Engineering Commons^™

Tracking Perfluoroalkyl Substances From Wastewater Influent To Its Accumulation In Vegetables And Forage Grass, Simon Kozik

All Graduate Theses and Dissertations, Fall 2023 to Present

Per and poly-fluorinated alkyl substances (PFAS) are a class of chemicals that are persistent in the environment. PFAS was found in wastewater, which can be used after wastewater treatment for irrigation water, and in the biosolids that can be mixed with soils to provide nutrients and generally improve soil quality. This study found when wastewater was used it increases the level of PFAS in vegetables and forage grass. PFAS concentrations were tracked from the influent of the wastewater treatment plant to the effluent, to the irrigation water, to the soil, and finally into the vegetable and forage grass grown on …

Occurrence Of Per- And Polyfluoroalkyl Substances (Pfas) In New Hampshire Biosolids, Katherine A. Wieck

Honors Theses and Capstones

Per- and polyfluoroalkyl substances (PFAS) are a group of over 4,000 compounds used in the manufacturing of products including aqueous film forming foams for firefighting, stain repellents, waterproofing agents, and nonstick cookware since their initial development in the 1940s. The long fluorinated carbon chain structure of PFAS causes chemical and thermal stability, and thus resistance to biodegradation. Biosolids produced at wastewater facilities for uses such as agricultural land-applied compost and fertilizer for lawns and athletic fields, as well as sludge disposed in landfills can cause contamination of groundwater and surface water. This poses a significant threat to human and environmental …

Mechanisms Of Pathogen Inactivation In Wastewater And Pharmaceutical Applications, Christa L. Meingast

Dissertations, Master's Theses and Master's Reports

Infectious diseases are a significant threat to public health. Though society enacts practices to prevent the spread of these dangerous diseases, challenges remain. Therefore, continual advancements in treatment and prevention are required. Wastewater treatment and viral clearance in pharmaceutical applications are two key health measures that prevent the spread of infections.

A low-cost, low-technology biosolids treatment process was developed to improve wastewater treatment by collecting key information on storage temperature, ammonia, volatile solids, moisture content, pH, and pathogen inactivation in biosolids over long-term storage at two wastewater treatment plants located in northern climates of the United States. Inactivation of pathogens …

Kinetic Analysis Of Biosolid Pyrolysis, William Regan Kreutter

Master's Theses (2009 -)

Waste reduction and energy recovery have been an environmental focus. Many of these solutions involve the thermal degradation of waste, such as household garbage or organic waste. To help reduce the negative environmental impact associated with processes like incineration, methods have been developed to utilize the carbonaceous material and energy contained in waste. Wastewater treatment plants are responsible for collecting and cleaning billions of gallons of sewage and stormwater each year. The water collected goes through multiple cleaning stages before being discharged into surface water. Sewage sludge, commonly referred to as biosolids, are produced during the process. Biosolids are carbon …

A Preliminary Sustainability Analysis Of Producing Class A Biosolids With Conventional And Low-Cost, Low-Tech Processes, Janna Brown

Dissertations, Master's Theses and Master's Reports

Producing Class A biosolids is a beneficial way to reuse wastewater sludge. Low-cost, low-tech (LCLT) processes are attractive to small water resource recovery facilities (WRRF) because of their low capital costs and simple designs. This study examined the sustainability of conventional and LCLT processes at small WRRFs. The environmental impacts were determined by conducting life cycle assessments. Cost analyses determined the economic impacts. The social impacts were analyzed by investigating case studies and surveys of social response to biosolids. The environmental, economic, and social impacts were normalized, and each technology received an overall score. The technologies studied were direct heat …

Pathogen And Indicator Organism Inactivation And Quantification For Low-Cost Low-Tech Biosolids Treatment, Karina Eyre

