Engineering Commons^™

Effect Of Graphitic Carbon Nanomodifiers On The Electromagnetic Shielding Effectiveness Of Linear Low Density Polyethylene Nanocomposites, Byron Villacorta Hernandez

All Dissertations

Conductive polymer composites have become alternative materials for providing electromagnetic and electrostatic shielding where metals are not suitable. In this study, the effect of crystallinity, morphology, concentration and orientation of carbon nanomodifiers on shielding provided by their polyethylene-based composites has been investigated relative to their transport properties.

First, the electrical properties and EM SE of composites consisting of heat-treated carbon nanofibers (Pyrograf^® -III PR-19 CNF) in a linear low density polyethylene (LLDPE) matrix were assessed. Heat treatment (HT) of CNF at 2500°C significantly improved their graphitic crystallinity and intrinsic transport properties, thereby increasing the EM SE of the nanocomposites. …

Phonon Transport Analysis Of Semiconductor Nanocomposites Using Monte Carlo Simulations, Mayank Malladi

All Theses

Nanocomposites are composite materials which incorporate nanosized particles, platelets or fibers. The addition of nanosized phases into the bulk matrix can lead to significantly different material properties compared to their macrocomposite counterparts. For nanocomposites, thermal conductivity is one of the most important physical properties. Manipulation and control of thermal conductivity in nanocomposites have impacted a variety of applications. In particular, it has been shown that the phonon thermal conductivity can be reduced significantly in nanocomposites due to the increase in phonon interface scattering while the electrical conductivity can be maintained. This extraordinary property of nanocomposites has been used to enhance …

Advanced Biomaterials From Renewable Resources: An Investigation On Cellulose Nanocrystal Composites And Co2 Extraction Of Rendered Materials, Jose Orellana

All Dissertations

The annual global consumption of petroleum-based plastics is approximately 280 million tons and is impacting the sustainability of our planet and prosperity of future generations. One solution is the development of bio-based polymer materials with advanced properties for commercial applications. Therefore, the ultimate goal of this dissertation is to investigate the properties of new bio-based materials for broader applications. This dissertation includes two research areas: cellulose nanocomposites, and CO₂ extractions of rendered fat. In the first half, cellulose nanocrystals (CNCs), which exhibit excellent mechanical and optical properties, were investigated for the reinforcement of a biodegradable polymer. The properties of …

Multiscale Study Of Batio3 Nanostructures And Nanocomposites, Lydie Louis Louis

Graduate Theses and Dissertations

Advancements in integrated nanoelectronics will continue to require the use of unique materials or systems of materials with diverse functionalities in increasingly confined spaces.

Hence, research on finite-dimensional systems strive to unearth and expand the knowledge of fundamental physical properties in certain key materials which exhibit numerous concurrent and exploitable functions.

Correspondingly, ferroelectric nanostructures, which particularly display a plethora of complex phenomena, prevalent in countless fields of research, are noteworthy candidates. Presently, however, the assimilation of zero-(0D) and one-dimensional (1D) ferroelectric into micro- or nano-electronics has been lagging, in part due to a lack of applied and fundamental studies but …

High Volume Fraction Mg-Based Nanocomposites: Processing, Microstructure And Mechanical Behavior, Jinling Liu

Electronic Theses and Dissertations

Mg-based metal matrix nanocomposites (MMNCs) with mechanical properties, superior to those of coarse-grained composites, are promising structural materials for applications in the automotive and aerospace industries. The research in this area was primarily focused earlier on either micro-scaled reinforcements or nano-scaled reinforcements with very low volume fractions. MMNCs with high volume fractions have not been explored yet. In this research, we study the processing, microstructures and properties of MMNCs containing ceramic nanoparticles up to 30 vol.%. We first investigated the mechanical alloying of Al2O3 nanoparticles and pure Mg under high-energy ball milling conditions. The phase evolution and their distribution were …

Physical, Mechanical And Chemical Aging Of Polyurea Nanocomposites, Ghanshyam Pal

Electronic Theses and Dissertations

Two component polyurea systems, on one hand, are gaining popularity as corrosion and abrasion resistant coatings and linings while on the other hand there are a few polyurea compositions being used as barrier against blast and ballistic threats to protect nation's critical infrastructure. Physical properties of polymer composites can be tailored with appropriate choice of type, size and amount of reinforcement. In general, nano-sized reinforcements provide better reinforcing over conventional reinforcements due to higher surface to volume ratio. In this dissertation, the first aim is to study effect of nanoreinforcement addition on the overall character (mechanical, chemical and microstructural) of …

Three-Dimensional Evolution Of Mechanical Percolation In Nanocomposites With Random Microstructures, Bethany Suzanne Fralick

Theses and Dissertations

One mechanism that is expected to play a large role in the enhanced, and sometimes novel, mechanical properties of nanocomposites is the probabilistic formation of percolated or connected microstructures. The majority of the models used to describe mechanical percolation have the functional form of a power law and depend on prior knowledge of a percolation threshold or critical volume fraction. While these models have been fairly accurate predictors of electrical conductivity in composites, they do not take any microstructural mechanisms, other than connectivity, into consideration. Classic mean-field micromechanics models, however, do not capture the variability in effective properties due to …