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Polyhedral Oligomeric Silsesquioxane-Phosphate Glass Matrix Nanocomposites With Additional Chapter On Phosphate Glass-Poly(Ethylene Terephthalate) Matrix Composites, Kyoungtae Kim
Dissertations
Preparation and characterization of tin fluorophosphate glass (Pglass) matrix nanocomposites incorporating polyhedral oligomeric silsesquioxane (POSS) were investigated on the structural, thermal, morphological, mechanical, and rheological properties. Various processes including synthesis, extrusion and sintering processes were applied to prepare the nanocomposite samples. Another application of POSS with hydrophobic functional groups on the well-structured nanoscale silicate cage with three silanol groups was investigated to present the feasibility to use POSS molecule as a coating material on the surface of the hydrophilic inorganic glass. In addition, Poly(ethylene terephthalate) polymer matrix composites incorporating Pglass was studied to present the benefits of the Pglass with …
Studies On Controlling The Morphology Of An Organic Bulk-Heterojunction Photovoltaic Device To Improve Its Efficiency, Kelly R. Mcleod
Studies On Controlling The Morphology Of An Organic Bulk-Heterojunction Photovoltaic Device To Improve Its Efficiency, Kelly R. Mcleod
Honors Theses
A systematic study of the effects of alteration of processing parameters in combination with incorporation of polyhedral oligomeric silsesquioxane (POSS) molecules on the properties and structure of bulk heterojunction organic photovoltaic cells made from P3HT:PCBM blends was undertaken. On implementing the correct processing protocol, incorporation of POSS molecules with specific structures resulted in considerable enhancement in cell efficiencies. Octaaminophenyl POSS incorporation resulted in a 20% increase in cell efficiency over the control and caused the formation of crystalline, fiber-like structures in the active layer of the photovoltaic cell.