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Articles 1 - 30 of 42
Full-Text Articles in Engineering
Fluid–Structure Interaction Modeling Of Wind Turbines: Simulating The Full Machine, Ming-Chen Hsu, Yuri Bazilevs
Fluid–Structure Interaction Modeling Of Wind Turbines: Simulating The Full Machine, Ming-Chen Hsu, Yuri Bazilevs
Ming-Chen Hsu
In this paper we present our aerodynamics and fluid–structure interaction (FSI) computational techniques that enable dynamic, fully coupled, 3D FSI simulation of wind turbines at full scale, and in the presence of the nacelle and tower (i.e., simulation of the “full machine”). For the interaction of wind and flexible blades we employ a nonmatching interface discretization approach, where the aerodynamics is computed using a low-order finite-element-based ALE-VMS technique, while the rotor blades are modeled as thin composite shells discretized using NURBS-based isogeometric analysis (IGA). We find that coupling FEM and IGA in this manner gives a good combination of efficiency, …
Isogeometric Fluid–Structure Interaction Analysis With Emphasis On Non-Matching Discretizations, And With Application To Wind Turbines, Y. Bazilevs, Ming-Chen Hsu, M. A. Scott
Isogeometric Fluid–Structure Interaction Analysis With Emphasis On Non-Matching Discretizations, And With Application To Wind Turbines, Y. Bazilevs, Ming-Chen Hsu, M. A. Scott
Ming-Chen Hsu
In this paper we develop a framework for fluid–structure interaction (FSI) modeling and simulation with emphasis on isogeometric analysis (IGA) and non-matching fluid–structure interface discretizations. We take the augmented Lagrangian approach to FSI as a point of departure. Here the Lagrange multiplier field is defined on the fluid–structure interface and is responsible for coupling of the two subsystems. Thus the FSI formulation does not rely on the continuity of the underlying function spaces across the fluid–structure interface in order to produce the correct coupling conditions between the fluid and structural subdomains. However, in deriving the final FSI formulation the interface …
Mechanism Design For Base Station Association And Resource Allocation In Downlink Ofdma Network, Mingyi Hong, Alfredo Garcia
Mechanism Design For Base Station Association And Resource Allocation In Downlink Ofdma Network, Mingyi Hong, Alfredo Garcia
Mingyi Hong
We consider a resource management problem in a multi-cell downlink OFDMA network whereby the goal is to find the optimal combination of (i) assignment of users to base stations and (ii) resource allocation strategies at each base station. Efficient resource management protocols must rely on users truthfully reporting privately held information such as downlink channel states. However, individual users can manipulate the resulting resource allocation (by misreporting their private information) if by doing so they can improve their payoff. Therefore, it is of interest to design efficient resource management protocols that are strategy-proof, i.e. it is in the users' best …
Quantum Chemistry Simulations Using Optimization Methods, Kumara Sastry, Duane D. Johnson, Alexis L. Thompson, Todd J. Martinez, David E. Goldberg
Quantum Chemistry Simulations Using Optimization Methods, Kumara Sastry, Duane D. Johnson, Alexis L. Thompson, Todd J. Martinez, David E. Goldberg
Duane D. Johnson
Embodiments of the present invention provide, among other things, methods, apparatus, and systems for tuning a semiempirical process for predicting energy for different molecular configurations. In an example method, an energy value and an energy gradient are determined for each of a plurality of molecular configurations using an accurate method. A functional form of the semiempirical process is optimized using the determined energy values and energy gradients via multiobjective optimization. The functional form relates one or more parameters to energy values and energy gradients.
Wind Turbine Aerodynamics Using Ale–Vms: Validation And The Role Of Weakly Enforced Boundary Conditions, Ming-Chen Hsu, Ido Akkerman, Yuri Bazilevs
Wind Turbine Aerodynamics Using Ale–Vms: Validation And The Role Of Weakly Enforced Boundary Conditions, Ming-Chen Hsu, Ido Akkerman, Yuri Bazilevs
Ming-Chen Hsu
In this article we present a validation study involving the full-scale NREL Phase VI two-bladed wind turbine rotor. The ALE–VMS formulation of aerodynamics, based on the Navier–Stokes equations of incompressible flows, is employed in conjunction with weakly enforced essential boundary conditions. We find that the ALE–VMS formulation using linear tetrahedral finite elements is able to reproduce experimental data for the aerodynamic (low-speed shaft) torque and cross-section pressure distribution of the NREL Phase VI rotor. We also find that weak enforcement of essential boundary conditions is critical for obtaining accurate aerodynamics results on relatively coarse boundary layer meshes. The proposed numerical …
E-Mentoring For Employability, Andrea S. Wheeler, Simon Austin, Jacqui Glass
E-Mentoring For Employability, Andrea S. Wheeler, Simon Austin, Jacqui Glass
Andrea S. Wheeler
Recession and higher costs of higher education have over the past few years increased concerns over employability amongst engineering and construction students.
