Engineering Commons^™

Fabrication, Testing And Analysis Of A Fatigue Sensor For Structural Health Monitoring, Subash Gokanakonda

Dissertations

A novel fatigue monitoring sensor (FMS) is designed, fabricated and tested for detecting and monitoring the fatigue damage and estimating the remaining life of structures and components subjected to cyclic loads. The concept is based on the characteristics of stress / strain life cycle relationship of engineering materials. Sensor consists of alternate slots and strips having different strain magnification factor with respect to the nominal strain. The sensor is designed in such a way that the strips will experience the strain which closely resemble the actual strain distribution in the notch or critical area of the component. The sensor can …

Printing Functional Electronic Circuits And Components, Ahmed Tausif Aijazi

Dissertations

The purpose of this study was to investigate the challenges in printing reliable multilayer flexible circuits, devices and components. Gravure was used as the primary printing process for this work, but due to some limitations of gravure, other printing methods were also investigated. At first a systematic study was done to determine the optimum parameters for the gravure printing of sub 50 micron lines. Commercially available silver nanoparticle inks were printed on a lab scale gravure printer, Accupress®. The highest resolution line that was electrically conductive was 36μm wide. The 9μm, 18μm and 27μm lines were printed but were not …

Lntegration Of Conventional Lithography And Printing Processes As A Key Enabling Technology For Printed And Flexible Sensing Systems, Binu Baby Narakathu

Dissertations

Sensors, which are used ubiquitously in a wide variety of applications, are revolutionizing the already ever-changing world we live in by providing real-time information about our surroundings. This dissertation focuses on the integration of conventional photolithography and printing processes as a key enabling technology for printed and flexible sensing systems.

Initially, an efficient opto-electrochemical sensing system, for the dual detection of heavy metal compounds was successfully developed. A novel microfluidic flow cell, with a reservoir volume of 25 μl, was designed and fabricated using acrylic. An electrochemical sensor with gold (Au) interdigitated electrodes (IDE) on a glass substrate was photolithographically …

Utilization Of Aqueous Raft Prepared Copolymers To Improve Anticancer Drug Efficacy, Andrew Christopher Holley

Dissertations

The advent of controlled radical polymerization (CRP) techniques, along with advancements in facile conjugation chemistry, now allow synthetic tailoring of precise, polymeric architectures necessary for drug/gene delivery. Reversible addition- fragmentation chain transfer (RAFT) polymerization and its aqueous counterpart (aRAFT) afford quantitative control over key synthetic parameters including block length, microstructure, and placement of structo-pendent and structo-terminal functionality for conjugation of active agents and targeting moieties. The relevance of water-soluble and amphiphilic (co)polymers synthesized by RAFT for in vitro delivery of therapeutics in biological fluids is an especially attractive feature. In many cases, polymerization, binding, conjugation, …

Development Of Workforce Skills: Student Perceptions Of Mentoring In First Robotics, Katie Joan Veal Wallace

Dissertations

In today’s global economy, new workforce competencies are needed for success at both individual and societal levels. The new workforce skills extend beyond basic reading, writing, and arithmetic to include higher order processes such as critical thinking and problem solving. Technical job opportunities have grown by approximately 17%, yet the United States continues to decline in science, technology, engineering and mathematics (STEM) disciplines. Further, U.S. students earn average or below average test scores when compared to other developed countries. Researchers cite the need to incorporate the learning of workplace skills into secondary education curriculum, and advocates call for new teaching …

Evaluation Of Environmental Materials As Thermal Witness Materials, Shashank Vummidi Lakshman

Dissertations

New and complex energetic materials are under development for achieving tunable pyrotechnical events for applications such as neutralization of biological weapons, bunker busters and many others. To guide the development of hybrid materials, the pyrotechnical environment they produce requires higher degree of characterization i.e. good description of spatial and temporal temperature distribution.

