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Full-Text Articles in Engineering

An Analysis Of Microstructure And Corrosion Resistance In Underwater Friction Stir Welded 304l Stainless Steel, Tad Dee Clark Jun 2005

An Analysis Of Microstructure And Corrosion Resistance In Underwater Friction Stir Welded 304l Stainless Steel, Tad Dee Clark

Theses and Dissertations

An effective procedure and parameter window was developed for underwater friction stir welding (UWFSW) 304L stainless steel with a PCBN tool. UWFSW produced statistically significant: increases in yield strengths, decreases in percent elongation. The ultimate tensile strength was found to be significantly higher at certain parameters. Although sigma was identified in the UWFSWs, a significant reduction of sigma was found in UWFSWs compared to ambient FSWs. The degree of sensitization in UWFSWs was evaluated using double loop EPR testing and oxalic acid electro-etched metallography. Results were compared to base metal, ambient FSW, and arc welds. Upper and lower sensitization localization …


Ethane Oxidation And Pyrolysis From 5 Bar To 1000 Bar: Experiments And Simulation, Abdul Aziz Abdul Raman Mar 2005

Ethane Oxidation And Pyrolysis From 5 Bar To 1000 Bar: Experiments And Simulation, Abdul Aziz Abdul Raman

Abdul Aziz Abdul Raman

An extensive experimental study of ethane oxidation and pyrolysis has been conducted in the high pressure shock tube at UIC covering reflected shock pressures from 5-1000 bar, reaction temperatures up to 1550 K and stoichiometric (Φ = 1 ), fuel rich (Φ = 5), and pyrolytic mixtures. The experimental data has been used to develop a single model that can simulate the whole dataset very well and is the first ethane model capable of simulating experimental results over such an extensive range of pressure, temperature, and stoichiometry. © 2005 Wiley Periodicals, Inc.


Analysis Of Oxidation And Surface Characteristics In Hot Strip Rolling, Zhengyi Jiang, Weihua Sun, Jianning Tang, Dongbin Wei, A K. Tieu Jan 2005

Analysis Of Oxidation And Surface Characteristics In Hot Strip Rolling, Zhengyi Jiang, Weihua Sun, Jianning Tang, Dongbin Wei, A K. Tieu

Faculty of Engineering - Papers (Archive)

Deformation characteristics of the oxide scale in hot strip mill have not been quantified before and the principle of the effect of oxide scale deformation in the roll bite on strip surface roughness has not yet been revealed. In this paper, analysis of the thin secondary oxide scale formed in hot metal rolling and its surface roughness micro deformation is carried out by experiments and finite element analysis. Simulation results are compared with the measured values, which show that they are in close agreement. Surface roughness transfer during hot metal rolling is also discussed.


Purification And Structural Characterization Of Caged Dna Oligonucleotides, Brendan Michael Mcadams Jan 2005

Purification And Structural Characterization Of Caged Dna Oligonucleotides, Brendan Michael Mcadams

LSU Master's Theses

“Cage” molecules reversibly block the bioactivity of a target substrate molecule by a photolyzable covalent bond formed at a functional site of the target molecule. The attachment of cage molecules to DNA oligodeoxynucleotides (ODNs) to transiently block bioactivity, and site-specific restoration of bioactivity using targeted light exposure, would enable a new method of control for use in gene therapy, molecular/DNA computing, molecular biology, and drug delivery. The reaction of the cage molecule 1-(4,5-dimethoxy-2-nitrophenyl)diazoethane (DMNPE) with DNA ODNs in an batch reaction yields a mixture of products with varying degrees of caging. Purification and verification of the hypothesized site of DMNPE …


Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole Jan 2005

Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole

Civil & Environmental Engineering Theses & Dissertations

Halonitromethanes (HNMs) are low molecular weight halogenated disinfection-by-products (DBPs) found to be formed during ozonation, chlorination, or chloramination of waters containing natural bromide ion and nitrogenous organic matter. This work identifies the absolute rate constants for the oxidative hydroxyl radical (•OH) and reductive hydrated electron e- aq extinction of HNM compounds. Three forms of HNMs included in this study are the chlorinated, brominated, and mixed halogenated compounds. Electron pulse radiolysis and transient absorption spectroscopy were used to measure •OH and e- aq radical absolute reaction rate constants for a total of nine HNMs. To elucidate the decomposition reaction …