Fractionation Of Distillers Dried Grains With Solubles (Ddgs) Through A Narrowing Of Particle Size Distribution Followed By Aspiration, Rafael A. Garcia, Kurt A. Rosentrater
Fractionation Of Distillers Dried Grains With Solubles (Ddgs) Through A Narrowing Of Particle Size Distribution Followed By Aspiration, Rafael A. Garcia, Kurt A. Rosentrater
Kurt A. Rosentrater
Distiller's dried grains with solubles (DDGS) may have more value and utility if they can be separated into high protein and high fiber fractions. A variety of such separation processes have been proposed; two of the most promising processes involve three screening and three air classification unit operations. In the present study, an alternative process involving fewer unit operations is demonstrated. DDGS are subjected to a single screening, and the oversize particles are processed in a mill setup so that it narrows the particle size distribution of the oversize fraction. The milled DDGS is then processed in an air classification …
Ale-Vms And St-Vms Methods For Computer Modeling Of Wind-Turbine Rotor Aerodynamics And Fluid–Structure Interaction, Yuri Bazilevs, Ming-Chen Hsu, Kenji Takizawa, Tayfun E. Tezduyar
Ale-Vms And St-Vms Methods For Computer Modeling Of Wind-Turbine Rotor Aerodynamics And Fluid–Structure Interaction, Yuri Bazilevs, Ming-Chen Hsu, Kenji Takizawa, Tayfun E. Tezduyar
Ming-Chen Hsu
We provide an overview of the Arbitrary Lagrangian–Eulerian Variational Multiscale (ALE-VMS) and Space–Time Variational Multiscale (ST-VMS) methods we have developed for computer modeling of wind-turbine rotor aerodynamics and fluid–structure interaction (FSI). The related techniques described include weak enforcement of the essential boundary conditions, Kirchhoff–Love shell modeling of the rotor-blade structure, NURBS-based isogeometric analysis, and full FSI coupling. We present results from application of these methods to computer modeling of NREL 5MW and NREL Phase VI wind-turbine rotors at full scale, including comparison with experimental data.
Twin-Screw Extrusion Processing Of Distillers Dried Grains With Solubles (Ddgs)-Based Yellow Perch (Perca Flavescens) Feeds, Ferouz Y. Ayadi, Kurt A. Rosentrater, Kasiviswanathan Muthukumarappan, Michael L. Brown
Twin-Screw Extrusion Processing Of Distillers Dried Grains With Solubles (Ddgs)-Based Yellow Perch (Perca Flavescens) Feeds, Ferouz Y. Ayadi, Kurt A. Rosentrater, Kasiviswanathan Muthukumarappan, Michael L. Brown
Kurt A. Rosentrater
Increases in global aquaculture production, compounded with limited availabilities of fish meal for fish feed, has created the need for alternative protein sources. Twin-screw extrusion studies were performed to investigate the production of nutritionally balanced feeds for juvenile yellow perch (Perca flavescens). Five isocaloric (~3.06 kcal/g) ingredient blends, adjusted to a target protein content of 36.7% db, were formulated with 0%, 10%, 20%, 30%, and 40% distillers dried grains with solubles (DDGS) at an initial moisture content of 5–7% db, with appropriate amounts of fish meal, fish oil, whole wheat flour, corn gluten meal, and vitamin and mineral premixes. During …
Replacing −Ch2ch2– With −Conh– Does Not Significantly Change Rates Of Charge Transport Through Agts-Sam//Ga2o3/Egain Junctions, Martin M. Thuo, William F. Reus, Felice C. Simeone, Choongik Kim, Michael D. Schulz, Hyo Jae Yoon, George M. Whitesides
Replacing −Ch2ch2– With −Conh– Does Not Significantly Change Rates Of Charge Transport Through Agts-Sam//Ga2o3/Egain Junctions, Martin M. Thuo, William F. Reus, Felice C. Simeone, Choongik Kim, Michael D. Schulz, Hyo Jae Yoon, George M. Whitesides
Martin M. Thuo
This paper describes physical-organic studies of charge transport by tunneling through self-assembled monolayers (SAMs), based on systematic variations of the structure of the molecules constituting the SAM. Replacing a −CH2CH2– group with a −CONH– group changes the dipole moment and polarizability of a portion of the molecule and has, in principle, the potential to change the rate of charge transport through the SAM. In practice, this substitution produces no significant change in the rate of charge transport across junctions of the structure AgTS-S(CH2)mX(CH2)nH//Ga2O3/EGaIn (TS = template stripped, X = −CH2CH2– or −CONH–, and EGaIn = eutectic alloy of gallium and …
