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Full-Text Articles in Engineering

Modeling And Performance Analysis Of Deb Based Hydrogen Getters, John A. Matteson Aug 2022

Modeling And Performance Analysis Of Deb Based Hydrogen Getters, John A. Matteson

Chemical and Biological Engineering ETDs

Hydrogen getter materials are used to irreversibly absorb hydrogen gas in sealed environments. The DEB based getter system, despite finding widespread use in this application, still posses challenges with respect to experimental performance analysis and fundamental understanding of reaction mechanism. The second chapter of this report addresses the experimental challenges of this getter system by demonstrating the utility and experimental strengths of a custom magnetic suspension balance (MSB) based gravimetric sorption system. This apparatus enables performance evaluation in process relevant conditions including dilute mixed gas environments which our results indicate is necessary for accurate performance evaluation of getter systems. Chapter …


Interfacial Interactions Of Uranium And Hdpe In Agricultural Soil And Their Bioacummulation In Mentha Arvensis, Casey Miller, Andrew Neidhart, Kendra Hess, Abdul-Mehdi S. Ali, Angelica Benavidez, Michael Spilde, Laura Green, José M. Cerrato, Jorge Gonzalez Estrella, Eliane El Hayek Jul 2022

Interfacial Interactions Of Uranium And Hdpe In Agricultural Soil And Their Bioacummulation In Mentha Arvensis, Casey Miller, Andrew Neidhart, Kendra Hess, Abdul-Mehdi S. Ali, Angelica Benavidez, Michael Spilde, Laura Green, José M. Cerrato, Jorge Gonzalez Estrella, Eliane El Hayek

Civil Engineering ETDs

We investigated the adsorption, precipitation, and phytoavailability of uranium after reactions with soil, high-density polyethylene particles, and Mentha arvensis through the integration of batch experiments, plant exposure, microscopy, and spectroscopy. Soluble U (initially 100 µM) decreased by 98.6% (1.09 µM) at pH 5 and 86.2% (13.81 µM) at pH 7.5 after 0.1 h of reaction with 10 g of soil in solution. Heterogenous U precipitates were observed in weathered HDPE surfaces for experiments without soil at both pH conditions. This suggests the weathering of the microplastic surfaces enhanced the nucleation of the U precipitates. Plants exposed to both U and …


Co-Occurrence Of Microplastics, Uranium And Arsenic In Heavy Metal-Contaminated Freshwaters And Their Potential Interaction, Jasmine Anne Quiambao Mar 2022

Co-Occurrence Of Microplastics, Uranium And Arsenic In Heavy Metal-Contaminated Freshwaters And Their Potential Interaction, Jasmine Anne Quiambao

Civil Engineering ETDs

This study identified microplastics and heavy metals in fields sites of freshwater systems in New Mexico and evaluated the interactions of arsenic (As) and uranium (U) with commercial microplastics for acidic and neutral pH in laboratory-controlled conditions. The potential interaction of microplastics with other contaminants is not well-established. Microplastics could interact with heavy metals in ecosystems with naturally elevated background concentrations of metals or affected by anthropogenic activities. Previous studies have found heavy metal contamination in freshwater systems in New Mexico near abandoned mine sites. The objective of this study is (1) to identify and characterize microplastics from metal contaminated …


Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca Jun 2017

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …