Engineering Commons^™

Polyisobutylene Telechelic Prepolymers By In Situ End-Quenching And Post-Polymerization Modifications, Bin Yang

Dissertations

This volume focuses on the development of telechelic polyisobutylene (PIB) prepolymers by combining end-capping of living carbocationic polymerization of isobutylene (IB) with suitable reactants and post-polymerization modifications. Alkylation kinetics of PIB tert-chloride with alkoxybenzenes using either TiCl₄ or AlCl₃ were investigated. Quantitative para-position end-capped products were only achieved if the alkoxybenzene/AlCl₃ molar ratio was greater than unity; while no such molar ratio is required for TiCl₄, but the alkylation rate was slower than AlCl₃ under the same conditions. Photopolymerization kinetics analysis of PIB triphenol tri(meth)acrylates with low and high M_ns, …

Design And Synthesis Of Dynamic Covalent Polymer Scaffolds With Controlled Architectures, Emily Annette Hoff

Dissertations

The design and synthesis of functional, controlled polymer architectures is essential to the development of new materials with precise and tailorable properties or applications. The work described in this dissertation focuses on the development of controlled polymer architectures with dynamic linkages for the design of multifunctional materials and surfaces via robust, efficient, and stimuli-responsive strategies.

In Chapter III, a post-polymerization modification strategy based on ambient temperature nucleophilic chemical deblocking of polymer scaffolds bearing N-heterocycle blocked isocyanate moieties is reported. Room temperature RAFT polymerization of three azole-N-carboxamide methacrylates, including 3,5-dimethyl pyrazole, imidazole, and 1,2,4-triazole derivatives, afforded reactive polymer scaffolds …

The Influence Of The Electric Supply Industry On Economic Growth In Less Developed Countries, Edward Richard Bee

Dissertations

This study measures the impact that electrical outages have on manufacturing production in 135 less developed countries using stochastic frontier analysis and data from World Bank’s Investment Climate surveys. Outages of electricity, for firms with and without backup power sources, are the most frequently cited constraint on manufacturing growth in these surveys.

Outages are shown to reduce output below the production frontier by almost five percent in Africa and by a lower percentage in South Asia, Southeast Asia and the Middle East and North Africa. Production response to outages is quadratic in form. Outages also increase labor cost, reduce exports …

Understanding Millennial, Generation X, And Baby Boomer Preferred Leadership Characteristics: Informing Today’S Leaders And Followers, Lee-Volker Cox

Dissertations

Purpose. This quantitative study’s purpose was to describe and determine the degree of difference and importance of leadership characteristics as perceived by Baby Boom, Generation X, and Millennial generational cohort followers in STEM-related U.S.-based or headquartered aerospace and computer organizations as measured by the Multigenerational Leadership Characteristics Questionnaire (MLCQ).

Methodology. This was a cross-sectional, nonexperimental, comparative and correlational quantitative, ex post facto study. A web-based MLCQ was developed after conducting an academic literature review. Participants used a 6-point Likert scale identifying the importance of 30 characteristics with 2 aggregation questions identifying the most and least important characteristics; 408 members of …

Novel Software Defined Radio Architecture With Graphics Processor Acceleration, Lalith Narasimhan

Dissertations

Wireless has become one of the most pervasive core technologies in the modern world. Demand for faster data rates, improved spectrum efficiency, higher system access capacity, seamless protocol integration, improved security and robustness under varying channel environments has led to the resurgence of programmable software defined radio (SDR) as an alternative to traditional ASIC based radios. Future SDR implementations will need support for multiple standards on platforms with multi-Gb/s connectivity, parallel processing and spectrum sensing capabilities. This dissertation implemented key technologies of importance in addressing these issues namely development of cost effective multi-mode reconfigurable SDR and providing a framework to …

Hybrid Aryl-Ether-Ketone And Hyperbranched Epoxy Networks, John Misasi

Dissertations

In this dissertation, relationships between chemical structures, cure kinetics and network architectures are correlated to bulk mechanical properties for novel, hybrid epoxy-amine networks. The work is split into two primary sections: the first is the synthesis and characterization of multifunctional glassy networks based on aryl-ether-ketone diamine curatives, while the second is based on the synthesis and characterization of hyperbranched epoxy polymers and their resulting networks.