Modified Friction Device For Control Of Large-Scale Systems, Simon Laflamme, Douglas Taylor, Mohamed Abdellaoui Maane, Jerome J. Connor
Modified Friction Device For Control Of Large-Scale Systems, Simon Laflamme, Douglas Taylor, Mohamed Abdellaoui Maane, Jerome J. Connor
Simon Laflamme
Semi-active control of civil structures has shown to be promising at mitigating vibrations. Those systems typically perform significantly better than passive systems, and only necessitate small power to operate. Nevertheless, semi-active control devices are not yet accepted by the construction and structural engineering communities. Among impeding factors, semi-active devices are not perceived as sufficiently reliable or robust. In this paper, a new semi-active damping device based on existing reliable technology is proposed. It is composed of a stiffness element, a viscous damper, and a braking mechanism in parallel. The device, termed the modified friction device (MFD), is essentially a variable …
A Reference-Free Algorithm For Computational Normalization Of Shotgun Sequencing Data, C. Titus Brown, Adina Howe, Qingpeng Zhang, Alexis B. Pyrkosz, Timothy H. Brom
A Reference-Free Algorithm For Computational Normalization Of Shotgun Sequencing Data, C. Titus Brown, Adina Howe, Qingpeng Zhang, Alexis B. Pyrkosz, Timothy H. Brom
Adina Howe
Deep shotgun sequencing and analysis of genomes, transcriptomes, amplified single-cell genomes, and metagenomes has enabled investigation of a wide range of organisms and ecosystems. However, sampling variation in short-read data sets and high sequencing error rates of modern sequencers present many new computational challenges in data interpretation. These challenges have led to the development of new classes of mapping tools and {\em de novo} assemblers. These algorithms are challenged by the continued improvement in sequencing throughput. We here describe digital normalization, a single-pass computational algorithm that systematizes coverage in shotgun sequencing data sets, thereby decreasing sampling variation, discarding redundant data, …
Measuring Markers Of Liver Function Using A Micropatterned Paper Device Designed For Blood From A Fingerstick, Sarah J. Vella, Patrick Beattie, Rebecca Cademartiri, Anna Laromaine, Andres W. Martinez, Scott T. Phillips, Katherine A. Mirica, George M. Whitesides
Measuring Markers Of Liver Function Using A Micropatterned Paper Device Designed For Blood From A Fingerstick, Sarah J. Vella, Patrick Beattie, Rebecca Cademartiri, Anna Laromaine, Andres W. Martinez, Scott T. Phillips, Katherine A. Mirica, George M. Whitesides
Rebecca Cademartiri
This paper describes a paper-based microfluidic device that measures two enzymatic markers of liver function (alkaline phosphatase, ALP, and aspartate aminotransferase, AST) and total serum protein. A device consists of four components: (i) a top plastic sheet, (ii) a filter membrane, (iii) a patterned paper chip containing the reagents necessary for analysis, and (iv) a bottom plastic sheet. The device performs both the sample preparation (separating blood plasma from erythrocytes) and the assays; it also enables both qualitative and quantitative analysis of data. The data obtained from the paper-microfluidic devices show standard deviations in calibration runs and “spiked” standards that …
Soft Capacitive Sensor For Structural Health Monitoring Of Large-Scale Systems, Simon Laflamme, M. Kollosche, J. J. Connor, G. Kofod
Soft Capacitive Sensor For Structural Health Monitoring Of Large-Scale Systems, Simon Laflamme, M. Kollosche, J. J. Connor, G. Kofod
Simon Laflamme
Structural integrity of infrastructures can be preserved if damage is diagnosed, localized, and repaired in time. During the past decade, there has been a considerable effort to automate the process of structural health monitoring, which is complicated by the inherent large size of civil structures. Hence, a need has arisen to develop new approaches that enable more effective health monitoring.In this paper, a new sensing technique for damage localization on large civil structures is proposed. Specifically, changes in strain are detected using a capacitance sensor built with a soft, stretchable dielectric polymer with attached stretchable metal film electrodes. A change …
