Engineering Commons^™

Engineering Order-Disorder Transitions For High-Performance Thermoelectric Fe2val Heusler Alloys, Cory T. Cline

Dartmouth College Ph.D Dissertations

Fe₂VAl shows great promise as an eco-friendly and low-cost replacement to conventional low-temperature (250-500 K) thermoelectric materials. Current thermoelectric materials use toxic and expensive elements like Te and Sb, whereas Fe₂VAl offers a larger power factor at a lower cost and a reduced risk of environmental pollution. The key issue with Fe₂VAl is the alloy’s relatively large thermal conductivity compared to its semiconductor competitors. This thesis aims to investigate a hierarchical approach to reduce lattice thermal conductivity through a preliminary exploration of heavy element substitutions and mechanical deformation, then through probing order-disorder transitions for …

Materials Design For Energy Applications Using Ab- Initio Calculations, Hind Hemaidee Alqurashi

Graduate Theses and Dissertations

The structural, dynamical, electronic, and thermoelectric properties of rock-salt and wurtzite Cd1-xZnxO alloys, VTiRhZ (Al, Ga, In, Si, Ge, Sn) and ZrTiRhZ (Ge, Sn) quaternary Heusler alloys (QHAs) were investigated using density functional theory (DFT) and semi-classical Boltzmann transport theory. From these calculations, the alloys were identified as potential materials for future thermoelectric applications. Furthermore, the magnetic and spin-polarization properties of these QHAs were investigated. The total magnetic moments were found to be integer values for all QHAs. In addition, all studied QHAs except VTiRhAl possess a half-metallic behavior with a 100% spin-polarization. The half-metallic ferromagnetic behavior makes them promising …

Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya

Doctoral Dissertations

The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …

Development And Characterization Of Nanofiber-Based Thermoelectric And Piezoelectric Composites, Julio Enrique Trevino

Theses and Dissertations

This study focuses on the development and characterization of nanofiber-based composites with the goal of developing flexible, lightweight, and cost effective thermoelectric and piezoelectric devices. The following materials were used in the development of the composites: polyvinylidene fluoride (PVDF) with polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), polycarbazole (PCZ), polyacrylonitrile (PAN), functionalized multi-walled carbon nanotubes (MWCNT-COOH), and camphorsulfonic acid (CSA). Blends and in-situ polymerization techniques were utilized to increase the desired thermoelectric/piezoelectric response. Nanofiber systems were produced utilizing the Forcespinning® technique. The morphology, structure, electrochemical, thermal stability, thermoelectric, and piezoelectric performance was analyzed. All of the nanofiber PVDF/CP …

Exploring A Platinum Nanocatalytic Microcombustion-Thermoelectric Coupled Device, Dylan Moore Mcnally

Theses and Dissertations

This work aimed to create a first-generation power device for eventual application to portable electronics. A platinum nanoparticle catalytic substrate was employed in a microcombustion-thermoelectric coupled (MTC) device for the purpose of chemical-to-electrical energy conversion. Multiple microcombustion reactors were designed, fabricated, and investigated. Most importantly, the reactor configuration was designed to accommodate thermoelectric generators (TEGs) for power production. Temperature studies with catalytic combustion of methanol-air fuel mixtures were used to evaluate the thermal power generation performance of each reactor. The final reactor design enabled ignition at room temperature with the ability to achieve repeat catalytic cycles upon subsequent exposure to …

The Design, Fabrication, And Testing Of A Cooling Garment, Richard James Garza

Theses and Dissertations

The aim of this research is to design a device or technology capable of cooling the user – such as a college student walking to class, for example – in a manner as convenient as putting on a jacket. The idea is to use the peltier effect – a phenomenon in which two dissimilar semi-conductors heat up and cool down with the application of an electric current – as the source of heat absorption used to cool the user. In this research it will be determined whether or not it is feasible to use such a phenomenon to keep the …

Investigation Of The Structural, Electronic, And Thermoelectric Properties Of Mono- Chalcogenides, Aida Sheibani

Graduate Theses and Dissertations

The structural, electronic, and thermoelectric properties of GeTe are studied using density functional theory and Boltzmann transport equations. This material has a rhombohedral crystal structure in ambient temperature with a ferroelectric behavior due to lack of inversion symmetry. This study suggests that the presence of asymmetry in GeTe can lead to an improvement in the thermoelectric properties of this material. In addition, studies on introducing Group III, IV, and V dopants to GeSe show that while these impurities can improve the power factor and decrease the lattice thermal conductivity, they cannot enhance the figure of merit.