Temperature measurements in pyrotechnical events are especially challenging, where the temperature of the environment rises more than 2000 K on microseconds to few milliseconds time scale. These environments produce high thermal stress where traditional sensors like thermocouples, optical pyrometers struggle to describe the dynamic changes in the environment. …

Synthesis And Characterization Of Metal-Based Reactive Powders, Yasmine Aly

Dissertations

Aluminum added to propellants, explosives, and pyrotechnics, boosts their energy density. Different approaches were investigated that could shorten aluminum ignition delays, increase combustion rates, and decrease the tendency of aluminum droplets to agglomerate. Here, Al-based reactive, mechanically milled materials are prepared and characterized.

For powders with Fe, Ni, or Zn additives, the particles consist of an aluminum matrix and inclusions of Fe, Ni, or Zn comprising 10 at % of the bulk composition. For additives of Ni and Zn, only short milling times can be used to prepare composites; intermetallic phases form at longer milling times. Thermogravimetric analysis shows selective …

Novel Scrubbing Systems For Post-Combustion Co2 Capture And Recovery, Tripura Mulukutla

Dissertations

Power plant emissions of flue gas releases considerable CO₂ to the atmosphere; CO₂ is considered to be the main contributor to global warming. Several gas absorption techniques are being investigated to reduce the capital and operating costs for CO₂ capture from post-combustion flue gas. Conventional method of CO₂ capture by an aqueous solution of monoethanolamine (MEA) and its subsequent stripping in a separate tower with steam at 120°C, is a highly energy intensive process. The low partial pressure of CO₂ in the flue gas inhibits the application of CO₂-selective membranes unless methods are …

Ignition Mechanism In Nanocomposites Thermites, Rayon Williams

Dissertations

Nanocomposite thermites (n-thermites) have been actively investigated for a wide range of potential applications including propellants, explosives, and pyrotechnics. There have been several recent efforts aimed at understanding ignition mechanisms of nanocomposite reactive materials. Although significant progress has been made, ignition mechanisms remain elusive. At the same time, a robust ignition model is required to incorporate these materials in practical energetic formulations. A challenge of this effort is to describe the mechanisms of ignition of n-thermites prepared by Arrested Reactive Milling (ARM) with different stimuli, including heat, spark and impact and also develop a multi-step kinetic model describing different processes …

Fundamental Investigations Of Clay/Polymer Nanocomposites And Applications In Co-Extruded Microlayered Systems, Jeremy John Decker

Dissertations

The second and fourth generations of hydroxylated dendritic polyesters (HBP2, HBP4) were combined with unmodified sodium montmorillonite clay (Na+MMT) in water to generate a broad range of polymer clay nanocomposites from 0 to 100% wt/wt Na+MMT. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were used to investigate intercalation states of the clay galleries. It was shown that interlayer spacings were independent of generation number and changed over the composition range from 0.5 nm to 3.5 nm in 0.5 nm increments that corresponded to a flattened HBP conformation within the clay tactoids.

The HBP4/Na+MMT systems were investigated to study the …

Modeling That Leads To The Prediction Of Photocatalytic Coatings Characterization, Biju Bajracharya

Dissertations

One of the abundant sources of energy on earth is a solar energy which is the clean and safest energy source. It is also known as universal energy, the most important source of renewable energy available today. On realizing that the light source has a crucial role in daily life, several scientists and researchers from centuries ago have studied to establish photo induced systems and utilized them. Long after the knowledge of thermal energy, photovoltaic energy, and photosynthesis in plants, two prominent scientists, Fujishima and Honda, have discovered the electrochemical photolysis of water with the Titanium dioxide electrode which was …

Fluorine Containing Uv-Curable Materials For Advanced Transport Applications, James Thomas Goetz

Dissertations

The characterization of structure, thermal, gas transport, and free volume properties of two unique UV cured polymeric systems are studied and reported. In the initial pursuit of waterproof high water vapor transport membranes, it became apparent that the UV curing of fluorinated materials yielded routes to develop unique materials that fundamentally challenge conventional models for free volume and light gas transport behavior. UV-curing provides a means to rapidly “lock-in” morphologies that are accessible in the small molecule, monomer phase but rapidly become kinetically inaccessible when constraints such as covalent bonding and cross linking limit motion in the polymer system. This …

