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Full-Text Articles in Engineering
An Analysis Of Microstructure And Corrosion Resistance In Underwater Friction Stir Welded 304l Stainless Steel, Tad Dee Clark
An Analysis Of Microstructure And Corrosion Resistance In Underwater Friction Stir Welded 304l Stainless Steel, Tad Dee Clark
Theses and Dissertations
An effective procedure and parameter window was developed for underwater friction stir welding (UWFSW) 304L stainless steel with a PCBN tool. UWFSW produced statistically significant: increases in yield strengths, decreases in percent elongation. The ultimate tensile strength was found to be significantly higher at certain parameters. Although sigma was identified in the UWFSWs, a significant reduction of sigma was found in UWFSWs compared to ambient FSWs. The degree of sensitization in UWFSWs was evaluated using double loop EPR testing and oxalic acid electro-etched metallography. Results were compared to base metal, ambient FSW, and arc welds. Upper and lower sensitization localization …
Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole
Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole
Civil & Environmental Engineering Theses & Dissertations
Halonitromethanes (HNMs) are low molecular weight halogenated disinfection-by-products (DBPs) found to be formed during ozonation, chlorination, or chloramination of waters containing natural bromide ion and nitrogenous organic matter. This work identifies the absolute rate constants for the oxidative hydroxyl radical (•OH) and reductive hydrated electron e- aq extinction of HNM compounds. Three forms of HNMs included in this study are the chlorinated, brominated, and mixed halogenated compounds. Electron pulse radiolysis and transient absorption spectroscopy were used to measure •OH and e- aq radical absolute reaction rate constants for a total of nine HNMs. To elucidate the decomposition reaction …
Purification And Structural Characterization Of Caged Dna Oligonucleotides, Brendan Michael Mcadams
Purification And Structural Characterization Of Caged Dna Oligonucleotides, Brendan Michael Mcadams
LSU Master's Theses
“Cage” molecules reversibly block the bioactivity of a target substrate molecule by a photolyzable covalent bond formed at a functional site of the target molecule. The attachment of cage molecules to DNA oligodeoxynucleotides (ODNs) to transiently block bioactivity, and site-specific restoration of bioactivity using targeted light exposure, would enable a new method of control for use in gene therapy, molecular/DNA computing, molecular biology, and drug delivery. The reaction of the cage molecule 1-(4,5-dimethoxy-2-nitrophenyl)diazoethane (DMNPE) with DNA ODNs in an batch reaction yields a mixture of products with varying degrees of caging. Purification and verification of the hypothesized site of DMNPE …