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Materials Science and Engineering Faculty Research & Creative Works

Phase transitions

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Full-Text Articles in Engineering

Effects Of Specimen Size And Yttria Concentration On Mechanical Properties Of Single Crystalline Yttria-Stabilized Tetragonal Zirconia Nanopillars, Ning Zhang, Mohsen Asle Zaeem Jul 2017

Effects Of Specimen Size And Yttria Concentration On Mechanical Properties Of Single Crystalline Yttria-Stabilized Tetragonal Zirconia Nanopillars, Ning Zhang, Mohsen Asle Zaeem

Materials Science and Engineering Faculty Research & Creative Works

The nanoscale plastic deformation of yttria-stabilized tetragonal zirconia (YSTZ) is highly dependent on the crystallographic orientations, i.e., dislocation is induced when the loading direction is 45° tilted to {111} and {101} slip planes, while tetragonal to monoclinic phase transformation dominates the plastic deformation when loading direction is perpendicular to the slip planes. This study investigates the effects of specimen size and yttria concentration on the mechanical response of single crystalline YSTZ nanopillars. Through uniaxial compression test, the smaller-is-stronger phenomenon is revealed in nanopillars deformed through a dislocation motion mechanism. Serrated stacking faults are observed in the smallest nanopillar, while neat …


Nanoscale Mechanical Switching Of Ferroelectric Polarization Via Flexoelectricity, Yijia Gu, Zijian Hong, Jason Britson, Long-Qing Chen Jan 2015

Nanoscale Mechanical Switching Of Ferroelectric Polarization Via Flexoelectricity, Yijia Gu, Zijian Hong, Jason Britson, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

Flexoelectric coefficient is a fourth-rank tensor arising from the coupling between strain gradient and electric polarization and thus exists in all crystals. It is generally ignored for macroscopic crystals due to its small magnitude. However, at the nanoscale, flexoelectric contributions may become significant and can potentially be utilized for device applications. Using the phase-field method, we study the mechanical switching of electric polarization in ferroelectric thin films by a strain gradient created via an atomic force microscope tip. Our simulation results show good agreement with existing experimental observations. We examine the competition between the piezoelectric and flexoelectric effects and provide …


Electric-Field Induced Ferromagnetic Phase In Paraelectric Antiferromagnets, Maya D. Glinchuk, Eugene A. Eliseev, Yijia Gu, Long-Qing Chen, Venkatraman Gopalan, Anna N. Morozovska Jan 2014

Electric-Field Induced Ferromagnetic Phase In Paraelectric Antiferromagnets, Maya D. Glinchuk, Eugene A. Eliseev, Yijia Gu, Long-Qing Chen, Venkatraman Gopalan, Anna N. Morozovska

Materials Science and Engineering Faculty Research & Creative Works

The phase diagram of a quantum paraelectric antiferromagnet EuTiO33 under an external electric field is calculated using Landau-Ginzburg-Devonshire theory. The application of an electric field E in the absence of strain leads to the appearance of a ferromagnetic (FM) phase due to the magnetoelectric (ME) coupling. At an electric field greater than a critical field, Ecr, the antiferromagnetic (AFM) phase disappears for all considered temperatures, and FM becomes the only stable magnetic phase. The calculated value of the critical field is close to the values reported recently by Ryan et al. [Nat. Commun. 4, 1334 (2013)10.1038/ncomms2329] …


Low-Symmetry Monoclinic Ferroelectric Phase Stabilized By Oxygen Octahedra Rotations In Strained Euₓsr₁₋ₓtio₃ Thin Films, Anna N. Morozovska, Yijia Gu, Victoria V. Khist, Maya D. Glinchuk, Long-Qing Chen, For Full List Of Authors, See Publisher's Website. Apr 2013

Low-Symmetry Monoclinic Ferroelectric Phase Stabilized By Oxygen Octahedra Rotations In Strained Euₓsr₁₋ₓtio₃ Thin Films, Anna N. Morozovska, Yijia Gu, Victoria V. Khist, Maya D. Glinchuk, Long-Qing Chen, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

Using Landau-Ginzburg-Devonshire theory and phase-field modeling, we explore the complex interplay between a structural order parameter (oxygen octahedron rotation) and polarization in EuxSr1-xTiO3 thin films. Under a biaxially tensile strain, a low-symmetry monoclinic phase with in-plane ferroelectric polarization is found to be stabilized by antiferrodistortive oxygen octahedra tilts. The monoclinic phase is stable over a wide temperature range. It is characterized by a large number of energetically equivalent polar and structural twin domains. This work demonstrates the development of a spontaneous polarization and piezo- and pyroelectricity in a ferroelastic twin boundary arising from flexoelectric coupling …


Universal Emergence Of Spatially Modulated Structures Induced By Flexoantiferrodistortive Coupling In Multiferroics, Eugene A. Eliseev, Sergei V. Kalinin, Yijia Gu, Maya D. Glinchuk, Victoria V. Khist, For Full List Of Authors, See Publisher's Website. Jan 2013

Universal Emergence Of Spatially Modulated Structures Induced By Flexoantiferrodistortive Coupling In Multiferroics, Eugene A. Eliseev, Sergei V. Kalinin, Yijia Gu, Maya D. Glinchuk, Victoria V. Khist, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

We proved the existence of a universal flexoantiferrodistortive coupling as a necessary complement to the well-known flexoelectric coupling. The coupling is universal for all antiferrodistortive systems and can lead to the formation of incommensurate, spatially modulated phases in multiferroics. Our analysis can provide a self-consistent mesoscopic explanation for a broad range of modulated domain structures observed experimentally in multiferroics.