Engineering Commons^™

Transport Of Water And Ions Through Single-Walled Armchair Carbon Nanotubes: A Molecular Dynamics Study, Michelle Patricia Aranha

Doctoral Dissertations

The narrow hydrophobic interior of a carbon nanotube (CNT) poses a barrier to the transport of water and ions, and yet, unexpectedly, numerous experimental and simulation studies have confirmed fast water transport rates comparable to those seen in biological aquaporin channels. These outstanding features of high water permeability and high solute rejection of even dissolved ions that would typically require a lot of energy for separation in commercial processes makes carbon nanotubes an exciting candidate for desalination membranes. Extending ion exclusion beyond simple mechanical sieving by the inclusion of electrostatics via added functionality to the nanotube bears promise to not …

Fabrication And Characterization Of Hybrid Energy Harvesting Microdevices, Zhongcheng Gong

Doctoral Dissertations

In this dissertation, a hybrid energy harvesting system based on a lead zirconate titanate (PZT) and carbon nanotube film (CNF) cantilever structure has been designed, fabricated and studied. It has the ability to harvest light and thermal radiation energy from ambient energy and convert them to electricity.

The proposed micro-scale energy harvesting device consists of a composite cantilever beam (SU-8/CNF/Pt/PZT/Pt) which is fixed on a silicon based anchor and two electrode pads for wire bonding. The CNF acts as an antenna to receive radiation energy and convert it to heat energy and then transfer to the whole cantilever structure. The …

Single-Walled Carbon Nanotube Device Fabrication Using Spin Coating Of Dispersions, Paul Jeremy Hummel

Doctoral Dissertations

This research looks at ways to utilize already synthesized carbon nanotubes (CNT) to manufacture electrical connections using current tools and fabrication methods employed in the semiconductor industry. Purchased single-walled carbon nanotubes (SWNT) are separated and placed in suspension using poly(sodium styrene sulfonate) (PSS). The PSS non-covalently bonds to the SWNTs, causing them to repel each other due to the negative charge of the PSS. The suspension of SWNTs is spin coated over a processed silicon (Si) wafer with fabricated trenches. A Si wafer with a top silicon dioxide (SiO 2) layer is spin coated with Shipley 1827 photoresist. UV light …