Doping With Rare Earth Elements And Resultant Nano-Inclusions On The Electrical And Thermal Properties Of The Mis-Fit Layered Thermoelectric Oxide, Geoffroy Gauneau

Graduate Theses, Dissertations, and Problem Reports

Thermoelectric generators produce electricity by directly converting temperature differences into electrical energy through Seebeck effect. Thermoelectric generators possess many unique features, such as having no moving part and being very reliable with a relatively long lifespan once built. They are solid-state waste heat harvesters. With various waste heat available throughout many industries, thermoelectric generators could offer economically competitive renewable energy. The current state of the art thermoelectric materials includes materials with relatively toxic elements and must work under vacuum, making them quite expensive to produce. Among the various thermoelectric materials, ceramic oxides have been proved to be more chemically stable …

Theoretical Investigations Of The Electronic, Magnetic, And Thermoelectric Properties Of Transition-Metal Based Compounds, Haleoot Edaan Raad

Graduate Theses and Dissertations

The electronic, magnetic, and thermoelectric properties of transition-metal based compounds were investigated by using the density functional theory and Boltzmann transport formalism. It was found that the Co-based Heusler compounds and InSe monochalcogenide are among the materials that may be used for future thermoelectric devices. Furthermore, the investigation showed that the quaternary Heusler compounds, such as, CoFeYGe, where Y is Ti or Cr, are half-metallic ferromagnetic materials with full electron spin polarization. The lattice thermal conductivity (κL) was found to decrease for these alloys as the temperature increases. The present investigation indicated that the phonon optical modes have a major …

A Study Of Catalytic Microcombustion For A Portable Power Supply Device, Bhanuprakash Reddy Guggilla

Theses and Dissertations

The essential need for portable and dense power sources has been greatly increased with the prevalence of portable electronic devices in the past decade. Catalytic combustion of hydrocarbon and oxygenated fuels has the potential to provide an alternative power source for portable electronic devices by replacing relatively today's heavy battery technology. A successful self-ignition and sustainable catalyst combustion for a variety of fuels using Platinum (Pt)-impregnated substrate was demonstrated in our previous work.

Present work explores the performance of a microcombustion thermoelectric coupled (MTC) device with improved reactor configuration design. Chemically synthesized platinum nanoparticles with particle diameters of approx. 8 …

Driver Cooling System, Joseph Fatin Bolous, Jake Donald Deboer, Alvin Theodore Lau

Mechanical Engineering

This document provides our Final Design Review (FDR) for the Driver Cooling System Project. It contains our background research, which includes current product research, technical research, and information on our sponsor’s needs as a customer as well our manufacturing process, test results, and final design. We created a problem statement to define the scope of the project, discuss sponsor and consumer needs and wants, and technical specifications. After brainstorming, we ultimately selected a thermoelectric cooling system (TEC) after presenting our Preliminary Design Report and Critical Design Report. We built the final prototype, as can be seen in the manufacturing plan, …

Morphological And Energetic Effects On Charge Transport In Conjugated Polymers And Polymer-Nanowire Composites, Zhiming Liang

Theses and Dissertations--Chemistry

Organic semiconductors have wide applications in organic-based light-emitting diodes, field-effect transistors, and thermoelectrics due to the easily modified electrical and optical properties, excellent mechanical flexibility, and solution processability. To fabricate high performance devices, it is important to understand charge transport mechanisms, which are mainly affected by material energetics and material morphology. Currently it is difficult to control the charge transport properties of new organic semiconductors and organic-inorganic nanocomposites due to our incomplete understanding of the large number of influential variables. Molecular doping of π-conjugated polymers and surface modification of nanowires are two means through which charge transport can be manipulated. …

Fabrication And Thermoelectric Characterization Of Stretchable Conductive Latex-Based Composites, Cory Michael Arcovitch

Graduate College Dissertations and Theses

Miniaturized stretchable electronic devices that can be bent and strained elastically without breaking, have drawn considerable research interest in recent years for wearable computers and integrated bio-sensor applications. Portable electrical power harvesting remains a critical challenge in flexible electronics materials. One proposed solution has been to convert waste heat from the human body into electricity using thermoelectric materials. Traditionally, however, these materials are brittle ceramic semiconductors with limited fracture resistance under deformation. The primary objective of this thesis is to address this challenge by fabricating and studying the mechanical, thermal and electrical performance of stretchable composites combining natural latex polymer …

Analytical Study Of Miniature Thermoelectric Device, Mohammed Dhannoon

Masters Theses

Miniature thermoelectric devices (TE) have been regarded as hopeful devices to attain efficient cooling in microprocessors and other small-scale devices. To recognize the performances of miniature thermoelectric coolers, a thermoelectric cooling module is theoretically analyzed. Particular attention is paid to the impact of the thermoelectric element length effect and the substrate material type influence on the cooling performance. The electrical contact resistance and thermal contact are taken into account.

