Commons^™

Numerical Implementation And Validation Of A Viscoelastic-Plastic Material Model For Predicting Curing Induced Residual Stresses In Adhesive Bonded Joints, Akshat Agha, Fadi Abu-Farha

Publications

One of the main challenges in the joining of multi-material components is the assessment of the nature and magnitude of the residual stresses developing in the adhesive bond during the heat curing manufacturing process. Numerical modeling of these residual stresses can provide insights for making informed decisions related to (i) material substrate properties; (ii) adhesive properties i.e., low, medium, or high stiffness; (iii) bondline geometry i.e., bondline width and bead thickness; (iv) curing cycle characteristics; and (v) fixation design i.e., type, spacing, the number of joints. This work presents a cure history-dependent viscoelastic-plastic material description for the modeling of adhesive …

Bio-Ionic Liquid Functionalized Hydrogels Towards Smart Tissue Regeneration, Vaishali Krishnadoss

Theses and Dissertations

A blend of scaffolds, biologically active molecules, and cells are required to assemble functional constructs to repair and regenerate damaged tissue or organ via tissue engineering. The scaffold supports cell growth and proliferation and acts as a medium for diverse cellular activities. Even though hydrogel's high-water content and flexible nature make it a pronounced applicant as a scaffold, they exhibit significant technical limitations such as the absence of cell-binding motifs, lack of oxygen, conductivity, adhesive properties, growth of cells in a 3-dimensional (3D) microenvironment. In this thesis, a novel material platform is evaluated and studied to address the concerns mentioned …

Correlating Fracture Toughness And Surface Roughness For A Ductile Epoxy Adhered To Aluminum Substrates, Kurt Ryan Smith

Masters Theses

Adhesively bonded joints are used across multiple disciplines as an efficient and cost effective method for reinforcing, repairing, or creating new structures. Sufficient understanding of the bond line characteristics of the adhesive is necessary to properly design a reliable bonded joint and ensure a long service life. It is well understood that surface preparation has a significant impact on these interface characteristics as a given level of surface roughness achieves mechanical interlocking between the resin and metal and is important to prevent premature interfacial failure [1]. The goal of this study is to characterize the fracture toughness values for an …

Numerical Performance Evaluation Of The Wooden Frame Structures With Adhesive Applied Connection Under Wind And Seismic Loading, Sharthak Bhandary

Masters Theses

The objective of the research is divided into two folds. The first objective is to study the state-of-the-art modeling method for the wooden frame construction, while the second objective is to evaluate the performance of a wooden frame structure with construction adhesives under hazardous loading conditions using the selected numerical modeling method. The numerical modeling tools were classified under academic and commercial categories based on the purpose of their development. Both academic and commercial tools were further classified based on model types of the structural systems (i.e., shear walls and three-dimensional (3D) buildings) and the applied loads (i.e., wind loading …

Structural Performance Evaluation Of Dynamic Message Signs With Adhesive And Welded Joints, Ibin Amatya

Electronic Theses and Dissertations

The ultimate objective of this study was to determine the structural performance of the Dynamic Message Sign (DMS) bonded with chemical adhesive in terms of ultimate strength and fatigue strength. To achieve this objective, this study first investigated the effects of various parameters, including humidity and temperature on tensile, shear, peel, and cleavage strength through small-scale tests of adhesive specimens with variation in specimen width. The tensile, shear, peel, and cleavage specimens were conditioned in a temperature-humidity controlled chamber prior to its testing. The tensile, shear, peel, and cleavage specimens with different widths were tested according to American Society for …

Analysis Of Adhesive Anchorage Systems Under Extreme In-Service Temperature Conditions, Rachel Wang

Masters Theses

Adhesive anchorage systems have found widespread use in structural applications, including bridge widening, concrete repair and rehabilitation, and barrier retrofitting. Because these applications typically require adhesive anchorage systems to be installed outdoors, the effects of climate conditions and day-to-day temperature fluctuations on adhesive behavior and performance should be considered. The purpose of this thesis is to simulate pullout tests of adhesive anchorage systems for threaded rod and reinforcing bars and to emulate effects under various temperature conditions through the use of finite element analysis. Results from the finite element simulation are then compared to the physical tests conducted at UMass …

