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2019

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Full-Text Articles in Engineering

Rhodococcus Opacus Pd630 Genetic Tool Development To Enable The Conversion Of Biomass, Drew Michael Delorenzo Dec 2019

Rhodococcus Opacus Pd630 Genetic Tool Development To Enable The Conversion Of Biomass, Drew Michael Delorenzo

McKelvey School of Engineering Theses & Dissertations

The discovery of fossil fuels facilitated a new era in human history and allowed many firsts, such as the mass production of goods, the ability to travel and communicate long distances, the formation of population dense cities, and unprecedented improvements in quality of life. Alternative sources of energy and chemicals are needed, however, as hydrocarbon reserves continue to deplete and the effects of burning fossils on the planet become better understood. Lignocellulosic biomass is the most abundant raw material in the world and a viable alternative to petroleum-derived products. The pre-treatment of lignocellulose (e.g., thermocatalytic depolymerization, enzymatic hydrolysis, pyrolysis, etc.) …


Instrumentation For Dynamic Nuclear Polarization And Application Of Electron Decoupling For Electron Relaxation Measurement, Nicholas Howard Alaniva Dec 2019

Instrumentation For Dynamic Nuclear Polarization And Application Of Electron Decoupling For Electron Relaxation Measurement, Nicholas Howard Alaniva

Arts & Sciences Electronic Theses and Dissertations

Dynamic nuclear polarization nuclear magnetic resonance (DNP NMR) exploits internal electron spin and nuclear spin interactions to increase sensitivity and uncover valuable information regarding structure and dynamics of a system. To manipulate these interactions, instrumentation is developed to combine high-power microwave and radiofrequency irradiation with the ability to spin samples at the magic angle (MAS) at temperatures from 90 K to 4.2 K. Electron decoupling uses frequency-modulated microwaves to mitigate the electron-nuclear dipolar interaction, improving signal intensity and resolution in DNP NMR experiments. Electron decoupling is combined with short DNP periods to encode electron spin information in polarized nuclear signal. …


Development Of High-Speed Photoacoustic Imaging Technology And Its Applications In Biomedical Research, Yun He Dec 2019

Development Of High-Speed Photoacoustic Imaging Technology And Its Applications In Biomedical Research, Yun He

McKelvey School of Engineering Theses & Dissertations

Photoacoustic (PA) tomography (PAT) is a novel imaging modality that combines the fine lateral resolution from optical imaging and the deep penetration from ultrasonic imaging, and provides rich optical-absorption–based images. PAT has been widely used in extracting structural and functional information from both ex vivo tissue samples to in vivo animals and humans with different length scales by imaging various endogenous and exogenous contrasts at the ultraviolet to infrared spectrum. For example, hemoglobin in red blood cells is of particular interest in PAT since it is one of the dominant absorbers in tissue at the visible wavelength.The main focus of …


Longitudinal Acoustic Traps: Design, Fabrication, And Evaluation For Biological Applications, Michael Moore Binkley Dec 2019

Longitudinal Acoustic Traps: Design, Fabrication, And Evaluation For Biological Applications, Michael Moore Binkley

McKelvey School of Engineering Theses & Dissertations

Acoustofluidics combine ultrasonic actuation with small-volume microfluidic channels to enable precise, contactless object manipulation for a range of applications from serial chemical processing to blood component separation and single-cell analysis. Micron- to millimeter-scale vibrational waves generate reproducible pressure fields within the microfluidic channels and chambers. By exploiting the material property mismatch between a particle (polymeric and silica beads, cells, etc.) and a suspending fluid, the acoustic radiation force is used to move particles toward regions of low (nodes) or high pressure (antinodes). An understanding of these field-particle interactions is applied to design and implement complicated channel architectures for preferential segregation …


Corrosion-Resistant Non-Carbon Electrocatalyst Supports For Proton Exchange Membrane Fuel Cells, Cheng He Dec 2019

Corrosion-Resistant Non-Carbon Electrocatalyst Supports For Proton Exchange Membrane Fuel Cells, Cheng He

McKelvey School of Engineering Theses & Dissertations

Proton exchange membrane fuel cells (PEMFCs) are a promising portable power source due to their low operating temperature, minimal pollutant generation and fast startup. However, several challenges remain concerning lifetime, reliability, and cost. A critical issue is PEMFC component durability. Platinum supported on high surface area carbon has been one of the most widely used electrocatalysts in PEMFCs. However, carbon corrosion over the course of normal PEMFC operation occurs due to the relatively low standard electrode potential for the carbon dioxide/carbon redox couple (0.207V vs. standard hydrogen electrode). Considering this challenge, it is imperative to identify alternative support materials to …


Kernel Methods For Graph-Structured Data Analysis, Zhen Zhang Dec 2019

Kernel Methods For Graph-Structured Data Analysis, Zhen Zhang

McKelvey School of Engineering Theses & Dissertations

Structured data modeled as graphs arise in many application domains, such as computer vision, bioinformatics, and sociology. In this dissertation, we focus on three important topics in graph-structured data analysis: graph comparison, graph embeddings, and graph matching, for all of which we propose effective algorithms by making use of kernel functions and the corresponding reproducing kernel Hilbert spaces.For the first topic, we develop effective graph kernels, named as "RetGK," for quantitatively measuring the similarities between graphs. Graph kernels, which are positive definite functions on graphs, are powerful similarity measures, in the sense that they make various kernel-based learning algorithms, for …


The Role Of Multi-Charged Responses: Construction And Application Of A Tandem Differential Mobility Analyzer (Tdma), Christopher Ray Oxford Dec 2019

The Role Of Multi-Charged Responses: Construction And Application Of A Tandem Differential Mobility Analyzer (Tdma), Christopher Ray Oxford

McKelvey School of Engineering Theses & Dissertations

Atmospheric aerosols impact health outcomes, visibility, and the energy balance of the earth. The atmosphere contains a variety of compounds, and the volatility (phase change enthalpy and vapor pressure) of each compound determines its partitioning between the gas phase and the particle phase. The hygroscopicity (an aerosol’s affinity for water) of an atmospheric aerosol particle is determined by the many compounds present in the particle, and thus, the volatility impacts hygroscopicity. Changes in hygroscopicity alter the fraction of the aerosol deposited in the lungs and the fraction of the aerosol activated into cloud droplets. Thus, understanding the volatility and hygroscopicity …


Dynamics And Control In Spiking Neural Networks, Fuqiang Huang Dec 2019

Dynamics And Control In Spiking Neural Networks, Fuqiang Huang

McKelvey School of Engineering Theses & Dissertations

In the brain, neurons (brain cells) produce electrical impulses, or spikes, that are thought to be the substrate of information processing and computation. Through enigmatic processes, these spikes are ultimately decoded into perceptions and actions. The nature of this encoding and decoding is one of the most pervasive questions in theoretical neuroscience. In other words, what are the specific functions enacted by neural circuits, through their biophysics and dynamics? This thesis examines the dynamics of neural networks from the perspective of control theory and engineering. The pivotal concept is that of the normative synthesis of neural circuits, wherein neural dynamics …


Finding A Viable Neural Network Architecture For Use With Upper Limb Prosthetics, Maxwell Lavin Dec 2019

Finding A Viable Neural Network Architecture For Use With Upper Limb Prosthetics, Maxwell Lavin

Master of Science in Computer Science Theses

This paper attempts to answer the question of if it’s possible to produce a simple, quick, and accurate neural network for the use in upper-limb prosthetics. Through the implementation of convolutional and artificial neural networks and feature extraction on electromyographic data different possible architectures are examined with regards to processing time, complexity, and accuracy. It is found that the most accurate architecture is a multi-entry categorical cross entropy convolutional neural network with 100% accuracy. The issue is that it is also the slowest method requiring 9 minutes to run. The next best method found was a single-entry binary cross entropy …


Ambient Temperature Dependence Of Air-Cooled Condenser Performance And Parameters, Alexander Darr Smith Dec 2019

Ambient Temperature Dependence Of Air-Cooled Condenser Performance And Parameters, Alexander Darr Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermoelectric power generation uses 38% of total fresh water withdrawals and majority of that water is used during steam condensation. Air-cooled condensers are an alternative to water-cooled condensers for power generation. Ambient air temperature affects the performance of air-cooled condensers. A small air-cooled condenser was run under the ambient air temperature extremes of Las Vegas in order to examine the system performance and air-side heat transfer parameters. Three different sets of tubes with different surface areas and geometries were studied. The condenser is equipped with several air velocity sensors, thermocouples and thermistors to measure the conditions to develop the air-side …