Statistical Tools For Analyzing Measurements Of Charge Transport, William F. Reus, Christian A. Nijhuis, Jabulani R. Barber, Martin M. Thuo, Simon Tricard, George M. Whitesides
Statistical Tools For Analyzing Measurements Of Charge Transport, William F. Reus, Christian A. Nijhuis, Jabulani R. Barber, Martin M. Thuo, Simon Tricard, George M. Whitesides
Martin M. Thuo
This paper applies statistical methods to analyze the large, noisy data sets produced in measurements of tunneling current density (J) through self-assembled monolayers (SAMs) in large-area junctions. It describes and compares the accuracy and precision of procedures for summarizing data for individual SAMs, for comparing two or more SAMs, and for determining the parameters of the Simmons model (β and J0). For data that contain significant numbers of outliers (i.e., most measurements of charge transport), commonly used statistical techniques—e.g., summarizing data with arithmetic mean and standard deviation and fitting data using a linear, least-squares algorithm—are prone to large errors. The …
Electrical Resistance Of Agts–S(Ch2)N−1ch3//Ga2o3/Egain Tunneling Junctions, Ludovico Cademartiri, Martin M. Thuo, Christian A. Nijhuis, William F. Reus, Simon Tricard, Jubulani R. Barber, Rana N.S. Sodhi, Peter Brodersen, Choongik Kim, Ryan C. Chiechi, George M. Whitesides
Electrical Resistance Of Agts–S(Ch2)N−1ch3//Ga2o3/Egain Tunneling Junctions, Ludovico Cademartiri, Martin M. Thuo, Christian A. Nijhuis, William F. Reus, Simon Tricard, Jubulani R. Barber, Rana N.S. Sodhi, Peter Brodersen, Choongik Kim, Ryan C. Chiechi, George M. Whitesides
Martin M. Thuo
Tunneling junctions having the structure AgTS–S(CH2)n−1CH3//Ga2O3/EGaIn allow physical–organic studies of charge transport across self-assembled monolayers (SAMs). In ambient conditions, the surface of the liquid metal electrode (EGaIn, 75.5 wt % Ga, 24.5 wt % In, mp 15.7 °C) oxidizes and adsorbs―like other high-energy surfaces―adventitious contaminants. The interface between the EGaIn and the SAM thus includes a film of metal oxide, and probably also organic material adsorbed on this film; this interface will influence the properties and operation of the junctions. A combination of structural, chemical, and electrical characterizations leads to four conclusions about AgTS–S(CH2)n−1CH3//Ga2O3/EGaIn junctions. (i) The oxide is ∼0.7 …
An Analytical Model Of A Ferrite-Cored Inductor Used As An Eddy Current Probe, John R. Bowler, Yi Lu, Theodoros P. Theodoulidis
An Analytical Model Of A Ferrite-Cored Inductor Used As An Eddy Current Probe, John R. Bowler, Yi Lu, Theodoros P. Theodoulidis
John R. Bowler
An analytical model of an axisymmetric eddy current ferrite-cored probe above a multi-layered conducting half-space has been developed using a procedure in which the domain of the problem is truncated radially. This means that solutions can be expressed in the form of generalized Fourier-Bessel series. The expansion coefficients are found by matching the field across the interfaces between the subregions of the problem. Initially, the magnetic vector potential of a simple circular current filament is expanded in a series form. The solution is then modified to accommodate an infinitely long coaxial ferrite core, and the principle of superposition is invoked …
Bacterial Isolation By Lectin-Modified Microengines, Susana Campuzano, Jahir Orozco, Daniel Kagan, Maria Guix, Wei Gao, Sirilak Sattayasamitsathit, Jonathan C. Claussen, Arben Merkoci, Joseph Wang
Bacterial Isolation By Lectin-Modified Microengines, Susana Campuzano, Jahir Orozco, Daniel Kagan, Maria Guix, Wei Gao, Sirilak Sattayasamitsathit, Jonathan C. Claussen, Arben Merkoci, Joseph Wang
Jonathan C. Claussen
New template-based self-propelled gold/nickel/polyaniline/platinum (Au/Ni/PANI/Pt) microtubular engines, functionalized with the Concanavalin A (ConA) lectin bioreceptor, are shown to be extremely useful for the rapid, real-time isolation of Escherichia coli (E. coli) bacteria from fuel-enhanced environmental, food, and clinical samples. These multifunctional microtube engines combine the selective capture of E. coli with the uptake of polymeric drug-carrier particles to provide an attractive motion-based theranostics strategy. Triggered release of the captured bacteria is demonstrated by movement through a low-pH glycine-based dissociation solution. The smaller size of the new polymer-metal microengines offers convenient, direct, and label-free optical visualization of the captured bacteria and …