The Effect Of Cellulose Nanocrystals On Latex And Adhesive Properties In Emulsion- Based Polymer Nanocomposites, Marc A. Dubé, Emily D. Cranston, Carole Fraschini, Richard Berry

Polymer Reaction Engineering X (PRE 10) (2018)

Pressure sensitive adhesives (PSAs) adhere quickly and firmly to surfaces with the application of light pressure, and can be removed without leaving a residue. Their mechanical performance is measured by tack, peel strength and shear strength. A balanced combination between the three mechanical performance measurements depends on the specific end-use application and is challenging to achieve. This is particularly so when replacing solvent-based technologies with more sustainable, water-based (i.e., emulsion polymerization) technologies. PSAs synthesized using emulsion polymerization tend to have a lower shear strength due to poor gel network formation. As a result, conventional emulsion-based PSAs suffer from the inability …

Numerical Modeling Of Collision And Agglomeration Of Adhesive Particles In Turbulent Flows, Farzad Farajidizaji

Graduate College Dissertations and Theses

Particle motion, clustering and agglomeration play an important role in natural phenomena and industrial processes. In classical computational fluid dynamics (CFD), there are three major methods which can be used to predict the flow field and consequently the behavior of particles in flow-fields: 1) direct numerical simulation (DNS) which is very expensive and time consuming, 2) large eddy simulation (LES) which resolves the large scale but not the small scale fluctuations, and 3) Reynolds-Averaged Navier-Stokes (RANS) which can only predict the mean flow. In order to make LES and RANS usable for studying the behavior of small suspended particles, we …

Environmentally Friendly Alternates To Chemlok 233 Adhesive Cement, Madeline M. Busch

Williams Honors College, Honors Research Projects

The purpose of this project was to determine and qualify suitable, environmentally friendly replacement(s) for the current Chemlok 233 adhesive cement used by UTC Aerospace. Chemlok 233 was discontinued by the manufacturer based on the availability of a hazardous solvent (Trichloroethylene – TCE). The Chemlok 233 Control and four Experimental alternates with similar properties were lab tested for adhesion strength in various UTC proprietary cement specifications. The specifications modeled Chemlok’s uses in the construction of pneumatic de-icers. Chemlok 2332 was selected for use in Cement A, and Chemlok 402 was chosen for use in Cement B based on their highest …

How Strongly Do Oysters Stick?, Nicolás M. Morato, Andrés M. Tibabuzo, Jonathan J. Wilker

The Summer Undergraduate Research Fellowship (SURF) Symposium

Biological adhesives are a type of interfacial material that has incredible potential to generate new biomimetic compounds that can replace current strong, but toxic, adhesives. Therefore, a study of the chemical composition and mechanical properties of those bio-adhesives is necessary. However, in the case of oysters, despite known chemical characterization of the adult’s adhesive, there are almost no studies on its mechanical properties. Furthermore, there is no available information on the adhesive properties of spat (oysters in their larvae state). Herein, we present the first mechanical characterization of the spat adhesive, measuring its adhesion strength by hydrodynamic determination using a …

Performance Of Adhesive And Cementitious Anchorage Systems, Mirna Mendoza

Masters Theses

Post-installed anchoring systems are used extensively in Massachusetts Department of Transportation (MassDOT) projects due their ease of attachment to existing structures. However, recommendations on materials from various manufacturers are currently lacking for certain situations such as long-term tension loading. The purpose of the investigation presented in this thesis was to provide guidance on the use of anchoring systems to MassDOT. This research project evaluated the behavior of adhesive and cementitious bonded anchoring systems per the Stress-versus-Time-to-Failure approach found in the provisional standard AASHTO TP-84 in order to provide recommendations pertaining to the test method. Supplemental short-term anchor pullout tests were …

Flexural Creep Behavior Of Adhesively Bonded Metal And Composite Laminates, Hasan M. Nuwayer