Development And Applications Of The Expanded Equivalent Fluid Method, Bharath Kumar Kandula

Dissertations

Ocean acoustics is the study of sound in the oceans. Electromagnetic waves attenuate rapidly in the water medium. Sound is the best means to transmit information underwater. Computational numerical simulations play an important role in ocean acoustics. Simulations of acoustic propagation in the oceans are challenging due to the complexities involved in the ocean environment. Different methods have been developed to simulate underwater sound propagation. The Parabolic-Equation (PE) method is the best choice in several ocean acoustic problems. In shallow water acoustic experiments, sound loses some of its energy when it interacts with the bottom. An equivalent fluid technique was …

Improved Efficiency Organic Photovoltaic Cells Through Morphology Control And Process Modification, Qi Wu

Dissertations

Organic photovoltaic (OPV) cells have drawn great attention due to the potential to produce flexible, light weight, affordable solar cells using polymer organic photovoltaic materials; however, the current power conversion efficiency achieved for these systems is too low for widespread implementation of the technology. Morphology and phase separation are key factors determining the performance of organic photovoltaic cells. Precise control of the size and distribution of the phase-separated photoactive domains is necessary for optimum photon-electron conversion. Polyhedral oligomeric silsesquioxane (POSS) nanostructered chemicals have the potential to provide enhanced control of morphology, crystallinity, and phase dispersion in polymeric blend systems. In …

Integrating 3d Layered Manufacturing With Photonic Sintering, Precision Machining And Smart Coating Techniques For Rapid Casting Applications, Hemant Bohra

Dissertations

Developments in rapid casting technologies have led to a new era of inclusion of 3D printing. Three-Dimensional (3D) printing provides the flexibility and ease of reproducing a sand mold directly from CAD models, eliminating patterning steps, thus reducing the process time for creating prototypes. In addition to minimizing processing steps, 3D printing provides the advantages of higher precision and the ability to produce complex shaped sand molds, but it simultaneously possesses some limitations and concerns related to throughput, safety and logistics.

This study proposes an alternative method for creating sand molds by introducing a hybrid rapid prototyping approach to overcome …

Pbs Quantum Dot-Based Hetrojunction Solar Cells, Sawsan Khader Dagher

Dissertations

This study investigates the influence of nanoparticles (NPs) size on their optical properties, and the effect of combination of lead sulfide (PbS) quantum dots (QDs), with n-type and p-type NPs, on the photogenerated charge carriers transport across the heterojunction solar cell structure. PbS QDs, of a range of sizes, were synthesized using a co-precipitation process. In this study, p-type NPs, which are poly [3,4-ethylenedioxythiophene] –poly [styrenesulfonate] (PEDOT: PSS), copper oxide (CuO) and graphene oxide (GO); and n-type NPs which are zinc oxide (ZnO), titanium dioxide (TiO2), cadmium sulfide (CdS) and bismuth sulfide (Bi2S3), were synthesized and characterized by SEM and …

Hydrodynamic Evaluation Of Climate Change And The Effects Of Coastal Effluent On The Long-Term Circulation Ofthe Arabian Gulf And Its Impact On Desalination, Abubaker Awad Elhakeem

Dissertations

The prime objectives of this dissertation are to develop, validate, and use a state of the art 30 Hydrodynamic Model (HD) to evaluate the long-term salinity and seawater temperature variations in the Gulf subject to climate change and coastal effluent; and to develop a Quantification tool that can assess the impact of projected ambient conditions upon the cost of desalination. Both objectives were realized.