Meal Duration: Implications For Restaurant Revenue Management, Dale F. Billings Dec 2019

Meal Duration: Implications For Restaurant Revenue Management, Dale F. Billings

UNLV Theses, Dissertations, Professional Papers, and Capstones

A comprehensive revenue management strategy addressing space, product, price and time, has been shown to increase profits within the hospitality sector. While the literature shows that the restaurant industry has frequently addressed space, product, and price when looking at financial strategy, the effect of the variable of time on revenue generation has not been adequately studied. Restaurants shy away from the practice of using time as a commodity, particularly regarding meal duration, due to fears of reducing customer satisfaction.

This project explores the use of time as a commodity in restaurant revenue management. In particular, it examines consumers’ feelings about …


Performance Modeling Of Supercritical Carbon Dioxide Zigzag-Channel Printed Circuit Heat Exchangers, Katrine Birgitte Bennett Dec 2019

Performance Modeling Of Supercritical Carbon Dioxide Zigzag-Channel Printed Circuit Heat Exchangers, Katrine Birgitte Bennett

UNLV Theses, Dissertations, Professional Papers, and Capstones

Supercritical carbon dioxide (sCO2) is currently being studied as the working fluid in power producing Brayton cycles due to its excellent physical and thermodynamic properties, especially near the critical point. Printed circuit heat exchangers (PCHEs) are being considered for use as condensers and recuperators for this purpose due to their high strength and compact designs. Many experimental and numerical studies are being conducted to characterize and optimize sCO2 PCHE operation and develop correlations to describe their thermal-hydraulic performance. Additionally, a few experimental and numerical structural assessments of these PCHEs have been conducted, but all have been somewhat limited due to …


Galena Creek Bridge Structural Health Monitoring Instrumentation And Modeling, Leopold Falkensammer Dec 2019

Galena Creek Bridge Structural Health Monitoring Instrumentation And Modeling, Leopold Falkensammer

UNLV Theses, Dissertations, Professional Papers, and Capstones

Structural health monitoring (SHM) of an instrumented structure provides numerous benefits when assessing the long-term condition of the structure against degradation, or the short-term condition after an extreme event, such as an earthquake. The Nevada Department of Transportation (NDOT) has an interest in expanding the use of SHM for such assessments. Accordingly, the objective of the current study is to develop and implement a permanent SHM system for the Galena Creek Bridge, the largest concrete cathedral arch bridge in the world, to monitor its response to routine traffic and seismic activity. Completed in 2012, the bridge connects Reno and Carson …


Examining The Effectiveness Of A 4d Schedule And A Virtual Reality Model On A Modular Project: Unlv Solar Decathlon Case, Rajarshi Ghimire Dec 2019

Examining The Effectiveness Of A 4d Schedule And A Virtual Reality Model On A Modular Project: Unlv Solar Decathlon Case, Rajarshi Ghimire

UNLV Theses, Dissertations, Professional Papers, and Capstones

The use of a 4D schedule as technological advancement has brought significant improvement to the planning and execution of construction projects, through visualizing stepwise construction progress, following a sequence of pre-planned activities, and finalizing a baseline schedule with necessary changes. Moreover, the application of virtual reality (VR) to create interactive 3D models of a planned structure has made it possible to make a detailed planning of any construction project. Because of these benefits, the use of 4D schedules and VR in the construction industry has increased drastically, leading to improved planning and execution. However, past studies have given little attention …


Alkali-Silica Reactivity Of Mortars Containing Natural Pozzolan, Arash Kian Dec 2019

Alkali-Silica Reactivity Of Mortars Containing Natural Pozzolan, Arash Kian

UNLV Theses, Dissertations, Professional Papers, and Capstones

Alkali-silica reactivity is one of the most recognized deleterious phenomena in Portland cement concrete resulting in cracks, spalling, and other deleterious mechanisms.

