Engineering Commons^™

Evaluation Of Environmental Materials As Thermal Witness Materials, Shashank Vummidi Lakshman

Dissertations

New and complex energetic materials are under development for achieving tunable pyrotechnical events for applications such as neutralization of biological weapons, bunker busters and many others. To guide the development of hybrid materials, the pyrotechnical environment they produce requires higher degree of characterization i.e. good description of spatial and temporal temperature distribution.

Temperature measurements in pyrotechnical events are especially challenging, where the temperature of the environment rises more than 2000 K on microseconds to few milliseconds time scale. These environments produce high thermal stress where traditional sensors like thermocouples, optical pyrometers struggle to describe the dynamic changes in the environment. …

Synthesis And Characterization Of Metal-Based Reactive Powders, Yasmine Aly

Dissertations

Aluminum added to propellants, explosives, and pyrotechnics, boosts their energy density. Different approaches were investigated that could shorten aluminum ignition delays, increase combustion rates, and decrease the tendency of aluminum droplets to agglomerate. Here, Al-based reactive, mechanically milled materials are prepared and characterized.

For powders with Fe, Ni, or Zn additives, the particles consist of an aluminum matrix and inclusions of Fe, Ni, or Zn comprising 10 at % of the bulk composition. For additives of Ni and Zn, only short milling times can be used to prepare composites; intermetallic phases form at longer milling times. Thermogravimetric analysis shows selective …

Novel Scrubbing Systems For Post-Combustion Co2 Capture And Recovery, Tripura Mulukutla

Dissertations

Power plant emissions of flue gas releases considerable CO₂ to the atmosphere; CO₂ is considered to be the main contributor to global warming. Several gas absorption techniques are being investigated to reduce the capital and operating costs for CO₂ capture from post-combustion flue gas. Conventional method of CO₂ capture by an aqueous solution of monoethanolamine (MEA) and its subsequent stripping in a separate tower with steam at 120°C, is a highly energy intensive process. The low partial pressure of CO₂ in the flue gas inhibits the application of CO₂-selective membranes unless methods are …

Ignition Mechanism In Nanocomposites Thermites, Rayon Williams

Dissertations

Nanocomposite thermites (n-thermites) have been actively investigated for a wide range of potential applications including propellants, explosives, and pyrotechnics. There have been several recent efforts aimed at understanding ignition mechanisms of nanocomposite reactive materials. Although significant progress has been made, ignition mechanisms remain elusive. At the same time, a robust ignition model is required to incorporate these materials in practical energetic formulations. A challenge of this effort is to describe the mechanisms of ignition of n-thermites prepared by Arrested Reactive Milling (ARM) with different stimuli, including heat, spark and impact and also develop a multi-step kinetic model describing different processes …

Gaussian Beam Scattering From A Deterministic Rough Metal Surface, Qi Wang

Theses

A full-wave theory of plane wave scattering from rough surfaces called the Correction Current (CC) method was recently developed for the two-dimensional scatter problem that have a one-dimensional roughness profile. The method involves a primary field and radiation modes that are plane-wave-type fields that satisfy the boundary conditions at the rough surface. These fields do not satisfy Maxwell's source free equations, but they are forced to satisfy Maxwell's equations with distributed sources upon the introduction of fictitious volume currents distributions which correct for the field errors. Additionally, current sheet distributions are introduced which generate a radiation modal field that satisfies …

The Photophysics Properties Of Lanthanide Luminescent Probes, Ke Li

Theses

A detailed study of the luminescence quantum yield, lifetimes and the number of water molecules coordinated to lanthanide luminescent probes based on biphenylyl-7-amino-4- methyl-2(1H)-quinolinon (Bi-cs124) derivatives have been carried out using a time- resolved fluorescence assay (TRFA). Bi-cs124 was conbined with different chelating agents, specifically diethylene triamine pentaacetic acid (DTPA), ethylene diamine tetraacetic acid (EDTA), ethylene glycol tetraacetic acid (EGTA), and 3,6,9,12-Tetrakis carboxymethyl)-3,6,9,12-tetraazatetradecane-1,14-dioic acid (TTHA). The results indicate that Bi-cs 124-TTHA has a longest lifetime and smallest number of coordinated water molecules because TTHA has larger number of chelating groups. The dependence of the luminescence lifetimes on the probes concentrations …