Evaluating the long-term variability of seawater salinity and temperature due to climate change and coastal effluent is a growing concern. It may represent an economic and operational limiting factor in the desalination process given the clear …

Opportunistic Service Differentiation And Cloud Resource Management In Support Of Enhanced Vehicular Applications, Mohammad Ali Salahuddin

Dissertations

An integral part of Intelligent Transportation Systems (ITS) are Vehicular Ad hoc Networks (VANETs), which consist of vehicles with on-board units (OBUs) and fixed road-side units (RSUs). Wireless Access in Vehicular Environment (WAVE) offers QoS via service differentiation by using application defined priorities. However, WAVE has unbounded delay and is oblivious to network load and severity of vehicles with respect to their environment. Our context severity metric innovatively enhances WAVE to be sensitive to vehicle and environment interactions. Our novel Opportunistic Service Differentiation (OSD) technique, dynamically readjusts the WAVE packet priorities to improve utilization of lower latency queues, prioritizing packets …

Gas-Solid Transport And Reaction Via Intervened Evaporating Sprays, Pengfei He

Dissertations

Fluid catalytic cracking (FCC) is a major process used for converting heavy oils to transportation fuels and light olefins. The gas-solid transport with reaction via intervened evaporating sprays in the FCC riser is specially important but complicated, with coupled mechanisms of chemical reaction and heat, momentum and mass transfer among multiple phases (liquid, solid and gas) in the restriction of wall boundary. Recent developments in FCC process models have progressed along two lines. One aims to develop composition-based kinetic models derived from molecular characterization of petroleum fractions while overlooking the hydrodynamic effect on local catalyst to oil ratio (CTO). The …

Kinetic Analysis Of Thiol Oxidation To Study The Effects Of Fluorinated Groups On Metal Phthalocyanine Catalysts, Nellone Eze Reid

Dissertations

The oxidation of thiol (RSH) to disulfide (RSSR) is important biologically and industrially. Corrosive and malodorous thiols exist as contaminants in wastewater discharge from mining facilities, pulp and paper mills, tanneries, and oil refineries. The elimination of thiols from petroleum products is necessary for even cleaner fuels. Thiols in gas products can also inhibit catalyst activity for some downstream processes.

Experiments and mechanistic kinetic studies were conducted for the aerobic oxidation of 2-mercaptoethanol (2-ME) and 4-fluorobenzenethiol (4-FBT) catalyzed by cobalt phthalocyanines: H₁₆PcCo, F₁₆PcCo, and F₆₄PcCo, each exhibiting a metal center subject to increasing Lewis …

Global Optimization Methods For Localization In Compressive Sensing, Marco Rossi

Dissertations

The dissertation discusses compressive sensing and its applications to localization in multiple-input multiple-output (MIMO) radars. Compressive sensing is a paradigm at the intersection between signal processing and optimization. It advocates the sensing of “sparse” signals (i.e., represented using just a few terms from a basis expansion) by using a sampling rate much lower than that required by the Nyquist-Shannon sampling theorem (i.e., twice the highest frequency present in the signal of interest). Low-rate sampling reduces implementation’s constraints and translates into cost savings due to fewer measurements required. This is particularly true in localization applications when the number of measurements is …

Optimization Of Vehicle Routing And Scheduling With Travel Time Variability - Application In Winter Road Maintenance, Haifeng Yu

Dissertations

This study developed a mathematical model for optimizing vehicle routing and scheduling, which can be used to collect travel time information, and also to perform winter road maintenance operations (e.g., salting, plowing). The objective of this research was to minimize the total vehicle travel time to complete a given set of service tasks, subject to resource constraints (e.g., truck capacity, fleet size) and operational constraints (e.g., service time windows, service time limit).

The nature of the problem is to design vehicle routes and schedules to perform the required service on predetermined road segments, which can be interpreted as an arc …

Characterizing Motor Control Signals In The Spinal Cord, Yi Guo

Dissertations

The main goal of this project is to develop a rodent model to study the central command signals generated in the brain and spinal cord for the control of motor function in the forearms. The nature of the central command signal has been debated for many decades with only limited progress. This thesis presents a project that investigated this problem using novel techniques. Rats are instrumented to record the control signals in their spinal cord while they are performing lever press task they are trained in. A haptic interface and wireless neural data amplifier system simultaneously collects dynamic and neural …

Congestion Control, Energy Efficiency And Virtual Machine Placement For Data Centers, Yan Zhang

Dissertations

Data centers, facilities with communications network equipment and servers for data processing and/or storage, are prevalent and essential to provide a myriad of services and applications for various private, non-profit, and government systems, and they also form the foundation of cloud computing, which is transforming the technological landscape of the Internet. With rapid deployment of modern high-speed low-latency large-scale data centers, many issues have emerged in data centers, such as data center architecture design, congestion control, energy efficiency, virtual machine placement, and load balancing.