Melting Point Suppression In New Lanthanoid(Iii) Ionic Liquids By Trapping Of Kinetic Polymorphs: An In Situsynchrotron Powder Diffraction Study, Anthony S.R. Chesman, Mei Yang, Bert Mallick, Tamsyn M. Ross, Ian A. Gass, Glen B. Deacon, Stuart R. Batten, Anja V. Mudring
Melting Point Suppression In New Lanthanoid(Iii) Ionic Liquids By Trapping Of Kinetic Polymorphs: An In Situsynchrotron Powder Diffraction Study, Anthony S.R. Chesman, Mei Yang, Bert Mallick, Tamsyn M. Ross, Ian A. Gass, Glen B. Deacon, Stuart R. Batten, Anja V. Mudring
Anja V. Mudring
he inclusion of lanthanoids in ionic liquids (ILs) offers an ideal route to incorporate their unique luminescent and magnetic properties into a bulk solution.1,2 However, lanthanoid compounds often exhibit a poor solubility in commonly used ILs because the IL anions are typically very weakly coordinating, prohibiting the simple dissolution of a lanthanoid salt by complexation to any beneficial extent.2 One strategy used to achieve high lanthanoid concentrations is to incorporate the lanthanoid cation directly into an anion that will form ILs.3 This is best accomplished by employing a ligand which readily coordinates to a lanthanoid atom and possesses properties, such …
Mox/Cnts Hetero-Structures For Gas Sensing Applications: Role Of Cnts Defects, G. Neri, S. G. Leonardi, N. Donato, C. Marichy, Jean-Philippe Tessonnier, M.-G. Willinger, Kyeong-Hwan Lee, N. Pinna
Mox/Cnts Hetero-Structures For Gas Sensing Applications: Role Of Cnts Defects, G. Neri, S. G. Leonardi, N. Donato, C. Marichy, Jean-Philippe Tessonnier, M.-G. Willinger, Kyeong-Hwan Lee, N. Pinna
Jean-Philippe Tessonnier
The preparation, characterization and sensing properties of CNT composites with a thin metal oxide (MOx) surface layer is presented. Atomic layer deposition (ALD) was applied for the coating of the inner and outer CNTs walls with thin films of ZnO and SnO2 of precisely controlled thicknesses. Differently treated CNTs with different degree of surface functionalization were used as support for the oxide films. The sensing properties of the obtained composite materials towards NO2 were investigated and related to the morphological and microstructural characteristics of both the coating and support. SnO2-based composites on CNTs treated at 700 °C show enhanced performance …
Analysis Of The Risks And Benefits Of Flight Deck Adaptive Systems, Michael C. Dorneich, William Rogers, Stephen D. Whitlow, Robert Demers
Analysis Of The Risks And Benefits Of Flight Deck Adaptive Systems, Michael C. Dorneich, William Rogers, Stephen D. Whitlow, Robert Demers
Michael C. Dorneich
The objectives of this work were to identify human performance risks and benefits of adaptive systems through a systematic analysis and heuristic evaluation of adaptive system component types and characteristics. As flight deck automated systems have more access to aircraft data, sensor data, stored databases, communicated information, and real time flight crew inputs, as well as more ability to process that information in sophisticated ways to identify situational priorities and context, it is becoming more realistic for those automated systems to adapt their behavior based on context. Automated systems that can make such changes on their own are called adaptive …
Phosphate Protected Fluoride Nano-Phosphors, Joanna Cybinska, Chantal Lorbeer, Anja V. Mudring
Phosphate Protected Fluoride Nano-Phosphors, Joanna Cybinska, Chantal Lorbeer, Anja V. Mudring
Anja V. Mudring
A fast and easy 2-in-1 step microwave reaction procedure to phosphate coated nanofluorides allows for the formation of phosphate protected fluoride nanoparticles from simple lanthanide precursors in ionic liquids. The phosphate shell efficiently prevents the fluoride particle from decomposition in an atmosphere (containing oxygen and water) at elevated temperatures.