Preparation And Characterization Of Fast Dissolving Pullulan Films Containing Griseofulvin Nanoparticles For Bioavailability Enhancement, Zhelun Ma

Theses

The aim of this study is to enhance the bioavailability of griseofulvin, a model poorly water-soluble drug, via increasing drug dissolution rate through preparation of drug nanoparticle-laden, pullulan-based strip films. The work entails (i) wet-milling griseofulvin in a stirred media mill using pullulan (polymer) along with sodium dodecyl sulfate (surfactant) as stabilizers, (i i) preparing strip films by casting-drying a precursor suspension consisting of the mixture of the milled drug suspension and a film-forming pul l ul an–xanthan gum-glycerin solution, (iii) characterizing the suspensions and the films, and (iv) exploring the effects of film thickness, drug and xanthan gum loadings, …

Gas-Solid Transport And Reaction Via Intervened Evaporating Sprays, Pengfei He

Dissertations

Fluid catalytic cracking (FCC) is a major process used for converting heavy oils to transportation fuels and light olefins. The gas-solid transport with reaction via intervened evaporating sprays in the FCC riser is specially important but complicated, with coupled mechanisms of chemical reaction and heat, momentum and mass transfer among multiple phases (liquid, solid and gas) in the restriction of wall boundary. Recent developments in FCC process models have progressed along two lines. One aims to develop composition-based kinetic models derived from molecular characterization of petroleum fractions while overlooking the hydrodynamic effect on local catalyst to oil ratio (CTO). The …

Kinetic Analysis Of Thiol Oxidation To Study The Effects Of Fluorinated Groups On Metal Phthalocyanine Catalysts, Nellone Eze Reid

Dissertations

The oxidation of thiol (RSH) to disulfide (RSSR) is important biologically and industrially. Corrosive and malodorous thiols exist as contaminants in wastewater discharge from mining facilities, pulp and paper mills, tanneries, and oil refineries. The elimination of thiols from petroleum products is necessary for even cleaner fuels. Thiols in gas products can also inhibit catalyst activity for some downstream processes.

Experiments and mechanistic kinetic studies were conducted for the aerobic oxidation of 2-mercaptoethanol (2-ME) and 4-fluorobenzenethiol (4-FBT) catalyzed by cobalt phthalocyanines: H₁₆PcCo, F₁₆PcCo, and F₆₄PcCo, each exhibiting a metal center subject to increasing Lewis …

Global Optimization Methods For Localization In Compressive Sensing, Marco Rossi

Dissertations

The dissertation discusses compressive sensing and its applications to localization in multiple-input multiple-output (MIMO) radars. Compressive sensing is a paradigm at the intersection between signal processing and optimization. It advocates the sensing of “sparse” signals (i.e., represented using just a few terms from a basis expansion) by using a sampling rate much lower than that required by the Nyquist-Shannon sampling theorem (i.e., twice the highest frequency present in the signal of interest). Low-rate sampling reduces implementation’s constraints and translates into cost savings due to fewer measurements required. This is particularly true in localization applications when the number of measurements is …

Optimization Of Vehicle Routing And Scheduling With Travel Time Variability - Application In Winter Road Maintenance, Haifeng Yu

Dissertations

This study developed a mathematical model for optimizing vehicle routing and scheduling, which can be used to collect travel time information, and also to perform winter road maintenance operations (e.g., salting, plowing). The objective of this research was to minimize the total vehicle travel time to complete a given set of service tasks, subject to resource constraints (e.g., truck capacity, fleet size) and operational constraints (e.g., service time windows, service time limit).