The objective of this thesis is multi-fold. First, an enhanced Quantized Congestion Notification (QCN) congestion notification …

Physical Controls On Water Flow And Solute Transport In Coastal Aquifers, Xiaolong Geng

Dissertations

Groundwater flow and associated subsurface solute fates have a significant impact on the structure and productivity of near-shore coastal ecosystems. For proper assessment and management of these coastal groundwater resources, it is quite essential to investigate the key factors (tides, waves, evaporation, and freshwater recharge etc.) affecting coastal groundwater systems. The main objective of this study is to examine and quantify two important physical control factors, oceanic waves and evaporation, on the groundwater flow and solute transport in near-shore aquifers. For the investigation of wave effects, a Computational Fluid Dynamics (CFD) modeling tool, Fluent, is used to simulate wave- induced …

Field Methods For Rapidly Characterizing Contaminant Mobility In Paint Waste During Bridge Rehabilitation, Zhan Shu

Dissertations

Currently, the New York State Department of Transportation (NYSDOT) uses a conservative approach of classifying all paint waste as hazardous from bridges undergoing rehabilitation which were constructed before 1989. This practice stems from the fact that there is no approved reliable, fast, and efficient method for classifying paint waste in-situ as non-hazardous. The main objective of this study was to develop a model that can predict the leachability of trace metals in paint waste generated during bridge rehabilitation. A statistically significant number of bridge sites were sampled based on hypothesis testing. Samples were then evaluated for total concentration of Resource …

Modeling, Control And Simulation Of Control-Affine Nonlinear Systems With State-Dependent Transfer Functions, Roger Kobla Kwadzogah

Dissertations

There has been no known research that applies nonlinear transfer function to a nonlinear control problem. The belief is that nonlinear systems have no transfer functions. The Laplace transformation required to define transfer functions is not tractable mathematically when the coefficients of the differential equation are functions of state, output and control variables. In other words, it is not defined for systems that do not obey principles of superposition. Only linear systems obey this principle. Therefore, this dissertation work represents the very first research to demonstrate how transfer functions can be used to represent and design feedback control for nonlinear …

Dynamics Of 1d Granular Column, Luo Zuo

Dissertations

This dissertation is focused on a discrete element study of the dynamics of a one- dimensional column of inelastic spheres that it subjected to taps by prescribing a half sine wave pulse to supporting floor. Contact interactions obey the Walton-Braun soft-sphere model in which the loading (unloading) path is governing by linear springs of stiffness K1, thereby producing col lisional energy loss through a constant restitution coefficient e. Over a ‘short time scale’, computations are done to examine the floor pulse wave as it propagates through the column contact network. Comparisons of the simulated findings are made with experimental measurements …

Resource Allocation For Wireless Relay Networks, Hanan Hassan Al-Tous

Dissertations

In this thesis, we propose several resource allocation strategies for relay networks in the context of joint power and bandwidth allocation and relay selection, and joint power allocation and subchannel assignment for orthogonal frequency division multiplexing (OFDM) and orthogonal frequency division multiple access (OFDMA) systems. Sharing the two best ordered relays with equal power between the two users over Rayleigh flat fading channels is proposed to establish full diversity order for both users. Closed form expressions for the outage probability, and bit error probability (BEP) performance measures for both amplify and forward (AF) and decode and forward (DF) cooperative communication …

Development Of An Integrated Incident And Transit Priority Management Control System, Faisal Ahmed

Dissertations

The aim of this thesis is to develop a distributed adaptive control system which can work standalone for a single intersection to handle various boundary conditions of recurrent, non-recurrent congestion, transit signal priority and downstream blockage to improve the overall network in terms of productivity and efficiency. The control system uses link detectors’ data to determine the boundary conditions of all incoming and exit links. Four processes or modules are deployed. The traffic regime state module estimates the congestion status of the link. The incident status module determines the likelihood of an incident on the link. The transit priority module …