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Full-Text Articles in Engineering

Geochemistry, Petrology, And Palynology Of The Princess No. 3 Coal, Greenup County, Kentucky, Madison M. Hood, Cortland F. Eble, James C. Hower, Shifeng Dai Dec 2020

Geochemistry, Petrology, And Palynology Of The Princess No. 3 Coal, Greenup County, Kentucky, Madison M. Hood, Cortland F. Eble, James C. Hower, Shifeng Dai

Center for Applied Energy Research Faculty and Staff Publications

The high volatile C bituminous-rank, Bolsovian-age Princess No. 3 coal, a correlative of the heavily-mined Hazard No. 7 coal and the Peach Orchard and Coalburg Lower Split coals, was investigated three sites at a mine in Greenup County, Kentucky. The coal exhibits a “dulling upwards” trend, with decreasing vitrinite and a greater tendency towards dull clarain and bone lithotypes towards the top of the coal. The relatively vitrinite-rich basal lithotype is marked by a dominance of lycopod tree spores. The palynology transitions upwards to a middle parting co-dominated by tree fern and small lycopod spores and an upper bench dominated …


Rare Earth-Bearing Particles In Fly Ash Carbons: Examples From The Combustion Of Eastern Kentucky Coals, James C. Hower, John G. Groppo Jr. Sep 2020

Rare Earth-Bearing Particles In Fly Ash Carbons: Examples From The Combustion Of Eastern Kentucky Coals, James C. Hower, John G. Groppo Jr.

Center for Applied Energy Research Faculty and Staff Publications

Graphitic carbons from the combustion of bituminous coals and, perhaps, other coal ranks, tend to capture iron and a number of hazardous elements, including As, Hg, and Se. Rare earth elements in fly ashes occur in minerals, such as monazite, xenotime, and davidite. They also occur in sub-nm particles, probably in a mineral form, within the Al–Si glass on the investigated fly ashes. Just as graphitic carbons can capture Fe and hazardous elements, the carbons surrounding the fly ash glass and magnetic particles captures or encapsulates a broad suite of rare earth elements.


Leaching Kinetics Of Rare Earth Elements From Fire Clay Seam Coal, Xinbo Yang, Rick Q. Honaker May 2020

Leaching Kinetics Of Rare Earth Elements From Fire Clay Seam Coal, Xinbo Yang, Rick Q. Honaker

Mining Engineering Faculty Publications

Recovery of rare earth elements (REEs) from coal samples collected from the Fire Clay coal seam using diluted mineral acid solutions was investigated. The initial processing step was coal recovery using conventional froth flotation which concentrated the REEs in tailing material resulting in an upgrade to values around 700 ppm on a dry whole mass basis. Leaching experiments were performed on the flotation tailings material using a 1.2 M sulfuric acid solution adjusted to a temperature of 75 °C to study the extractability of REEs from coal material. The effect of particle size, leaching time, leaching temperature, and solid concentration …


Recovery Of Thorium From Monazite Ore For Applications In Clean, Sustainable Nuclear Power, Samantha Karklins, Aaron Kuhn, Haley Prater, Thomas Welker May 2020

Recovery Of Thorium From Monazite Ore For Applications In Clean, Sustainable Nuclear Power, Samantha Karklins, Aaron Kuhn, Haley Prater, Thomas Welker

Chancellor’s Honors Program Projects

No abstract provided.


Causes Of Anomaly Of Rare Earth Elements Of Seam 2 Of Yan’An Formation In The Northern Margin Of Ordos Basin And Its Geological Significance, Yang Yi, Lyu Dawei, Zhang Jianqiang, Wu Dun Apr 2020

Causes Of Anomaly Of Rare Earth Elements Of Seam 2 Of Yan’An Formation In The Northern Margin Of Ordos Basin And Its Geological Significance, Yang Yi, Lyu Dawei, Zhang Jianqiang, Wu Dun

Coal Geology & Exploration

The cause of rare earth elements(REE) anomalies in No.2 coal seam of the Yan’an Formation in the northern margin of the Ordos basin has been controversial. This paper takes Dahaize coal mine, Yulin area with well developed No.2 coal as an example to analyze REE, mineralogical characteristics of coal and partings, and to reveal the causes of anomaly of REE by Inductive Coupled Plasma Mass Spectrometry(ICP-MS) and Scanning Electron Microscopy(SEM). The results show that the total rare earth element(∑REE) concentration in the coal samples ranges from 3.71 to 46.21 μg/g. Light rare earths elements(LREE, La-Eu) are more abundant than heavy …


Separation Of Radionuclides From A Rare Earth-Containing Solution By Zeolite Adsorption, Deniz Talan, Qingqing Huang Jan 2020

Separation Of Radionuclides From A Rare Earth-Containing Solution By Zeolite Adsorption, Deniz Talan, Qingqing Huang

Faculty & Staff Scholarship

The increasing industrial demand for rare earths requires new or alternative sources to be found. Within this context, there have been studies validating the technical feasibility of coal and coal byproducts as alternative sources for rare earth elements. Nonetheless, radioactive materials, such as thorium and uranium, are frequently seen in the rare earths’ mineralization, and causes environmental and health concerns. Consequently, there exists an urgent need to remove these radionuclides in order to produce high purity rare earths to diversify the supply chain, as well as maintain an environmentally-favorable extraction process for the surroundings. In this study, an experimental design …


Fundamental Studies On The Recovery Of Rare Earth Elements From Acid Mine Drainage, Xue Huang Jan 2020

Fundamental Studies On The Recovery Of Rare Earth Elements From Acid Mine Drainage, Xue Huang

Graduate Theses, Dissertations, and Problem Reports

The Rare Earth Elements (REEs) are a group of 17 chemically similar elements that are essential raw materials for modern society. Given their increasing importance in civil and defense applications, many national governments, including the US, have denoted the REEs as critical materials and emphasized the need to identify and develop both conventional and unconventional resources to meet the growing demand. To address this challenge, the US Department of Energy has recently spearheaded efforts to evaluate the technical and economic feasibility of recovering REEs from coal and coal byproducts, which have been shown to contain REEs at an elevated concentration …


Selective Precipitation And Recovery Of Rare Earth Elements From Acid Mine Drainage, Robyn Lauren Christoferson Jan 2020

Selective Precipitation And Recovery Of Rare Earth Elements From Acid Mine Drainage, Robyn Lauren Christoferson

Graduate Theses, Dissertations, and Problem Reports

The ability to secure rare earth elements (REEs) in the United States is of concern due to the rapid growth in demand and the monopolistic supply chain. The demand for REEs has skyrocketed in recent years due to the development of many green technologies. The United States and many other countries are currently reliant on China for REEs, who currently control greater than 90% of the global supply. Due to the severe impact of previous Chinese export quotas, it is important to lessen the reliance on importation and explore methods of recycling REEs from secondary sources. A secondary REE source …