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University of New Orleans Theses and Dissertations

Theses/Dissertations

Thermoelectric

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Studies On Structure And Property Of Polymer-Based Nano-Composite Materials, Yun Zhai May 2013

Studies On Structure And Property Of Polymer-Based Nano-Composite Materials, Yun Zhai

University of New Orleans Theses and Dissertations

The mixing of polymers and nanoparticles makes it possible to give advantageous macroscopic material performance by tailoring the microstructure of composites. In this thesis, five combinations of nano inclusion and polymer matrix have been investigated.

The first type of composites is titanium dioxide/ polyaniline combination. The effects of 4 different doping-acids on the microstructure, morphology, thermal stability and thermoelectric properties were discussed, showing that the sample with HCl and sulfosalicylic dual acids gave a better thermoelectric property. The second combination is titanium dioxide/polystyrene composite. Avrami equation was used to investigate the crystallization process. The best fit of the mass derivative …