Dissertations, Master's Theses and Master's Reports

Biosolids are a by-product of municipal wastewater treatment which, when treated to reduce pathogens, can be land applied as a fertilizer. Class A biosolids must contain low pathogen levels and are unrestricted in their use. This thesis describes methods to identify pathogen and indicator organism (PIO) inactivation mechanisms and PIO inactivation rates for use in low-cost low-tech Class A processes. Procedures to control the levels of spiked bacteria and viruses, total solids, volatile fatty acids, pH, and temperature in biosolids are described for their use in laboratory experiments. Methods for coliphage in biosolids as a surrogate for total enteric viruses …

Improved Methods For The Quantification Of Viable Ascaris Suum And Application To Biosolids, Tanner Keyzers

Dissertations, Master's Theses and Master's Reports

The current method for detection of Ascaris ova in biosolids and wastewater has several drawbacks including being labor and time intensive as well as being difficult to quantify viable ova that have larvated during treatment. The goal of this thesis was to improve several methods for the detection and quantification of Ascaris ova during long term-storage of biosolids including improvement of quantifying viable ova using a heat and bleach treatment to promote movement of larvae inside of ova, and comparison of the traditional microscopic method with qPCR and PMA-qPCR to prevent the false-positive results. Improved methods to promote movement of …

The Impact Of Phosphorous Species On Dewaterability Of Wastewater Solids, Erik Anderson

Master's Theses (2009 -)

Phosphorus regulations are causing Water Resource Recovery Facilities (WRRFs) to implement new technologies to remove phosphorus (P) before they discharge liquid effluent. Enhanced Biological Phosphorus Removal (EBPR) is often employed to remove P from water. However, sludges from EBPR plants have shown decreases in dewaterability soon after EBPR was initiated. This decline in dewaterability is not well understood, nor is the best way to improve the dewatering EBPR sludge. Specifically, the role of different P species on sludge dewaterability is not well understood. Several laboratory experiments were conducted at the Marquette University Water Quality Center with the following objectives: i) …

Biosolids-Derived Biochar For Micropollutant Removal From Wastewater, Lee Kimbell

Master's Theses (2009 -)

Trace organic compounds including antibiotics, hormones, pharmaceuticals and personal care products are discharged to the environment with liquid and solid effluent streams from water resource recovery facilities. These compounds are referred to as micropollutants, and can have negative impacts in receiving waters. Current wastewater treatment processes are not specifically designed to remove micropollutants, and many of these compounds are recalcitrant to conventional treatment technologies. Triclosan (TCS) was selected as a representative micropollutant in this study due to frequent detection in liquid effluents, residual biosolids, and surface waters. Pyrolysis - the thermochemical decomposition of organic matter at elevated temperatures in the …

Pilot-Scale Study Of Low-Tech Methods Of Sustainable Class A Biosolids Production: A Trial Run, Rebecca L. Green

Dissertations, Master's Theses and Master's Reports

Water resource recovery facilities can improve sustainability by producing Class A biosolids. However, many conventional methods for achieving Class A biosolids are expensive, with high maintenance and energy costs. However, low-cost, low-tech (LCLT) treatment methods are also available. The overall goal of the larger project of which this study was a part is to develop a rational and universal approach for design of LCLT processes. To achieve this goal, pilot-scale studies of LCLT processes will be performed. The goal of this portion of the project was to perform a trial run pilot-scale study. During the trial run, the pilot-scale biosolids …

Self-Sustaining Smouldering Combustion As A Novel Disposal Destruction Method For Waste Water Biosolids, Tarek L. Rashwan

Electronic Thesis and Dissertation Repository

Managing biosolids, the major by-product from wastewater treatment plants (WWTPs), persists as a major global challenge that often constitutes the majority of WWTP operating costs. Self-sustained smouldering is a new approach for organic waste treatment, in which the waste (i.e., the fuel) is destroyed in an energy efficient manner after mixing it with sand. Smouldering has never been applied to biosolids. Column experiments, using biosolids obtained from a WWTP, were employed to identify if - and under what conditions - smouldering could be used for treating biosolids. The parameter space in which smouldering was self-sustaining was mapped as a function …