Three aryl-ether-ketone (AEK) diamines of increasing molecular weights were synthesized and used to cure 4,4’-tetraglycidylether of diaminodiphenylmethane (TGDDM); the resulting networks were compared to 4,4’-diaminodiphenyl sulfone cured TGDDM. Architectural differences were created by varying cure …

Development Of Dual-Cure Hybrid Polybenzoxazine Thermosets, Jananee Narayanan Sivakami

Dissertations

Polybenzoxazines are potential high performance thermoset replacements for traditional phenolic resins that can undergo an autocatalytic, thermally initiated ring - opening polymerization, and possess superior processing advantages including excellent shelf-life stability, zero volatile loss and limited volumetric shrinkage. The simplistic monomer synthesis and availability of a wide variety of inexpensive starting materials allows enormous molecular design flexibility for accessing a wide range of tailorable material properties for targeted applications. Despite the fact, once fully cured, benzoxazines are difficult to handle due to their inherent brittleness, leaving a very little scope for any modifications. The motivation of this dissertation is directed …

On The Selection Of A Good Shape Parameter For Rbf Approximation And Its Application For Solving Pdes, Lei-Hsin Kuo

Dissertations

Meshless methods utilizing Radial Basis Functions~(RBFs) are a numerical method that require no mesh connections within the computational domain. They are useful for solving numerous real-world engineering problems. Over the past decades, after the 1970s, several RBFs have been developed and successfully applied to recover unknown functions and to solve Partial Differential Equations (PDEs).
However, some RBFs, such as Multiquadratic (MQ), Gaussian (GA), and Matern functions, contain a free variable, the shape parameter, c. Because c exerts a strong influence on the accuracy of numerical solutions, much effort has been devoted to developing methods for determining shape parameters which provide …

Secure And Reliable Routing Protocol For Transmission Data In Wireless Sensor Mesh Networks, Nooh Adel Bany Muhammad

Dissertations

Abstract

Sensor nodes collect data from the physical world then exchange it until it reaches the intended destination. This information can be sensitive, such as battlefield surveillance. Therefore, providing secure and continuous data transmissions among sensor nodes in wireless network environments is crucial. Wireless sensor networks (WSN) have limited resources, limited computation capabilities, and the exchange of data through the air and deployment in accessible areas makes the energy, security, and routing major concerns in WSN. In this research we are looking at security issues for the above reasons. WSN is susceptible to malicious activities such as hacking and physical …

A Novel Approach For Identifying Cloud Clusters Developing Into Tropical Cyclones, Chaunte' W. Lacewell

Dissertations

Providing advance notice of rare events, such as a cloud cluster (CC) developing into a tropical cyclone (TC), is of great importance. Having advance warning of such rare events possibly can help avoid or reduce the risk of damages and allow emergency responders and the affected community enough time to respond appropriately. Considering this, forecasters need better data mining and data driven techniques to identify developing CCs. Prior studies have attempted to predict the formation of TCs using numerical weather prediction models as well as satellite and radar data. However, refined observational data and forecasting techniques are not always available …

Utilization Of Aqueous Raft Prepared Copolymers To Improve Anticancer Drug Efficacy, Andrew Christopher Holley

Dissertations

The advent of controlled radical polymerization (CRP) techniques, along with advancements in facile conjugation chemistry, now allow synthetic tailoring of precise, polymeric architectures necessary for drug/gene delivery. Reversible addition- fragmentation chain transfer (RAFT) polymerization and its aqueous counterpart (aRAFT) afford quantitative control over key synthetic parameters including block length, microstructure, and placement of structo-pendent and structo-terminal functionality for conjugation of active agents and targeting moieties. The relevance of water-soluble and amphiphilic (co)polymers synthesized by RAFT for in vitro delivery of therapeutics in biological fluids is an especially attractive feature. In many cases, polymerization, binding, conjugation, …

Development And Applications Of The Expanded Equivalent Fluid Method, Bharath Kumar Kandula