Considering Etiquette In The Design Of An Adaptive System, Michael C. Dorneich, Patricia May Ververs, Santosh Mathan, Stephen Whitlow, Caroline C. Hayes
Considering Etiquette In The Design Of An Adaptive System, Michael C. Dorneich, Patricia May Ververs, Santosh Mathan, Stephen Whitlow, Caroline C. Hayes
Michael C. Dorneich
In this article, the authors empirically assess the costs and benefits of designing an adaptive system to follow social conventions regarding the appropriateness of interruptions. Interruption management is one area within the larger topic of automation etiquette. The authors tested these concepts in an outdoor environment using the Communications Scheduler, a wearable adaptive system that classifies users' cognitive state via brain and heart sensors and adapts its interactions. Designed to help dismounted soldiers, it manages communications in much the same way as a good administrative assistant. Depending on a combination of message priority, user workload, and system state, it decides …
Chemically Modified Multi-Walled Carbon Nanotubes (Mwcnts) With Anchored Acidic Groups, Nuruzatulifah Bt Asari Mansor, Jean-Philippe Tessonnier, Ali Rinaldi, Sylvia Reiche, M. G. Kutty
Chemically Modified Multi-Walled Carbon Nanotubes (Mwcnts) With Anchored Acidic Groups, Nuruzatulifah Bt Asari Mansor, Jean-Philippe Tessonnier, Ali Rinaldi, Sylvia Reiche, M. G. Kutty
Jean-Philippe Tessonnier
Surface functionalization of multi-walled carbon nanotubes (MWCNTs) was carried out using a gas phase treatment in a Universal Temperature Program (UTP) reactor by flowing SO 3 gas onto the CNTs while being heated at different temperatures. The functionalized nanotubes were characterized using X-ray Fluorescence (XRF), Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectroscopy. The amount of oxyen and sulfur containing groups was determined by acid-base titration. The titration results were in good agreement with elemental analysis using X-ray fluorescence. FTIR analysis showed the presence of oxygen and sulfur containing groups, S=O, C-S, C=O and-COOH. Raman spectroscopy confirmed that oxygen and …
Towards A Characterization Of Adaptive Systems: A Framework For Researchers And System Designers, Karen M. Feigh, Michael C. Dorneich, Caroline C. Hayes
Towards A Characterization Of Adaptive Systems: A Framework For Researchers And System Designers, Karen M. Feigh, Michael C. Dorneich, Caroline C. Hayes
Michael C. Dorneich
Objective: This paper presents a systematic framework characterizing adaptive systems. Background: Adaptive systems are those which can appropriately modify their behavior to fit the current context. This concept is appealing because it offers the possibility of creating computer assistants that behave like good human assistants who can provide what is needed without being asked. However, the majority of adaptive systems have been experimental rather than practical because of the technical challenges in accurately perceiving and interpreting users’ current cognitive state; integrating cognitive state, environment and task information; and using it to predict users’ current needs. We anticipate that recent developments …
Measuring Changes In International Production From A Disruption: Case Study Of The Japanese Earthquake And Tsunami, Cameron A. Mackenzie, Joost R. Santos, Kash Barker
Measuring Changes In International Production From A Disruption: Case Study Of The Japanese Earthquake And Tsunami, Cameron A. Mackenzie, Joost R. Santos, Kash Barker
Cameron A. MacKenzie
The earthquake and tsunami that struck Japan on March 11, 2011 caused a tremendous loss of life and property. The disaster also disrupted global supply chains, which was blamed for anemic growth in the global economy. A multiregional input-output model can quantify the international impacts on production due to changes in demand from companies reducing their orders because of a disruption. Using the input-output model to conceptualize a supply chain, we present a unique method for calculating indirect production losses caused by disabled production facilities. Methods for calculating the possible transfer of demand to industries in other countries are also …
