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2019

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Chemical Engineering

212 Surface and interfaces

Articles 1 - 2 of 2

Full-Text Articles in Engineering

A New Interpretation Of The √7×√7 R19.1° Structure For P Adsorbed On A Ni(111) Surface, Elizabeth Barrow, Grant S. Seuser, Hiroko Ariga-Miwa, Donna A. Chen, Jochen A. Lauterbach, Kiyotaka Asakura Dec 2019

A New Interpretation Of The √7×√7 R19.1° Structure For P Adsorbed On A Ni(111) Surface, Elizabeth Barrow, Grant S. Seuser, Hiroko Ariga-Miwa, Donna A. Chen, Jochen A. Lauterbach, Kiyotaka Asakura

Faculty Publications

We have studied P adsorption on Ni(111), a system which shows complex adsorbate structures. We determined the phase diagram of the surface P adsorbed on Ni(111). At low coverage, amorphous P was observed. At temperatures between 373 and 673 K and coverages above 0.1 monolayer, we found a √7×√7 R19.1° structure, but above 673 K, other complex structures were created. These structures seemed to correlate with each other and we reinterpret a √7×√7 R19.1° structure of P adsorbed on Ni(111) based on the similarities of these surface structures. The new rectangular structure for the √7×√7 19.1° is discussed in relation …


A New Interpretation Of The √7×√7 R19.1° Structure For P Adsorbed On A Ni(111) Surface, Elizabeth Barrow, Grant S. Seuser, Hiroko Ariga-Miwa, Donna A. Chen, Jochen A. Lauterbach, Kiyotaka Asakura Dec 2019

A New Interpretation Of The √7×√7 R19.1° Structure For P Adsorbed On A Ni(111) Surface, Elizabeth Barrow, Grant S. Seuser, Hiroko Ariga-Miwa, Donna A. Chen, Jochen A. Lauterbach, Kiyotaka Asakura

Faculty Publications

We have studied P adsorption on Ni(111), a system which shows complex adsorbate structures. We determined the phase diagram of the surface P adsorbed on Ni(111). At low coverage, amorphous P was observed. At temperatures between 373 and 673 K and coverages above 0.1 monolayer, we found a √7×√7 R19.1° structure, but above 673 K, other complex structures were created. These structures seemed to correlate with each other and we reinterpret a √7×√7 R19.1° structure of P adsorbed on Ni(111) based on the similarities of these surface structures. The new rectangular structure for the √7×√7 19.1° is discussed in relation …