Wayne State University Dissertations

Adhesively bonded structures exhibit time dependent behavior when subjected to constant load (creep). In this investigation, long-term creep behavior of adhesively bonded aluminum and carbon fiber composite beams under flexural loading was investigated. Three point bending test was selected because of its simplicity and the fact that bending stresses are quite common. In this study, two types of adhesively bonded beam specimens were tested: specimens prepared by adhesively bonding two aluminum beams and specimens prepared by adhesively bonding two unidirectional carbon fiber laminated beams. Accelerated creep tests were performed at higher temperatures up to 60 °C and deflection was measured …

Mens Doped Adhesive And Influence On Fracture Toughness, Kao Z. Yang

FIU Electronic Theses and Dissertations

Composites are in high demand; however, fasteners are often required for joining process and can reduce their advantages. One solution is adhesive bonding, but uncertainty exists regarding long term durability and the ability to interrogate bonds noninvasively. One potential solution to qualify bond integrity over its service life is to dope an adhesive with magneto-electric nanoparticles (MENs). MENs can yield output magnetic signatures that are influenced by bond quality and damage state. In this study, adhesives have been doped with MENs prior to bonding at 1% volume concentration. For optimum implementation, this health monitoring system should be evaluated for effects …

Effect Of Time Delay Between Etching And Adhesive Bonding (“Outlife” Time) On Lap-Shear Strength Of Aluminum Alloys Using Environmentally-Friendly P2 Etch, Josh Barkhimer, Matthew Erich, Gokul Nair

Materials Engineering

Raytheon Company currently uses a Forest Products Laboratory (FPL) paste etchant for preparing aluminum surfaces for adhesive bonding, and FPL is a source of hazardous hexavalent chromium. The goal of this study was to evaluate a less-toxic P2 paste etchant as a possible replacement. Coupons of 2024-T3, 6061-T6, and 7075-T6 grades of aluminum alloy were solvent-degreased, abrasively cleaned, and etched at room temperature using P2 paste following a strict protocol adopted from Raytheon. Coupons were then left exposed to air for assigned time intervals (or “outlife” times) of 0, 1, 4, 8, 16, and 63 or 72 hours. The aluminum …

Ph Responsive, Adhesive Hydrogels Based On Reversible Catechol - Boronic Acid Complexation, Ameya Ravindra Narkar

Dissertations, Master's Theses and Master's Reports - Open

Smart hydrogel adhesives with tunable properties consist of adhesive moieties in the polymer network that respond to external stimuli like pH, temperature, etc. Responsiveness of smart adhesives to pH, in particular, is important because of the simple actuation mechanism and the ability to achieve facile bonding and debonding upon command. Covalently crosslinked hydrogel adhesives were prepared by employing an N-HEAA (hydroxyethyl acrylamide) backbone embedded with dopamine methacrylamide (DMA), a marine mussel inspired adhesive protein and 3-acrylamido phenylboronic acid (AAPBA), to determine the effect of pH on the interfacial binding properties of the hydrogel adhesive with a borosilicate glass substrate. Swelling …

Surgical Adhesive From Mussel Mimetic Polymer, Jenna Desousa, Cori Jenkins, Jonathan Wilker

The Summer Undergraduate Research Fellowship (SURF) Symposium

Injuries involving damaged tissues are currently repaired through an invasive technique involving the use of screws, plates and sutures as support, which can damage these tissues. The biomedical field currently lacks an adhesive that can replace harmful implants. A surgical adhesive can provide a quick and easy alternative, which will minimize the risk of damaging healthy tissue in surgery. Inspiration for such materials can be found by looking at marine mussels as they are able to stick to nearly any surface, even in wet environments. Marine mussels affix themselves to different surfaces using adhesive plaques consisting of various proteins. Polymer …

Properties Of Lignin From Oil Palm Empty Fruit Bunch And Its Application For Plywood Adhesive, Lucky Risanto, Euis Hermiati, Yanni Sudiyani