Evaluating The Consequences Of An Inland Waterway Port Closure With A Dynamic Multiregional Interdependence Model, Cameron A. Mackenzie, Kash Barker, F. Hank Grant
Evaluating The Consequences Of An Inland Waterway Port Closure With A Dynamic Multiregional Interdependence Model, Cameron A. Mackenzie, Kash Barker, F. Hank Grant
Cameron A. MacKenzie
As intermodal hubs connecting barge, train, and truck transportation modes, inland ports play an important role in U.S. and global commerce. Like coastal ports, inland ports face the risk of malevolent attacks, man-made accidents, and natural disasters. However, most port impact studies focus on the consequences of one of these disruptive events suddenly closing a coastal port. This paper examines the economic impact of suddenly closing an inland port by combining a simulation and a multiregional input-output model. The simulation models how companies may react if an inland waterway port suddenly closes, and the multiregional dynamic inoperability input-output model quantifies …
Lanthanide Coordination Polymers With Tetrafluoroterephthalate As A Bridging Ligand: Thermal And Optical Properties, Christiane Seidel, Chantal Lorbeer, Joanna Cyninska, Anja V. Mudring, Uwe Ruschewitz
Lanthanide Coordination Polymers With Tetrafluoroterephthalate As A Bridging Ligand: Thermal And Optical Properties, Christiane Seidel, Chantal Lorbeer, Joanna Cyninska, Anja V. Mudring, Uwe Ruschewitz
Anja V. Mudring
Seven new coordination polymers ∞2[Ln(tfBDC)(NO3)(DMF)2]·DMF (Ln3+ = Ce, Pr, Nd, Sm, Dy, Er, Yb) with the perfluorinated linker ligand tetrafluoroterephthalate (tfBDC2−) have been synthesized. Their crystal structures consist of layers (44 nets) weakly bound by van der Waals interactions. In addition, differential thermal analysis/thermogravimetry (DTA/TG) curves, as well as absorption and emission spectra, have been recorded for all compounds.
Mercuric Ionic Liquids: [Cnmim][Hgx3], Where N = 3, 4 And X = Cl, Br, Bert Mallick, Andreas Metlen, Mark Nieuwenhuyzen, Robin D. Rogers, Anja V. Mudring
Mercuric Ionic Liquids: [Cnmim][Hgx3], Where N = 3, 4 And X = Cl, Br, Bert Mallick, Andreas Metlen, Mark Nieuwenhuyzen, Robin D. Rogers, Anja V. Mudring
Anja V. Mudring
A series of mercury(II) ionic liquids, [Cnmim][HgX3], where [Cnmim] = n-alkyl-3-methylimidazolium with n = 3, 4 and X = Cl, Br, have been synthesized following two different synthetic approaches, and structurally characterized by means of single-crystal X-ray structure analysis ([C3mim][HgCl3] (1), Cc (No. 9), Z = 4, a = 16.831(4) Å, b = 10.7496(15) Å, c = 7.4661(14) Å, β = 105.97(2)°, V = 1298.7(4) Å3 at 298 K; [C4mim][HgCl3] (2), Cc (No. 9), Z = 4, a = 17.3178(28) Å, b = 10.7410(15) Å, c = 7.4706(14) Å, β = 105.590(13)°, V = 1338.5(4) Å3 at 170 K; [C3mim][HgBr3] …
Betaine Chloride-Betaine Tetrachloridoferrate(Iii)—An Ionic Liquid Related Crystal Structure Governed By The Pearson Concept, Anja V. Mudring, Tobias Backer
Betaine Chloride-Betaine Tetrachloridoferrate(Iii)—An Ionic Liquid Related Crystal Structure Governed By The Pearson Concept, Anja V. Mudring, Tobias Backer
Anja V. Mudring
The first betaine chloride tetrachloroidoferrate(III) double salt, (Hbet)2Cl[FeCl4] = (Hbet)Cl·(Hbet)[FeCl4], was obtained from a solution of betaine hydrochloride (HbetCl) and FeCl3∙6 H2O in water. The crystal structure (orthorhombic, Pbcm, a = 6.2717(13), b = 12.841(3), c = 25.693(5) Å, Z = 4) is characterized by layers of tetrachloridoferrate(III) anions separated by chloride-bridged, H-bond mediated cationic (Hbet) dimers. The hydrogen bonding network in the crystal structure follows the Pearson HSAB (hard acid-soft base) concept: According to the Pearson concept, the chloride anions show high affinity to the carboxyl group (hard acid and base), and the tetrachloroidoferrate(III) anion preferentially interacts with the …