Risk Characterization From Multipathway Exposure Associated With Land Applying Biosolids By Accounting For Multimedia Mass Loss, Karthik Kumarasamy

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

There continues to be concern among communities living in the vicinity of biosolids land application sites about potential adverse health effects from the chemical contaminants present in biosolids. This study describes a procedure that will help answer questions about the risks involved in biosolids land application at the site level, thus, this study will provide a crucial communication tool for wastewater treatment facilities and biosolids land appliers to address the concerns of the public. Specifically, the study quantifies the exposure concentrations that a human being can become exposed to during their lifetime from the practice. Crucially, it takes a quantitate …

Pyrolysis For Estrogens Removal From Wastewater Solids, Thomas C. Hoffman

Master's Theses (2009 -)

Wastewater treatment processes are not designed to remove estrogenic micropollutants and therefore when wastewater biosolids are land applied estrogenic micropollutants are discharged to the environment. Release of estrogenic compounds has deleterious effects on the terrestrial environment. Public concern stemming from micropollutants may reduce the value of biosolids which are important to water resource reclamation facilities (WRRF) as by-products. The objective of this research was to evaluate pyrolysis, the partial decomposition of organic material in an oxygen-deprived system under high temperatures, as a sustainable solution to remove estrogenic compounds from biosolids while producing a useable soil conditioner called biochar. Batch pyrolysis …

An Improved Biosolid Gasifier Model, Hannah Mclean

Electronic Theses and Dissertations

As populations increase and cities become denser, the production of waste, both sewage sludge and food biomass, increases exponentially while disposal options for these wastes are limited. Landfills have minimal space for biosolids; countries are now banning ocean disposal methods for fear of the negative environmental impacts. Agricultural application of biosolids cannot keep up with the production rates because of the accumulation of heavy metals in the soils. Gasification can convert biosolids into a renewable energy source that can reduce the amount of waste heading to the landfills and reduce our dependence on fossil fuels. A recently published chemical kinetic …

Fate Of Micropollutants During Pyrolysis Of Biosolids, John Ross

Master's Theses (2009 -)

Approximately 250 tons of organic micropollutants, including pharmaceuticals, antimicrobials, and hormones, are discharged to the environment during land application of wastewater biosolids annually. Reusing wastewater biosolids is vital to the sustainability of wastewater treatment, but current treatment processes do not remove micropollutants from biosolids in an efficient manner. Pyrolysis―the heating of biomass to temperatures between 400 and 800 °C under oxygen-free conditions―was proposed as a biosolids treatment process that could produce a beneficial soil amendment product, biochar, and remove micropollutants. The objective of this research was to determine the effect of pyrolysis temperature and residence time on the removal of …

Inactivation Of Ascaris In Double-Vault Urine-Diverting Composting Latrines In Panama: Methods And Environmental Health Engineering Field Applications, Daragh A. Gibson

USF Tampa Graduate Theses and Dissertations

The United Nations Millennium Development Goals have prioritized improving access to sanitation, but unfortunately about a third of the global population is still without an improved sanitation source and one billion still practice open defecation. Lack of access to adequate and safe sanitation means the proliferation of dangerous pathogens in the environment, especially soil-transmitted helminths (STHs). In the Bocas del Toro Province of Panama (and similar locations in the world), composting latrines have been built in many of the indigenous communities in the area. They are a form of dry or ecological sanitation and are designed to produce an end …

Fate Of Estrogens In Anaerobic Digestion And Their Removal In Advanced Oxidation, Shubhajit Sarkar

Electronic Thesis and Dissertation Repository

Estrogenic compounds are most significant endocrine disrupting compounds (EDC), which are of primary concern due to their widespread presence in the aqueous environment and also due to their adverse impact both on aquatic life and potential risk to human health. Conventional wastewater treatment plants are not designed to remove EDC, with biosorption on biosolids as the predominant removal mechanism. Anaerobic digestion is one of the most preferred processes employed for sludge stabilization in wastewater treatment plants. Advanced oxidation processes (AOPs) are seen as promising technologies for removal of estrogens from the environment. In this research, a controlled degradation study of …

