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Articles 1 - 6 of 6
Full-Text Articles in Engineering
Visible-Light-Active Disinfection Of Surface Water Coliform Using Silver/Titanium Dioxide/Silver Bromide(Ag/Tio2/Agbr) As Photocatalyst, Ashraya Upadhyaya
Visible-Light-Active Disinfection Of Surface Water Coliform Using Silver/Titanium Dioxide/Silver Bromide(Ag/Tio2/Agbr) As Photocatalyst, Ashraya Upadhyaya
University of New Orleans Theses and Dissertations
As human population becomes diverse, the need for sustainable, inexpensive, scalable, and decentralized water treatment technologies to supplement or replace conventional treatment methods are important, especially to satisfy the need of small, rural communities for safe drinking water. These challenges can be somewhat met with the use of semiconductor photocatalysis, especially if the process is driven by visible light energy. Visible-light-active (VLA) photocatalysis can be effectively applied in disinfection of drinking water. In comparison to traditional, energy-intensive, physical and chemical disinfection methods, VLA photocatalysis is capable of providing high disinfection efficiency with the use of cheaper energy, no harmful by-products, …
Designing A Reactor Chamber For Hot Electron Chemistry On Bimetallic Plasmonic Nanoparticles, Bryn Merrill, Bingjie Zhang, Jerry Larue
Designing A Reactor Chamber For Hot Electron Chemistry On Bimetallic Plasmonic Nanoparticles, Bryn Merrill, Bingjie Zhang, Jerry Larue
SURF Posters and Papers
Catalysis provides pathways for efficient and selective chemical reactions by lowering the energy barriers for desired products. Gold nanoparticles (AuNPs) show excellent promise as plasmonic catalysts. Plasmonic materials have localized surface plasmon resonances, oscillations of the electron bath at the surface of a nanoparticle, that generate energetically intense electric fields which rapidly decay into energetically excited electrons. The excited electrons have the potential to destabilize atoms strongly bound to the catalysts through occupation of antibonding orbitals. Tuning the antibonding orbitals to make them accessible for occupancy by electrons is achieved by coating the AuNP in a thin layer of another …
A Novel Method For Making Titanium Dioxide For Photocatalytic Applications, Gary Wilson
A Novel Method For Making Titanium Dioxide For Photocatalytic Applications, Gary Wilson
Graduate Theses & Non-Theses
Titanium dioxide possesses near-ideal properties for large-scale application as a photocatalyst. It is cheap and abundant, nontoxic, and environmentally safe. However, it still suffers from logistical problems preventing its application in industry: namely, rapid electron-hole recombination and inability to utilize visible light. For nearly five decades researchers in this booming field have made numerous attempts to address these problems, doping and combining titanium dioxide with a wide range of materials. A novel ambient-temperature approach to synthesis and doping/modification of anatase-form titanium dioxide was attempted using both oxygen-rich and oxygen deprived synthetic routes. Reactants were exposed to various wavelengths of ultraviolet …
Nitrogen-Doped Carbon Nanospheres-Modified Graphitic Carbon Nitride With Outstanding Photocatalytic Activity, Qiaoran Liu, Hao Tian, Zhenghua Dai, Hongqi Sun, Jian Liu, Zhimin Ao, Shaobin Wang, Chen Han, Shaomin Liu
Nitrogen-Doped Carbon Nanospheres-Modified Graphitic Carbon Nitride With Outstanding Photocatalytic Activity, Qiaoran Liu, Hao Tian, Zhenghua Dai, Hongqi Sun, Jian Liu, Zhimin Ao, Shaobin Wang, Chen Han, Shaomin Liu
Research outputs 2014 to 2021
Metals and metal oxides are widely used as photo/electro-catalysts for environmental remediation. However, there are many issues related to these metal-based catalysts for practical applications, such as high cost and detrimental environmental impact due to metal leaching. Carbon-based catalysts have the potential to overcome these limitations. In this study, monodisperse nitrogen-doped carbon nanospheres (NCs) were synthesized and loaded onto graphitic carbon nitride (g-C3N4, GCN) via a facile hydrothermal method for photocatalytic removal of sulfachloropyridazine (SCP). The prepared metal-free GCN-NC exhibited remarkably enhanced efficiency in SCP degradation. The nitrogen content in NC critically influences the physicochemical properties and performances of the …
Rational Catalyst Design For N2 Reduction Under Ambient Conditions: Strategies Towards Enhanced Conversion Efficiency, Lei Shi, Yu Yin, Shaobin Wang, Hongqi Sun
Rational Catalyst Design For N2 Reduction Under Ambient Conditions: Strategies Towards Enhanced Conversion Efficiency, Lei Shi, Yu Yin, Shaobin Wang, Hongqi Sun
Research outputs 2014 to 2021
Ammonia (NH3), one of the basic chemicals in most fertilizers and a promising carbon-free energy storage carrier, is typically synthesized via the Haber–Bosch process with high energy consumption and massive emission of greenhouse gases. The photo/electrocatalytic nitrogen reduction reaction (NRR) under ambient conditions has attracted increasing interests recently, providing alternative routes to realize green NH3 synthesis. Despite rapid advances achieved in this most attractive research field, the unsatisfactory conversion efficiency including a low NH3 yield rate, and limited Faradaic efficiency or apparent quantum efficiency still remains as a great challenge. The NRR performance is intrinsically related …
Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde
Ab Initio Investigation On The Surface Chemistry Of Functionalized Titania Membranes, Evan Hyde
Theses and Dissertations--Chemical and Materials Engineering
Titania (titanium dioxide) is a metal oxide which has recently been investigated as a photocatalyst, most commonly for use in hydrolysis, which absorbs mostly in the UV range. However, the range of absorption can be shifted to fall within the visible light range either by doping or by functionalizing the surface with atomic or molecular adsorbates. Over the course of this research, a series of Density Functional Theory (DFT) calculations are performed to ascertain the effects of these different methods on the photocatalytic performance of titania. While the effects of nitrogen doping and oxygen vacancies are well known, more recent …