The nature of the problem is to design vehicle routes and schedules to perform the required service on predetermined road segments, which can be interpreted as an arc …

Characterizing Motor Control Signals In The Spinal Cord, Yi Guo

Dissertations

The main goal of this project is to develop a rodent model to study the central command signals generated in the brain and spinal cord for the control of motor function in the forearms. The nature of the central command signal has been debated for many decades with only limited progress. This thesis presents a project that investigated this problem using novel techniques. Rats are instrumented to record the control signals in their spinal cord while they are performing lever press task they are trained in. A haptic interface and wireless neural data amplifier system simultaneously collects dynamic and neural …

Congestion Control, Energy Efficiency And Virtual Machine Placement For Data Centers, Yan Zhang

Dissertations

Data centers, facilities with communications network equipment and servers for data processing and/or storage, are prevalent and essential to provide a myriad of services and applications for various private, non-profit, and government systems, and they also form the foundation of cloud computing, which is transforming the technological landscape of the Internet. With rapid deployment of modern high-speed low-latency large-scale data centers, many issues have emerged in data centers, such as data center architecture design, congestion control, energy efficiency, virtual machine placement, and load balancing.

The objective of this thesis is multi-fold. First, an enhanced Quantized Congestion Notification (QCN) congestion notification …

Physical Controls On Water Flow And Solute Transport In Coastal Aquifers, Xiaolong Geng

Dissertations

Groundwater flow and associated subsurface solute fates have a significant impact on the structure and productivity of near-shore coastal ecosystems. For proper assessment and management of these coastal groundwater resources, it is quite essential to investigate the key factors (tides, waves, evaporation, and freshwater recharge etc.) affecting coastal groundwater systems. The main objective of this study is to examine and quantify two important physical control factors, oceanic waves and evaporation, on the groundwater flow and solute transport in near-shore aquifers. For the investigation of wave effects, a Computational Fluid Dynamics (CFD) modeling tool, Fluent, is used to simulate wave- induced …

Field Methods For Rapidly Characterizing Contaminant Mobility In Paint Waste During Bridge Rehabilitation, Zhan Shu

Dissertations

Currently, the New York State Department of Transportation (NYSDOT) uses a conservative approach of classifying all paint waste as hazardous from bridges undergoing rehabilitation which were constructed before 1989. This practice stems from the fact that there is no approved reliable, fast, and efficient method for classifying paint waste in-situ as non-hazardous. The main objective of this study was to develop a model that can predict the leachability of trace metals in paint waste generated during bridge rehabilitation. A statistically significant number of bridge sites were sampled based on hypothesis testing. Samples were then evaluated for total concentration of Resource …

Modeling, Control And Simulation Of Control-Affine Nonlinear Systems With State-Dependent Transfer Functions, Roger Kobla Kwadzogah

Dissertations

There has been no known research that applies nonlinear transfer function to a nonlinear control problem. The belief is that nonlinear systems have no transfer functions. The Laplace transformation required to define transfer functions is not tractable mathematically when the coefficients of the differential equation are functions of state, output and control variables. In other words, it is not defined for systems that do not obey principles of superposition. Only linear systems obey this principle. Therefore, this dissertation work represents the very first research to demonstrate how transfer functions can be used to represent and design feedback control for nonlinear …

Dynamics Of 1d Granular Column, Luo Zuo

Dissertations

This dissertation is focused on a discrete element study of the dynamics of a one- dimensional column of inelastic spheres that it subjected to taps by prescribing a half sine wave pulse to supporting floor. Contact interactions obey the Walton-Braun soft-sphere model in which the loading (unloading) path is governing by linear springs of stiffness K1, thereby producing col lisional energy loss through a constant restitution coefficient e. Over a ‘short time scale’, computations are done to examine the floor pulse wave as it propagates through the column contact network. Comparisons of the simulated findings are made with experimental measurements …

Approach To Flood Mitigation - A Post Sandy Study In New Jersey Meadowlands Area, Banshari Datta

Theses

In the last decade the continuous change in the climate has resulted in an increased frequency of natural catastrophic events and the magnitude of their impact. The immense damage caused by such events brought to light the vulnerabilities of the impacted communities. Coastal communities are alarmingly vulnerable due to flood and storm surge impacts such as those caused by super storm Sandy in 2012. In order to mitigate this risk, the communities need to look beyond the short term recovery measures, and build a sustainable community by implementing long term mitigation measures. The objective of this thesis is to investigate …