Dissertations

Ocean acoustics is the study of sound in the oceans. Electromagnetic waves attenuate rapidly in the water medium. Sound is the best means to transmit information underwater. Computational numerical simulations play an important role in ocean acoustics. Simulations of acoustic propagation in the oceans are challenging due to the complexities involved in the ocean environment. Different methods have been developed to simulate underwater sound propagation. The Parabolic-Equation (PE) method is the best choice in several ocean acoustic problems. In shallow water acoustic experiments, sound loses some of its energy when it interacts with the bottom. An equivalent fluid technique was …

Opportunistic Service Differentiation And Cloud Resource Management In Support Of Enhanced Vehicular Applications, Mohammad Ali Salahuddin

Dissertations

An integral part of Intelligent Transportation Systems (ITS) are Vehicular Ad hoc Networks (VANETs), which consist of vehicles with on-board units (OBUs) and fixed road-side units (RSUs). Wireless Access in Vehicular Environment (WAVE) offers QoS via service differentiation by using application defined priorities. However, WAVE has unbounded delay and is oblivious to network load and severity of vehicles with respect to their environment. Our context severity metric innovatively enhances WAVE to be sensitive to vehicle and environment interactions. Our novel Opportunistic Service Differentiation (OSD) technique, dynamically readjusts the WAVE packet priorities to improve utilization of lower latency queues, prioritizing packets …

Size-Dependent Interactions Of Metal Nanoparticles With Fluorophores And Semiconductors, Liyana A. Wajira Ariyadasa

Dissertations

In recent years, nanoscale metallic particles have gained considerable interest due to their potential applications in advanced technology. Despite such interest, synthetic procedures that produce gram-scale, well-defined metallic nanoparticles with controlled size and shape, especially with diameters less than 5 nm remains a challenge. Our work has focused on developing synthetic procedures that produce well-defined platinum and palladium metal nanoparticles in the 1-5 nm size range. Thioether ligands were used as stabilizers and resulted in metal nanoparticles with controlled size. The nanoparticles were characterized using transmission electron microscopy (TEM), x-ray diffraction (XRD), selected area electron diffraction (SAED), x-ray photoelectron spectroscopy …

A Metaevaluation Of Energy Efficiency Evaluations, Brandy Brown

Dissertations

This study systematically reviews the methodological characteristics of energy efficiency evaluations and uses metaevaluation to assess its quality. Metaevaluation is used to systematically assess the quality of evaluation products, confirm that evaluations deliver sound findings and conclusions, are useful to the client, are credible, are ethically conducted, and are done as cost-effective as possible. The results of this study show that the ability to accurately assess evaluation for methodological quality using evaluations reports as a primary data source depends on the presence of detailed descriptions of evaluation methods. Furthermore, the study suggests that methodological variations of energy efficiency evaluations coalesce …

Synergy Of The Developed 6d Bim Framework And Conception Of The Nd Bim Framework And Nd Bim Process Ontology, Shawn Edward O'Keeffe

Dissertations

The author developed a unified nD framework and process ontology for Building Information Modeling (BIM). The research includes a framework developed for 6D BIM, nD BIM, and nD ontology that defines the domain and sub-domain constructs for future nD BIM dimensions. The nD ontology defines the relationships of kinds within any new proposed dimensional domain for BIM. The developed nD BIM framework and ontology takes into account the current 2D-5D BIM dimensions. There is a synergy between the 6D and nD framework that allows the nD framework and ontology to be utilized as a unified template for future dimensional development. …

Organic Solar Cells Based On High Dielectric Constant Materials: An Approach To Increase Efficiency, Khalil Jumah Tawfiq Hamam

Dissertations

The efficiency of organic solar cells still lags behind inorganic solar cells due to their low dielectric constant which results in a weakly screened columbic attraction between the photogenerated electron-hole system, therefore the probability of charge separating is low. Having an organic material with a high dielectric constant could be the solution to get separated charges or at least weakly bounded electron-hole pairs. Therefore, high dielectric constant materials have been investigated and studied by measuring modified metal-phthalocyanine (MePc) and polyaniline in pellets and thin films. The dielectric constant was investigated as a function of temperature and frequency in the range …

