Engineering Commons^™

Electrocatalytic Oxidation Of Glucose On Nano Pt/C Electrode, Cui-Lian Chen

Journal of Electrochemistry

Nano Pt/C electrocatalysts were prepared by intermittent microwave heating method.The electrooxidation of glucose on smooth Pt and～Pt/C electrodes has been studied and compared.The results showed that the electrochemical properties on nano Pt/C were improved due to the reduction of the overpotential and the increase in the kinetic rate.The surface area would be significantly increased when the particle size of the catalyst was reduced to nano-scale,resulting in the increase in the activity.The enhancement in the resistance to poisoning could be explained that the oxygen-containing species are easier to react with poisoning species on nano Pt/C and re-active the electrode.

Dynamic Sulfur Tolerant Process And System With Inline Acid Gas-Selective Removal For Generating Hydrogen For Fuel Cells, Surjit Randhava, W. S. Winston Ho, Richard L. Kao, Elias H. Camara

Chemical and Materials Engineering Faculty Patents

This invention relates to a sulfur tolerant, dynamic, compact, lightweight fuel process and system that is capable of converting sulfur bearing carbonaceous fuels to hydrogen rich gases suitable for fuel cells or chemical processing applications. The process and system is based on the AHR and WGS reactions, followed by cleanup of byproduct sulfur-containing gases and carbon oxides that would otherwise poison the fuel cell electrocatalyst. Advantageously, this is accomplished via an ASMS and a methanator or an AWMR. The process and system preferably uses a special sulfur tolerant catalysts and hardware designs that enable the conversion in an energy efficient …

Fuel Cell Design For Gas Hydrates Exploration And Research, Gerhard Sauer

Masters

In this thesis the design, manufacture and testing of an Alkaline Fuel Cell (AFC) that provide electrical power to a deep sea measurement problem is described. The fuel cell was designed to operate in a long-term mode at low temperatures. The power required for the measurement probe was in the order of 5 Watts. The measurement probe was designed to operate at a depth of 3000m in sea water at a temperature of approx. 5°C and at 300 bar pressure

the main design issues included: The design of a Fuel Cell to operate at these conditions and produce enough energy …

Alkaline Fuel Cell Engineering And Testing, James Brunton, David Kennedy, Eugene Coyle

Conference Papers

A fuel cell is a device that directly converts the chemical energy of reactants (a fuel and an oxidant) into low d. c. electricity [1]. Used in conjunction with other sustainable energy options, hydrogen and fuel cell technology can provide a realistic alternative to fossil fuels. Although research is continuing in many areas we are no closer now to commercialisation than ten to twenty years ago. This is due to a number of key reasons, some of which include efficiency, scale, accessories and power output. This paper outlines the benefits that could be derived from switching to a hydrogen based …

Coastal Sediment And Fish Biosolids Remediation Using A Microbial Fuel Cell, Eric George Para

Electronic Theses and Dissertations

Abstract

Organic pollution of marine and freshwater environments has long been a problem due to spills, shipping or boating activity, runoff, and waste discharge. Microbial Fuel Cells (MFC) harness electrons released during the oxidation of organic carbon to produce an electric current. Hydrocarbons are normally broken down into carbon dioxide and water by microbial respiration, where electrons from hydrocarbons are transferred to an electron acceptor such as oxygen. In sediment, however, oxygen is consumed within the top few centimeters, and other electron acceptors such as sulfate yield less energy, which slows the degradation process. A MFC anode placed in the …