Hydrodynamic Cfd Modeling Of A Pharmaceutical Reactor Vessel Provided With A Retreat-Blade Impeller Under Different Baffling Conditions, Christopher G. Foehner

Theses

In the pharmaceutical industry, glass-lined reactors and vessels are often utilized to carry out a variety of different unit operations. Within these systems, both the vessel and impellers are typically glass-lined in order to provide superior corrosion resistance, prevent product contamination, and enhance cleanability. This approach, in turn, often requires the use of different, and sometimes sub-optimal, baffling conditions, which affect the hydrodynamics of the vessels and the reactor performance.

Computational Fluid Dynamics (CFD) is a computational tool that employs numerical methods and algorithms to discretize and numerically solve partial differential equations (PDEs) representing mass, energy, and momentum conservation equations …

The Effect Of Vergence Vision Training On Binocularly Normal Subjects, Henry Talasan

Theses

Vergence is the disjunctive (inward or outward) movement of the eyes that is stimulated by retinal disparity (difference of where an image is projected to the retina and the fovea). A recent randomized clinical trial showed the efficacy of vision therapy for children with the binocular dysfunction known as convergence insufficiency is 73%. However, it is unknown whether binocularly normal persons will have any significant change to their vergence ocular motor system if they participate in vision training sessions. A total of ten (n = 10) binocularly normal persons participated in this study (18 to 28 years of age). A …

Combustion Of Fine Magnesium Particles, Song Wang

Theses

Recent interest in developing Al-Mg alloys as reactive materials prompted studies of combustion mechanisms for particles of such alloys with different Al/Mg ratios. Reference experiments with pure Al and Mg powders are also desired to better understand and model combustion of the respective alloys. While combustion of pure Al powders has been addressed in many recent studies, combustion of magnesium explored mostly coarse, 50 μm, and larger particles. This effort is focused to characterize and understand combustion dynamics for fine Mg powders. Spherical, micron-sized magnesium particles were introduced in an air-acetylene flame using a custom-made screw feeder. Particles were observed …

Experimental Determination Of The Mixing Requirements For Solid Suspension In Pharmaceutical Stirred Tank Reactors, Anqi Zhou

Theses

Glass and glass-lined, stirred-tank reactors are of significant importance in the pharmaceutical and related industries. Because of fabrication issues, a retreat blade impeller (RBI) with a low impeller clearance off the tank bottom is commonly used in glass-lined reactors, typically combined with a single baffle (providing only partial baffling conditions) mounted from the top of the reactor. In addition, these reactors are often provided with a torispherical bottom. Other configurations are also used, including full baffling or no baffles at all, hemispherical bottoms, and different impeller types. Despite their common use, some of the most important mixing characteristics of this …

Short Term Modification Of Vergence Ramp Eye Movements In The Convergent Direction, Chang Yaramothu

Theses

Prior oculomotor studies have investigated the various effects of short-term modification on vergence, saccadic and smooth pursuit eye movements. Previous vergence studies have concentrated on step modification stimuli. Few have investigated the effects of short-term modification on vergence ramp movements. Thus, this study explores the trends observed within a short-term modification experiment studying smoothly tracking vergence eye movements responses elicited from convergent ramp stimuli. A short-term modification experiment is composed of three phases: baseline, modification and recovery. Baseline and recovery phases contain only test stimuli; whereas, during modification, the subject is presented test and conditioning stimuli in a ratio of …

Optimizing Alginate-Chitosan Microcapsules Using Co-Axial Air Flow Method As 3d Stem Cell Microenvironment, Noel Alfonso

Theses

Microencapsulation of cells is gaining popular interest in the field of biomedical engineering because it provides a more effective 3D scaffold that can mimic the cell microenvironment. The benefits of using microcapsules are biocompatibility, biodegradability, nontoxicity, and formation under mild gelation conditions. In this study, the ability of the alginate microcapsules to control the proliferation and differentiation of mouse OCT4-GFP embryonic stem cells is investigated. Microcapsules are produced by extrusion of alginate into a calcium chloride gelation bath with the aid of a co-axial air flow. It is shown that the size of the spheres is controlled based on needle …

