Engineering Commons^™

Advances In Modeling Gas Adsorption In Porous Materials For The Characterization Applications, Max A. Maximov

Dissertations

The dissertation studies methods for mesoporous materials characterization using adsorption at various levels of scale and complexity. It starts with the topic introduction, necessary notations and definitions, recognized standards, and a literature review.

Synthesis of novel materials requires tailoring of the characterization methods and their thorough testing. The second chapter presents a nitrogen adsorption characterization study for silica colloidal crystals (synthetic opals). These materials have cage-like pores in the range of tens of nanometers. The adsorption model can be described within a macroscopic approach, based on the Derjaguin-Broekhoff-de Boer (DBdB) theory of capillary condensation. A kernel of theoretical isotherms is …

Calculating Elastic Properties Of Confined Simple Fluids, Christopher D. Dobrzanski

Dissertations

Confinement in nanoporous materials is known to affect many properties of the fluids confined within their pores. The elastic properties are no exception. This dissertation begins with an overview of the relevant literature on ways of obtaining elastic properties of confined fluids. It outlines some fundamental gaps in our understanding. The chapters following address some of these gaps in understanding elastic properties of the confined fluid, in particular, how the shape of the confining pore matters, how supercriticality effects the properties, how an equation of state designed for confined fluids can be used to calculate elastic properties, and if an …

Activated Carbon Nanofibers From Renewable (Lignin) And Waste Resources (Recycled Pet) And Their Adsorption Capacity Of Refractory Sulfur Compounds From Fossil Fuels, Efstratios Svinterikos

Dissertations

The development of advanced engineering materials such as carbon nanofibers from low-cost, renewable and/or waste resources is a key aspect of sustainability. In addition, escalating concerns related to the presence of noxious sulfur compounds in commercial fuels are driving the need to develop more efficient desulfurization technologies. In this PhD dissertation research, activated carbon nanofibers were produced from a blend of lignin with recycled poly(ethylene terephthalate) (r-PET) and they were successfully tested for the adsorption of refractory sulfur compounds from a model diesel fuel. Starting from different lignin/r-PET mass ratios, precursor nanofibers of different morphologies were initially prepared using the …

Study On The Dispersion Of Particles At A Fluid-Liquid Interface And Its Application In Hydrophilous Pollination, Naga Aditya Musunuri

Dissertations

This dissertation work describes the physics of particle adsorption and the spontaneous dispersion of powders that occurs when they come in contact with a fluid-liquid interface and its application in hydrophilous pollination of Ruppia Maritima, an aquatic plant. The dispersion of particles can occur so quickly that it appears explosive, especially for small particles on the surface of mobile liquids like water. PIV (Particle Image Velocimetry) measurements show that the adsorption of a spherical particle at the interface causes an axisymmetric streaming flow about the vertical line passing through the particle center. The fluid directly below the particle rises upward, …

Adsorption Of Particles On Fluid-Liquid Interfaces, Bhavin Dalal

Dissertations

Particles floating on fluid-liquid interfaces are of considerable interest because of their importance in a range of physical applications and biological processes, e.g., self-- assembly of particles at fluid-fluid interfaces resulting in novel nano structured materials, stabilization of emulsions, formation of pollen and insect egg rafts, etc. The aim of this dissertation is to explore the mechanism by which particles are adsorbed at fluid-liquid interfaces. It is shown that the inertia of a particle plays an important role in its motion in the direction normal to a fluid-liquid interface, and in determining the particles adsorption trajectory and orientation in …

Heavy Metal Adsorption On Iron Oxide And Iron Oxide-Coated Silica : Macroscopic, Spectroscopic, And Modeling Studies, Ying Xu

Dissertations

To accurately model metal mobility and bioavailability in soils and sediments, systematic sorption studies are needed using representative and well-characterized minerals. Two important surfaces are iron oxide and silica, which are ubiquitous and associated with one another in the environment playing important roles in metal distribution. The objectives of this research are to develop models for predicting speciation and mobility of toxic trace metal ions in groundwater, soils, and sediments when competing ions are present. A model system for soils and sediments, iron oxide-coated silica, was synthesized; the degree of coatings was highly sensitive to the particle size of silica …

Mathematical Simulation Of Proteins Separation In A Packed Bed, Jing James Huang

Dissertations

The generalized adsorption models are developed to simulate the unsteady state mass transfer behavior in a packed column. Based on the nature of adsorbent particles, the adsorption models may be classified into two categories: (1) the surface adsorption model, (2) the pore diffusion model. In the first model, it is assumed that the internal diffusion is negligible, and the adsorption rate is determined by external diffusion and surface adsorption. In the second model, the effect of internal diffusion is considered as significant as that of external diffusion. For both models, the effect of axial dispersion in fluid phase is emphasized. …