Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 12 of 12

Full-Text Articles in Engineering

Production Of Anhydrous 1,4-Dioxane, Jean Yamanis Dec 1982

Production Of Anhydrous 1,4-Dioxane, Jean Yamanis

Chemical and Materials Engineering Faculty Patents

This invention relates to the production of anhydrous 1,4-dioxane by the dimerization of ethylene oxide in the presence of an acidic type of cation exchanger, preferably an acidic cation exchanger resin having sulfonic acid groups associated therewith. The 1,4-dioxane is formed by contacting ethylene oxide in the liquid phase with an acidic-type cation exchanger at a first temperature and for a time sufficient to yield a reaction product of the ethylene oxide and the cation exchanger, and thereafter heating the reaction product at a second temperature higher than the first temperature and for a time period sufficient to dissociate the …


Speciation Of Cr (Iii) And Cr (Vi) Via Reversed Phase Hplc With Inductively Coupled Plasma Emission Spectroscopic Detection (Hplc-Icp)24, Richard N. Savage, I. S. Krull, D. Bushee, R. G. Schleicher, S. B. Smith, Jr. Dec 1982

Speciation Of Cr (Iii) And Cr (Vi) Via Reversed Phase Hplc With Inductively Coupled Plasma Emission Spectroscopic Detection (Hplc-Icp)24, Richard N. Savage, I. S. Krull, D. Bushee, R. G. Schleicher, S. B. Smith, Jr.

Materials Engineering

Chromium ions, viz., chromic (Cr+3 = III) and chromate (Cr+6 = VI), can be reliably, conveniently, reproducibly, and quickly separated and detected by the use of conventional paired-ion, reversed phase (RP) high performance liquid chromatography (HPLC) together with refractive index (RI) and/or inductively coupled plasma emission spectroscopic (ICP) detection. A number of novel paired-ion approaches have now been developed, using PIC A (tetrabutylammonium hydroxide) or PIC B (sodium n-alkyl sulfonate) separately in the mobile phase. This allows for the retention of each Cr species depending on the particular ion pairing reagent being used, while the remaining Cr ion …


Nonlinear Anelasticity Of Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig Dec 1982

Nonlinear Anelasticity Of Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

An approximate solution of the equation of motion of a nonlinear anelastic reed at or near resonance is presented. The steady state solution reproduces the well-known nonlinear resonances. The solution also predicts the existence of auto modulations, i.e., self-excited modulations of the amplitude and phase at constant power of excitation of the reed. Numerical examples of such auto modulations are presented for an antisymmetric deformation potential. Experimental studies of finite amplitude oscillations of a magnesium reed vibrating at 72 and 431 Hz at room temperature confirm the existence of auto modulations. The experimental results can be semi quantitatively described in …


Factors Influencing The Production Rate And Quality Of Lead Sinter, John R. Knoepke, Hung Yang Tsai, Arthur E. Morris Mar 1982

Factors Influencing The Production Rate And Quality Of Lead Sinter, John R. Knoepke, Hung Yang Tsai, Arthur E. Morris

Materials Science and Engineering Faculty Research & Creative Works

The sintering characteristics of a typical Missouri lead concentrate were determined for two types of raw sinter mix: conventionally prepared and pelletized. The important sintering characteristics are sulfur elimination, sinter strength, production rate of sinter, permeability of the sinter bed, and bed temperature. These characteristics were analyzed statistically, and are described by an empirical model, in which proportion of returns, moisture content, air flow, bed height, size distribution of returns, and ignition time are the independent variables. The characteristics of a conventionally prepared sinter mix are most strongly affected by the moisture content of the raw mix. The characteristics of …


Metal Cation/Anion Speciation Via Paired-Ion, Reversed Phase Hplc With Refractive Index And/Or Inductively Coupled Plasma Emission Spectroscopic Detection Methods, Richard N. Savage, D. Bushee, I. S. Krull, S. B. Smith, Jr. Jan 1982

Metal Cation/Anion Speciation Via Paired-Ion, Reversed Phase Hplc With Refractive Index And/Or Inductively Coupled Plasma Emission Spectroscopic Detection Methods, Richard N. Savage, D. Bushee, I. S. Krull, S. B. Smith, Jr.