Evaluation Of Methods To Account For Release From Nanofiber Scaffolds, Jennifer Moy

Theses

Electrospinning is a common technique utilized to form fibers from the micro- to nanometer range. Nanofibers form through electrospinning can be utilized as scaffolds since the fiber structures are similar to the structures within the extracellular matrix. Researchers use additives, such as growth factors, to help facilitate cell proliferation and function. Also, researchers are attempting to use electrospun fibers for drug delivery and as wound dressings since the electrospun fibers have high surface area to volume ratio. In both situations, the release of either the additive or the drug needs to be controlled so that the fibers would release the …

Assessment Of A Marine Polysaccharide For Use As Excipient In Pharmaceutical Hot-Melt Extrusion, Qing Ye

Theses

Pharmaceutical Hot Melt Extrusion (HME) is currently investigated by both industry and academia as a method for manufacturing solid oral dosages with improved bioavailability of poorly-water soluble active pharmaceutical ingredients (APIs) and control drug release of water-soluble APIs. Although HME is traditionally utilizing synthetic polymers to produce such dosages, biopolymers constantly gain ground by virtue of renewability, biocompatibility and in some cases biodegradability. In this work, the possibility of using Keltone, a marine polysaccharide derived from brown seaweed, as a polymeric excipient for pharmaceutical HME is explored. Keltone is insoluble in acidic pH and soluble in basic pH, therefore making …

Dispersion And Dissolution Kinetics Of Api Particles In Pharmaceutical Hot Melt Extrusion, Wang Zhan

Theses

Pharmaceutical Hot Melt Extrusion (HME) is essentially a special case of polymer compounding. The elementary steps involved in traditional plastics melt processing are handling of particulates, melting, dispersive and distributive mixing, devolatilization and stripping, and finally pressurization and pumping. However, for pharmaceutical HME, the dissolution of the API (Active Pharmaceutical Ingredient) is an additional and very important elementary step, along with the melting of the polymeric excipient that precedes it, and mixing which accelerates the dissolution process. A major concern in pharmaceutical HME is the thermal degradation of the API. To avoid overexposure of API to heat while ensuring complete …

Rate Alterable Traumatic Brain Injury Device For Rodent Models, Radia Abdul Wahab

Dissertations

Traumatic Brain Injury (TBI) is a physical impact to the head resulting in functional deficits in memory and motor systems. TBI is a prevalent problem occurring in 1.7 million people annually in the United States (Faul et al. 2010). TBIs can differ greatly in terms of the biomechanics of the impact such as magnitude, direction and rate. Indeed, it is likely that the wide range of TBI outcomes may be due to the physical characteristics of the trauma. Studies to date on impact have used injury devices with limited alterable parameters. Therefore, the existing impact studies have considered the effect …

The Effect Of Mechanical Vestibular Stimulation On Muscle Tone And Spasticity In Individuals With Neurological Impairment, Ghaith J. Androwis

Dissertations

In the desire to better understand spasticity mainly in Cerebral Palsy (CP) and to examine vestibular stimulation as a future intervention for .muscle tone reduction, and to be able to describe the change in level of spasticity in subjects with disability and describe interventions effects, a series of experiments are done on children with spasticity. In addition to understanding the otoliths in the vestibular system and their projections, properties and pathways a more important major objective of this work is to validate the changes in otoliths signal caused by vestibular stimulation based on the Equilibrium Point Hypothesis and the inclusion …

Analyses Of Groundwater Contribution To A Riverine Wetland, Farzad Mahmoodinobar

Dissertations

Rainfall, runoff, overbank flow and groundwater, all contribute water to wetlands. Each transport element is associated with unique modeling approaches and uncertainties. Transpiration is perhaps the hardest to quantify as it is subject to all the variability of plant growth. Transpiration causes land area to lose moisture and the loss amount depends on precipitation incidence, the temperature and type and extent of vegetation. Plants can intercept virtually all recharge during the growing season and almost none from late fall to early spring in northeastern United States. Thus, an improvement in the transpiration element can contribute considerably to an improved groundwater …