Compositional And Structural Analysis Of Nitrogen Incorporated And Ion Implanted Diamond Thin Films, Elias James Garratt

Dissertations

Significant progress in area of nano-structured thin film systems has taken place in recent decades. In particular, diamond thin film systems are being widely studied for their wear resistant, optical and electronic properties. Of the various methods researchers use to modify the structure of such films, three techniques in particular are of interest due to their versatility: modification of the growth atmosphere, growth on metalized substrates, providing an interfacial layer, and modification through post-growth ion implantation. The aim of this study is to investigate the effects each has to the structure and composition of elements. Different techniques are applied in …

Tropical Cyclone Intensity Estimation Using Temporal And Spatial Features From Satellite Data, Gholamreza Fetanat Haghighi

Dissertations

Accurate intensity estimation of tropical cyclones (TC) is an important topic of research due to its economic impact and public safety concerns. An accurate measure of the current wind strength is necessary to accurately predict TC intensity. We have developed and tested automated method to estimate TC intensity based on the existing historical satellite images alone. The Hurricane Satellite data (HURSAT-B1) is used to develop the algorithm, which focuses on the North Atlantic from 1978-2009. The algorithm is trained and validated using aircraft reconnaissance-based data. Here, the data is restricted to include only fixes that are over water and are …

Adaptive Security-Aware Scheduling For Packet Switched Networks Using Real-Time Multi-Agent Systems, Ma'en Saleh Saleh

Dissertations

Conventional real-time scheduling algorithms are in care of timing constraints; they don’t pay any attention to enhance or optimize the real-time packet’s security performance. In this work, we propose an adaptive security-aware scheduling with congestion control mechanism for packet switching networks using real-time agentbased systems. The proposed system combines the functionality of real-time scheduling with the security service enhancement, where the real-time scheduling unit uses the differentiated-earliest-deadline-first (Diff-EDF) scheduler, while the security service enhancement scheme adopts a congestion control mechanism based on a resource estimation methodology.

The security service enhancement unit was designed based on two models: singlelayer and weighted …

Error Estimation Techniques To Refine Overlapping Aerial Image Mosaic Processes Via Detected Parameters, William Glenn Bond

Dissertations

In this paper, I propose to demonstrate a means of error estimation preprocessing in the assembly of overlapping aerial image mosaics. The mosaic program automatically assembles several hundred aerial images from a data set by aligning them, via image registration using a pattern search method, onto a GIS grid.

The method presented first locates the images from a data set that it predicts will not align well via the mosaic process, then it uses a correlation function, optimized by a modified Hooke and Jeeves algorithm, to provide a more optimal transformation function input to the mosaic program. Using this improved …

Leach-Sm: A Protocol For Extending Wireless Sensor Network Lifetime By Management Of Spare Nodes, Bilal Abu Bakr

Dissertations

Operational lifetime of a wireless sensor network (WSN) depends on its energy resources. Significant improvement of WSN lifetime can be achieved by adding spare sensor nodes to WSN. Spares are ready to be switched on when any primary (a node that is not a spare) exhausts its energy. A spare replacing a primary becomes a primary itself.

The LEACH-SM protocol (Low-Energy Adaptive Clustering Hierarchy with Spare Management) proposed by us is a modification of the prominent LEACH protocol. LEACH extends WSN lifetime via rotation of cluster heads but allows for inefficiencies due to redundant sensing target coverage. There are two …

Investigating Fabrication Methods For Micro Single-Chamber Solid Oxide Fuel Cells, Man Yang

Dissertations

A Solid Oxide Fuel Cell (SOFC) is a green energy technology that offers a cleaner and efficient alternative to fossil fuels. The efficiency and utility of SOFCs can be enhanced by fabricating miniaturized component structures within the fuel cell footprint. This research focuses on the microfabrication of parallel-connected inter-digitized design of micro single chamber SOFC (μ-SC-SOFCs). In this dissertation, candidate micro/nano fabrication techniques to precisely fabricate micro patterns on planar substrates have been studied. These include EBL, soft lithography, photolithography, and direct-writing. After analyzing preliminary results, two combinational approaches were further investigated. The first method involves the combination of the …