Makara Journal of Technology

Lignin from lignocellulosic biomass is a potential biopolymer for wood adhesive. The aims of this study were to characterize lignin isolated from the black liquor of oil palm empty fruit bunch fiber pretreated with steam explosion in alkaline conditions and to examine the bond quality of aqueous polymer isocyanate (API) adhesive prepared from lignin, natural rubber latex (NRL), and polyvinyl alcohol (PVA) as base polymers with isocyanate crosslinkers. Lignin was precipitated from the black liquor by adding hydrochloric acid; then the precipitate was separated by filtration, thoroughly washed with water up to pH 2 and pH 5, and dried. The …

Development Of A New Guidewire Torque Device, Erika Rigaud

USF Tampa Graduate Theses and Dissertations

Guidewires have been used in many operating rooms by vascular surgeons to assist them in positioning and maneuvering through a tortuous stenosis or lesion to a desired location, and to be used as a guide for the implantation of a catheter. Surgeons are tasked with having to insert a guidewire inside a small cavity, which requires a high level of skill and patience. The insertion of the guide wire is controlled by a torque device, which allows a surgeon to advance, rotate and grip the wet hydrophilic coating of the guidewire. Despite its many advantages, the torque device does, in …

The Use Of Embedded Sensors For The Monitoring Of Adhesive Joints In Marine Environments, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace

Gordon Wallace

A copolymer incorporating polyaniline was used as a sensing medium in the construction of a resistance based humidity sensor. Aniline monomer was polymerised in the presence of poly (butyl acrylate / vinyl acetate) and a copolymer containing polyaniline emeraldine salt was obtained. The sensing medium was then developed by redissolving 1-2 w/w% of the resulting polymer residue in dichloromethane to produce a processable polymer blend solution. Some of this polymer residue was also de-doped in a solution of ammonia, and then washed with distilled water until the waste water had a neutral pH. This residue was then redissolved at 1-2 …

Enhancement Of Local Buckling Behaviour Of Steel Structures Retrofitted Through Bonding Gfrp Plates, Mohammad Al Amin Siddique

Electronic Thesis and Dissertation Repository

An effective technique involving the use of glass fiber reinforced polymer (GFRP) plates to enhance the local buckling behaviour of steel plates, beams, and moment resisting frames is presented in this Thesis. The enhancement in buckling capacity is achieved by bonding GFRP plates to the steel sections. These steel/GFRP joints have the advantages of ease of application, low cost, high strength-to-weight ratio, and resistance to corrosion. An interface element that simulates the behaviour of the adhesive bonding the steel and GFRP elements is developed and is implemented into an in-house developed finite element model to represent steel/GFRP joints. The model …

Direct Verification Of The Locking Of Liquid Locking Compounds In Threaded Fasteners, Ryan Hunter

USF Tampa Graduate Theses and Dissertations

The motivation of this research is to explore the viability of a method to directly verify whether or not an anaerobic adhesive within a threaded fastener assembly has cured sufficiently to provide secondary locking. Direct verification was implemented via the application of a test torque in the loosening direction of a fastener assembly with Loctite (given a 24 hour cure time). A three phase test plan was developed with the intent of identifying and utilizing this verification torque value which is unique to a given fastener assembly.

It was proved that the direct verification method, as outlined in the test …

Mechanisms Of X-Ray Emission From Peeling Adhesive Tape, Evan Constable, Josip Horvat, R. A. Lewis

Roger A. Lewis

It has previously been reported that x-rays are emitted when adhesive tape is peeled in a vacuum but no account of the dependence of the x-ray emission on the pressure of the environment has been given to date. In this paper we present detailed experimental data on the number and angular distribution of x-ray photons as a function of pressure. We find that x-rays are emitted for pressures between p0 = 10−3 and p1 = 10−2 mBar, with ∼ 106 counts/(cm2 s) recorded by a 256×256 pixel2 silicon array sensor placed 35 mm from the tape. The main role of …

Mechanisms Of X-Ray Emission From Peeling Adhesive Tape, Evan Constable, Josip Horvat, R. A. Lewis