The aim of this study was (i) to assess the extent of reactivity of the aggregates, quarried from seven different sources, suspected of being conducive to ASR, and (ii) to compare the effectiveness of industrial (Class F fly ash) and natural pozzolans in mitigation of alkali-silica reactivity of the studied aggregates. To this end, seven aggregate sources, four natural pozzolan sources, and one source of Class F fly ash were used. ASTM Type V Portland cement was replaced …


Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier Dec 2019

Utility Of Bench Scale Sand Tank Experiments At Assessing Permeable Reactive Barrier Design, Brandon Meier

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of this work was to evaluate the utility of bench scale sand tank experiments at assessing permeable reactive barrier (PRB) design. Our criteria for meeting this goal was that differences between PRB designs could be identified solely by measuring concentration in outflow from the sand tank models. For our PRB designs (funnel-and-gate, staggered wells, and parallel bars), numerical simulations clearly showed that PRB design had a quantifiable effect on outflow concentration, provided that the solute reacted with the PRB materials. Conversely, use of a conservative (non-reactive) solute did not allow us to discern between PRB design alternatives. Employing …


Development Of Natural Perlite Based Concrete For Sustainable Construction, Seyedmahmoud Motaharikarein Dec 2019

Development Of Natural Perlite Based Concrete For Sustainable Construction, Seyedmahmoud Motaharikarein

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study aimed to partially replace Portland Cement (PC) with environmentally friendly binders capable of improving the longevity of concrete. The new binders consisted of different proportions of natural pozzolan (perlite) with various fineness and particle size distributions. A step-by-step research program was designed to: (1) discover the optimum fineness of perlite powder and its optimum replacement level with cement; (2) investigate the rheological properties of the perlite-containing mixtures, and examine whether this binder can be used in selfconsolidating concrete; and (3) assess the weaknesses of the new binder, and improve its deficiencies by using nanomaterials such as nano-silica. The …


Design Of Efficient Carbon-Based Adsorbents For The Removal Of Organic And Inorganic Water Contaminants, Sayedeh Soroosh Mortazavian Dehkordi Dec 2019

Design Of Efficient Carbon-Based Adsorbents For The Removal Of Organic And Inorganic Water Contaminants, Sayedeh Soroosh Mortazavian Dehkordi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Granular activated carbon (AC) and biochar (BC) are two carbon-based adsorbents commonly used for water and wastewater treatment. However, these adsorbents have drawbacks that suppress their aqueous contaminants removal efficiency. Their major disadvantages are that AC has low selectivity and reusability potential, and BC has a hydrophobic nature.

The scope of this dissertation is to enhance the performance of commonly-used carbon-based adsorbents for the removal of organic and inorganic water contaminants and to understand the interactive mechanism of contaminants’ ions/molecules with adsorbents. Hexavalent chromium (Cr(VI)) and trichloroethylene (TCE) are two types of inorganic and organic water contaminants, respectively, which are …


Sizing A New Bike Sharing System For The University Of Nevada, Las Vegas, Nesley Orochena Dec 2019

Sizing A New Bike Sharing System For The University Of Nevada, Las Vegas, Nesley Orochena

UNLV Theses, Dissertations, Professional Papers, and Capstones

The strategic planning objectives for a novel Bike Sharing Systems (BSS) are to locate the BSS stations, size the stations, and determine the bicycle fleet size, among others. Current guidelines to design BSS programs are tailored to city centers with large coverage areas and high bicycle to population ratios, and thus not directly transferable to a university setting. An ordered probit model was created using data from a university online stated preference survey to determine the key factors that affect the uptake rates for the UNLV BSS program and to estimate the potential demand. The demand analysis was incorporated into …


Impact Of Design Cost Percentage On Cost Growth, Schedule Growth, And Construction Intensity Of Road Construction Projects, Elina Prajapati Dec 2019

Impact Of Design Cost Percentage On Cost Growth, Schedule Growth, And Construction Intensity Of Road Construction Projects, Elina Prajapati

UNLV Theses, Dissertations, Professional Papers, and Capstones

The performance of construction projects is measured in terms of cost and schedule variation. Studies have identified that such variations are mainly due to design changes, which are more frequent on projects executed through the design-bid-build (DBB) delivery method. Thus, the design factor is identified as one of the major parameters affecting the performance of DBB projects. Despite the majority of road projects being constructed following the DBB method, the impact of design cost on the performance of road projects has not been sufficiently studied yet. Therefore, this study focuses on determining the effect of design cost on the performance …


Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke Dec 2019

Carbon Management And Volatile Fatty Acid Production In Primary Clarifiers At A Wastewater Treatment Plant, Brittany Nicole Radke

UNLV Theses, Dissertations, Professional Papers, and Capstones

An increasing number of treatment plants are required to remove nutrients from domestic wastewater to lessen the impact of nutrient loading to water bodies. Enhanced Biological Phosphorus Removal (EBPR) is one of the processes commonly used to remove phosphorus from domestic wastewater. The presence of an adequate quantity of volatile fatty acids (VFA) in the wastewater influent to EBPR is important for process efficiency and stability. The objective of this research was to investigate the production of VFAs through fermentation of sludge in primary clarifiers as it related to improving nutrient removal, primarily targeting phosphorus.

The research tested, in full-scale, …


Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani Dec 2019

Application Of Data-Driven And Process-Based Modeling Approaches For Water Quality Simulation In Lakes And Freshwater Reservoirs, Ali Saber Sichani

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lakes and freshwater reservoirs often serve as the primary drinking and irrigation water sources for surrounding communities. They provide recreational and tourism opportunities, thereby promoting the prosperity of neighboring communities. Reliable estimates of water quality in lakes and reservoirs can improve management practices to protect water resources.

Seasonal water temperature and solar shortwave radiation variations, and their subsequent interactions with water column aquatic life, combined with seasonal variations of mixing intensity throughout the water column, result in variations of water quality constituents with depth during the annual cycle. The complexity of these variations entails the use of advanced water quality …


Cfd Simulation Investigating The Effects Of Groove Geometry On Heat Transfer For Internally Grooved Tubes, Richard Zaven Saroukhanoff Dec 2019

Cfd Simulation Investigating The Effects Of Groove Geometry On Heat Transfer For Internally Grooved Tubes, Richard Zaven Saroukhanoff

UNLV Theses, Dissertations, Professional Papers, and Capstones

This numerical study investigates the thermal performance of internally grooved tubes used in heat exchangers. In order to enhance the performance of heat exchangers, turbulence promoters are inserted along the streamwise flow. The use of inserts, grooves, and augmentations along the axial length of the tube creates disturbances that improve the overall heat transfer due to enhanced fluid mixing and greater surface contact boundary walls. However, the implementation of tube wall augmentations creates an increase in pressure drop across the tube which must be compensated for with additional pumping power for the working fluid. Therefore, in order to analyze the …


Neural Network In Hardware, Jiong Si Dec 2019

Neural Network In Hardware, Jiong Si

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation describes the implementation of several neural networks built on a field programmable gate array (FPGA) and used to recognize a handwritten digit dataset – the Modified National Institute of Standards and Technology (MNIST) database. A novel hardwarefriendly activation function called the dynamic ReLU (D-ReLU) function is proposed. This activation function can decrease chip area and power of neural networks when compared to traditional activation functions at no cost to prediction accuracy.

The implementations of three neural networks on FPGA are presented: 2-layer online training fully-connected neural network, 3-layer offline training fully-connected neural network, and two solutions of Super-Skinny …


Pressure Driven Electronic Band Gap Engineering In Tin(Iv)-O,N Compounds, Daniel Thomas Sneed Dec 2019

Pressure Driven Electronic Band Gap Engineering In Tin(Iv)-O,N Compounds, Daniel Thomas Sneed

UNLV Theses, Dissertations, Professional Papers, and Capstones

The intrinsic link between long-range order, coordination geometry, and the electronic properties of a system must be understood in order to tailor function-specific materials. Although material properties are typically tailored using chemical dopants, such methods can cause irreversible changes to the structure, limiting the range of functionality. The application of high pressure may provide an alternative “clean” method to tune the electronic properties of semiconducting materials by tailoring their defect density and structure.