Materials Engineering

Conventional high performance liquid chromatography instrumentation and packing materials can be inexpensively and rapidly utilized for the qualitative and quantitative analysis of various metal cations or anions. The final approaches utilize reversed phase HPLC in the form of paired-ion separations. The detection of individually eluted, fully resolved metal cations or anions is possible via conventional refractive index or inductively coupled plasma emission spectroscopic detection. In many cases, unresolved mixtures of metal cations, eluted as a single peak on HPLC, can be resolved and identified via the use of ICP detection. Both metal cations and anions can be easily resolved, according …


Measurement Of Neck Development In Tensile Testing Using Projection Moire, Raghavan Srinivasan, C. S. Hartley, C. Raju, J. Clave Jan 1982

Measurement Of Neck Development In Tensile Testing Using Projection Moire, Raghavan Srinivasan, C. S. Hartley, C. Raju, J. Clave

Mechanical and Materials Engineering Faculty Publications

The projection moire technique affords an accurate method of measuring the geometry of the necked region in a tensile specimen. Corrections to the measured stress, necessary to account for the triaxiality introduced by the neck, require values for the radius of curvature of the specimen at the minimum section. The spacing of fringes resulting from the interference between a grating projected on the specimen surface and a master grating not only provide information which permits calculation of the radius but also demonstrates any changes in symmetry resulting from plastic deformation. Results obtained by testing specimens of copper and mild steel …


Phaseautomodulation In Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig Jan 1982

Phaseautomodulation In Magnesium, Alexander Aning, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

No abstract provided.


Effects Of Varying Oxygen Partial Pressure On Molten Silicon-Ceramic Substrate Interactions, And Oxygen Partial Pressure Measurements Of Silicon Sheet Production Facilities, P. D. Ownby, Harold V. Romero Jan 1982

Effects Of Varying Oxygen Partial Pressure On Molten Silicon-Ceramic Substrate Interactions, And Oxygen Partial Pressure Measurements Of Silicon Sheet Production Facilities, P. D. Ownby, Harold V. Romero

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.


Measurement Of The Wear Properties Of Metallic Solids With A Falex Lubricant Testing Machine, Edward Boyd Hale, Chun-Ping John Meng, Ronald A. Kohser Jan 1982

Measurement Of The Wear Properties Of Metallic Solids With A Falex Lubricant Testing Machine, Edward Boyd Hale, Chun-Ping John Meng, Ronald A. Kohser

Physics Faculty Research & Creative Works

A modified Falex Lubricant Testing Machine has been used to determine wear properties of metallic solids. In particular, wear mass loss, wear volume loss, wear rates, and other parameters have been determined for a basic steel, as heat treated and after ion implantation. Wear rate improvements of more than an order of magnitude were found in a nickel-chrome steel (SAE 3135) implanted with 2.5x1017 N+2/cm2. Wear tests were conducted with a cylinder-in-groove geometry in a mild lubricating oil with loads greater than 540 N, which corresponded to pressures which exceeded 108N/m2 …


Glass Surfaces Then And Now, Norbert J. Kreidl Jan 1982

Glass Surfaces Then And Now, Norbert J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

A reservoir of efficient instrumentation capable of detailed and quantitative exploration of glass surface features is now available in the face of the recognition of their crucial importance for both surface and bulk properties as well as performance. Yet it may be instructive to glance at what had been learned about glass surfaces by investigators before the advent of these intricate tools. Among such earlier findings are the recognition of the altered composition and structure of the surface layer, the extension of this disturbance to considerable depth, the effect of surface structure on adsorption, adhesion, wetting, finishing, etc. and on …


Anomalous Diffusion Of Carbon In A 70/30 Iron-Nickel Alloy, L. R. Chapman, D. A. Powers, Manfred Wuttig Jan 1982

Anomalous Diffusion Of Carbon In A 70/30 Iron-Nickel Alloy, L. R. Chapman, D. A. Powers, Manfred Wuttig

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.


Seeded Oscillatory Growth Of Si Over Sio² By Cw Laser Irradiation, G.K. Celler, L. E. Trimble, K.K. Ng, H.J. Leamy, H. Baumgart Jan 1982

Seeded Oscillatory Growth Of Si Over Sio² By Cw Laser Irradiation, G.K. Celler, L. E. Trimble, K.K. Ng, H.J. Leamy, H. Baumgart

Electrical & Computer Engineering Faculty Publications

Extensive seeded epitaxial growth of crystalline Si over SiO2 was achieved by an oscillatory regrowth method applied to rectangular Si pads recessed into a thick SiO2 film. Narrow (≃5 μm) via holes linked the pads with the bulk (100) Si substrate. Oriented single crystals propagated as far as 500 μm from the seeding area, following the long term advance of a scanned focused laser beam.