Josip Horvat

It has previously been reported that x-rays are emitted when adhesive tape is peeled in a vacuum but no account of the dependence of the x-ray emission on the pressure of the environment has been given to date. In this paper we present detailed experimental data on the number and angular distribution of x-ray photons as a function of pressure. We find that x-rays are emitted for pressures between p0 = 10−3 and p1 = 10−2 mBar, with ∼ 106 counts/(cm2 s) recorded by a 256×256 pixel2 silicon array sensor placed 35 mm from the tape. The main role of …

Chitosan Adhesive Films For Photochemical Tissue Bonding, Antonio Lauto, Damia Mawad, Matthew Barton, Sabine C. Piller, Leonardo Longo

Australian Institute for Innovative Materials - Papers

Photochemical tissue bonding (PTB) is a promising sutureless technique for tissue repair. PTB is often achieved by applying a solution of rose bengal (RB) between two tissue edges, which are irradiated by a green laser to crosslink collagen fibers with minimal heat production. In this study, RB has been incorporated in chitosan films to create a novel tissue adhesive that is laser-activated. Materials and Methods. Adhesive films, based on chitosan and containing ∼0.1wt% RB were manufactured and bonded to calf intestine by a solid state laser (wavelength =532nm, Fluence ∼110J/cm2, spot size ∼5 mm). A single-column tensiometer, interfaced with a …

Steel Beams Strengthened With Ultra High Modulus Cfrp Laminates, Nisal Abheetha Peiris

University of Kentucky Doctoral Dissertations

Advanced composites have become one of the most popular methods of repairing and/or strengthening civil infrastructure in the past couple of decades. While the use of Fiber Reinforced Polymer laminates and sheets for the repair and strengthening of reinforced concrete structures is well established, research on the application of FRP composites to steel structures has been limited. The use of FRP material for the repair and rehabilitation of steel members has numerous benefits over the traditional methods of bolting or welding of steel plates. Carbon FRPs (CFRPs) have been preferred over other FRP material for strengthening of steel structures since …

Time-Temperature Curing Relationship Of An Adhesive Binder With Rice Straw, Kevin Ka-Wan Ng

Master's Theses

Rice straw is a global and proliferate agricultural waste whose production grossly outstrips viable uses. Current disposal methods are not sustainable, and more convenient methods – such as incineration – exude poor environmental stewardship. Although the direct use of straw bales in building construction presents a practical and sustainable alternative, engineering challenges associated with using it prevent its wide adoption. The Stak Block – a composite formed from compressed rice straw and a heat-cured adhesive – may overcome challenges associated with straw bale building. However, the times and temperatures needed to cure the binder with straw are not well understood. …

Mechanisms Of X-Ray Emission From Peeling Adhesive Tape, Evan Constable, Josip Horvat, R. A. Lewis

Faculty of Engineering - Papers (Archive)

It has previously been reported that x-rays are emitted when adhesive tape is peeled in a vacuum but no account of the dependence of the x-ray emission on the pressure of the environment has been given to date. In this paper we present detailed experimental data on the number and angular distribution of x-ray photons as a function of pressure. We find that x-rays are emitted for pressures between p₀ = 10⁻³ and p₁ = 10⁻² mBar, with ∼ 10⁶ counts/(cm² s) recorded by a 256×256 pixel² silicon array sensor placed 35 mm …

The Use Of Embedded Sensors For The Monitoring Of Adhesive Joints In Marine Environments, Scott T. Mcgovern, Geoffrey M. Spinks, G G. Wallace

Faculty of Engineering - Papers (Archive)

A copolymer incorporating polyaniline was used as a sensing medium in the construction of a resistance based humidity sensor. Aniline monomer was polymerised in the presence of poly (butyl acrylate / vinyl acetate) and a copolymer containing polyaniline emeraldine salt was obtained. The sensing medium was then developed by redissolving 1-2 w/w% of the resulting polymer residue in dichloromethane to produce a processable polymer blend solution. Some of this polymer residue was also de-doped in a solution of ammonia, and then washed with distilled water until the waste water had a neutral pH. This residue was then redissolved at 1-2 …