We have explored a number of optoelectronic relevant materials with promising characteristics, specifically Sn-(O,N) compounds which have been predicted to undergo pressure-mediated opening of their optical band …


High-Speed Radhard Mega-Pixel Cis Camera For High-Energy Physics, Wenlan Wu Dec 2019

High-Speed Radhard Mega-Pixel Cis Camera For High-Energy Physics, Wenlan Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation describes the schematic design, physical layout implementation, system-level hardware with FPGA firmware design, and testing of a camera-on-a-chip with a novel high-speed CMOS image sensor (CIS) architecture developed for a mega-pixel array. The novel features of the design include an innovative quadruple column-parallel readout (QCPRO) scheme with rolling shutter that increases pixel rate, its ability to program the frame rate and to tolerate Total Ionizing Dose effects (TID). Two versions of the architecture, a small (128 x 1,024 pixels) and large (768 x 1,024 pixels) version were designed and fabricated with a custom layout that does not include …


Treatment Of Perchlorate And Multiple Oxyanions: Chemical And Biological Investigations, Mark Elkouz Dec 2019

Treatment Of Perchlorate And Multiple Oxyanions: Chemical And Biological Investigations, Mark Elkouz

UNLV Theses, Dissertations, Professional Papers, and Capstones

Groundwater contamination with oxyanions is an issue that must be addressed for environmental, ecological and societal reasons. Chemical and biological treatment methods of reduction are already known and practiced, but the simultaneous presence of multiple oxyanions can add complicating effects to treatment sequence and efficacy. This research was concerned with the investigation of the chemical reductive treatment of Cr(VI) using both calcium polysulfide (CaSx) and ferrous sulfate (FeSO4), and the biological reductive treatment of chlorate, Cr(VI), nitrate and perchlorate using multiple organic substrates. The chemical treatment phase consisted of initial jar tests, using CaSx and FeSO4, followed by a laboratory …


A Highly-Sensitive Global-Shutter Cmos Image Sensor With On-Chip Memory For Hundreds Of Kilo-Frames Per Second Scientific Experiments, Konstantinos Moutafis Dec 2019

A Highly-Sensitive Global-Shutter Cmos Image Sensor With On-Chip Memory For Hundreds Of Kilo-Frames Per Second Scientific Experiments, Konstantinos Moutafis

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this work, a highly-sensitive global-shutter CMOS image sensor with on-chip memory that can capture up to 16 frames at speeds higher than 200kfps is presented. The sensor fabricated and tested is a 100 x 100 pixel sensor, and was designed to be expandable to a 1000 x 1000 pixel sensor using the same building blocks and similar architecture.

The heart of the sensor is the pixel. The pixel consists of 11 transistors (11T) and 2 MOSFET capacitors. A 6T front-end is followed by a Correlated Double Sampling (CDS) circuitry that includes 2 capacitors and a reset switch. The 4T …


On Action Quality Assessment, Paritosh Parmar Dec 2019

On Action Quality Assessment, Paritosh Parmar

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this dissertation, we tackle the task of quantifying the quality of actions, i.e., how well an

action was performed using computer vision. Existing methods used human body pose-based features to express the quality contained in an action sample. Human body pose estimation in actions such as sports actions, like diving and gymnastic vault, is particularly challenging, since the athletes undergo convoluted transformations while performing their routines. Moreover, pose-based features do not take into account visual cues such as water splash in diving. Visual cues are taken into account by human judges. In our first work, we show that using …


Evaluation Of Titanosilicate Materials For The Sorption Of Cesium And Strontium From High Level Wastes, Matheus Tolentino Lauar Dec 2019

Evaluation Of Titanosilicate Materials For The Sorption Of Cesium And Strontium From High Level Wastes, Matheus Tolentino Lauar

UNLV Theses, Dissertations, Professional Papers, and Capstones

Treatment of high-level waste (HLW) stored in the U.S. Department of Energy (U.S. DOE) sites of Hanford and Savannah River involves the separation of radioactive cesium (137Cs) and strontium (90Sr). Challenges in treating the liquid HLW includes high alkalinity or acidity, and high salt content, many orders of magnitude above Cs and Sr concentrations. Ion exchange is the preferred process for removing these compounds, due to the availability of selective media and large volume-processing capacity by column operations. The crystalline silicotitanate (Na2Ti2O3SiO4·2H2O), i.e. CST, which structure is analog to the mineral sitinakite, is considered the reference material for this application. …