Solid Waste Reduction Practices In The Southeastern United States: Public Perceptions And Proposed Policy Changes, Lauren Ashley Raup-Plummer

Masters Theses

The U.S. Environmental Protection Agency (EPA) has highlighted the municipal solid waste stream as an area of critical interest due to the non-sustainable nature of existing landfilling or “dumping” practices. In addition to traditionally defined municipal solid waste – commonly referred to as garbage or rubbish – materials such as biosolids, a by-product of wastewater treatment, and animal manure also comprise the landfilled waste stream. Currently, disposal options for biosolids waste materials are limited due to regulations imposed by the EPA to protect waterways and coastal environments, and one of the few alternatives for biosolids disposal is land application. Unfortunately, …

Sudden Increase And Regrowth Of Fecal Coliforms And Escherichia Coli In Wastewater Biosolids After High Solids Centrifugation, Gordon G. Araujo

Master’s Theses

Treatment plants that operate either thermophilic or mesophilic anaerobic digesters with centrifugal dewatering processes have consistently observed densities of fecal coliform and Escherichia coli, both indicator bacteria, that decrease during digestion but then increase after dewatering and storage. The increases have been characterized as two separate phenomena to explain this observation: 1) “Sudden Increase,” or SI, which is defined as the increase that occurs immediately after dewatering and 2) “regrowth,” which is defined as an increase during storage of cake samples over a period of hours or days. The SI observation appears to be more prevalent with biosolids that are …

Assessing Phosphorus-Transport From Biosolids Land Application Sites In Utah, Mohan K. Kumar

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Phosphorus Site Index (PSI) is a phosphorus transport assessment tool used to estimate the risk of P transport from soils. Various components, such as soil erosion, P fertilizer application rate, plant available P in soil, etc. that have an influence on P transport from a site, are weighted and given ratings, and a combination of these components are expressed as PSI. This study has considered two biosolids land application sites in Utah, which received biosolids amendments over time, to develop a specialized PSI for the state of Utah.

Phosphorus from land application of biosolids has been considered a potential risk …

Variation Of Geotechnical Strength Properties With Age Of Landfills Accepting Biosolids, Kishore Pinapati

Electronic Theses and Dissertations

The solid portion of waste disposal, known as Municipal Solid Waste (MSW) can be landfilled. Landfilling has proved to be a safe, sanitary and economical method of disposal. A by-product from wastewater treatment plants called biosolids is sometimes co-disposed along with MSW in landfills. Recent work at the University of Central Florida has focused on the behavior of the mixture of MSW and biosolids. As an increased amount of waste accumulates in these landfills, it creates a new problem – the geotechnical stability of landfills. In current literature, classical geotechnical testing methods have been followed to find the strength properties …

Dewatering Of Biosolids By Sodium Ferrate, Andrea Rios

Electronic Theses and Dissertations

This study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge after conditioning were used. For centrifugation the volume reduction and the turbidity of the supernatant after centrifugation were evaluated. For filtration, the Capillary Suction Time test was used. The optimum …

Slope Stability Analysis Of Class I Landfills With Co Disposal Of Bios, Mrutyunjay Vajirkar

Electronic Theses and Dissertations

Land filling provides a major, safe, and economical disposal route for biosolids and sludges. With an expanding world, the demand for larger and higher capacity landfills is rapidly increasing. Proper analysis and design on such fills have pushed the boundaries of geotechnical engineering practice, in terms of proper identification and assessment of strength and deformation characteristics of waste materials. The engineering properties of Municipal Solid Waste (MSW) with co-disposal of biosolids and sludges with regards to moisture characteristics and geotechnical stability are of utmost importance. Significant changes in the composition and characteristics of landfill may take place with the addition …