Furthermore, miniature thermoelectric is compared with large thermoelectric, and effective material properties of miniature thermoelectric are studied. The obtained results also demonstrate power density (cooling/heating power per unit area of the …

Optimal Design Of Automotive Exhaust Thermoelectric Generator (Aeteg), Hassan Fagehi

Masters Theses

A consumption of energy continues to increase at an exponential rate, especially in terms of automotive spark ignitions vehicles. About 40% of the applied fuel into a vehicle is lost as waste exhaust to the environment. The desire for improved fuel efficiency by recovering the exhaust waste heat in automobiles has become an important subject. The thermoelectric generator (TEG) has the potential to convert exhaust waste heat into electricity as long as it is improving fuel economy. The remarkable amount of research being conducted on TEGs indicates that this technology will have a bright future in terms of power generation. …

Analytical Modeling And Numerical Simulation Of A Thermoelectric Generator Including Contact Resistances, Shripad Dhoopagunta

Masters Theses

With increasing demand for energy harvesting systems, research has been conducted in different areas in which Thermoelectric Generators (TEG) find their way into the top of many available resources. Out of many energy harvesting systems available, TEGs are comparatively easier to study, to manufacture and also to comprehend while producing enough energy for applications they find use in. They are solid state devices, meaning; they do not have any moving parts and hence makes them durable. Most of the energy that goes out of the automobile as exhaust is reused to power the TEGs. In most of the works that’s …

Design, Modeling And Simulation Of A Thermoelectric Cooling System (Tec), Pooja Iyer Mani

Masters Theses

Thermoelectric Devices are solid state devices which directly convert thermal energy to electrical energy and vice versa. In the recent past, a lot of effort has been made to improve the performance and also the power generated by a thermoelectric device. This is done by attaching heat sinks on either sides of the device. Optimizing heat sinks improves the overall efficiency of it but on the other hand the device also has to be optimized. TECs are mostly used for electronic cooling where the heated electronic devices serve as target that needs to be cooled while air acts as a …

Thermoelectric Half-Heuslers: Synthesis, Processing, And Performance, Joseph Robert Croteau

Boise State University Theses and Dissertations

Thermoelectric half-Heusler compounds have potential to convert the heat wasted from industrial and transportation processes to useful electricity. Among the highest performing half-Heusler compounds are nano-structured bulk materials which have been arc-melted, pulverized into a nano-powder, and sintered by DC-hot press. High performing n- and p-type half-Heusler compounds with nominal composition of Hf_0.25Zr_0.75NiSn_0.99Sb_0.01 and Nb_0.75Ti_0.25FeSb, respectively, have been provided to us in both dense and powder form by our collaborators at the University of Houston. We consolidate these powders by SPS, refine these powders to improve both particle size …

Prosthetic Socket Cooling System, Benjamin K. Kraw, Kathy Ha, Derek Piastrelli, Cuong Lai

Mechanical Engineering

A team of four senior-level undergraduate students in the Interdisciplinary Senior Project Design course in the Engineering Department of California Polytechnic State University: San Luis Obispo have worked to develop a prosthetic socket cooling system, namely for veteran Taylor Morris and exclusively for a transfemoral prosthetic socket, under the Quality of Life+ Laboratory. This cooling system will utilize the thermoelectric effect known as the Peltier effect to transmit heat generated from the residual limb to the surrounding environment by means of forced convection over small aluminum heat sinks. Two measurement devices have also been developed to, one, measure the heat …

Theory Of Carrier Transport From First Principles: Applications In Photovoltaic And Thermoelectric Materials, Alireza Faghaninia

McKelvey School of Engineering Theses & Dissertations

New sources of energy that are environmentally friendly, cost-effective, and renewable are essential if we are to combat the effects of global climate change. Two of these sources are solar photovoltaic (PV) cells to convert sunlight into electricity and thermoelectric (TE) devices to convert heat to electricity. To be practical on a large scale, the properties (e.g. electrical conductivity, band gap, Seebeck coefficient, etc) of the the underlying materials must be improved significantly through judicious control of structure and composition. Significant understanding of materials properties is required to design and engineer new high-performing materials. First principles calculations using density functional …

New Approaches To Chalcogenide Materials For Thermoelectrics: Lead Telluride-Based Nanostructures And Facile Synthesis Of Tetrahedrite And Doped Derivatives, Derak Justin James

Wayne State University Dissertations

The overall purpose of this work is to address several of the roadblocks to use of thermoelectric materials for generation of electricity, namely inefficient processing of materials and low performance, commonly rated by the figure of merit, ZT=T2/tot. The ZT includes  as the Seebeck coefficient,  as electrical resistivity, T as the average temperature, and tot as total thermal conductivity. tot is the sum of electronic charge carrier (C) and lattice (L) contributions to thermal conductivity. Attempts to increase ZT in the literature to values >1 have focused on decreasing the thermal conductivity via nanostructuring or optimizing the electrical …

An Experimental Investigation Towards Improvement Of Thermoelectric Properties Of Strontium Titanate Ceramics, Arash Mehdizadeh Dehkordi

All Dissertations

The direct energy conversion between heat and electricity based on thermoelectric effects is a topic of long-standing interest in condensed matter materials science. Experimental and theoretical investigations in order to understand the mechanisms involved and to improve the materials properties and conversion efficiency have been ongoing for more than half a century. While significant achievements have been accomplished in improving the properties of conventional heavy element based materials (such as Bi$_2$Te$_3$ and PbTe) as well as the discovery of new materials systems for the close-to-room temperature and intermediate temperatures, high-temperature applications of thermoelectrics is still limited to one materials system, …

Design And Construction Of A Chemical Engineering (Cheme) Car Using Thermoelectrics, Timothy Barnhill, Sara Davino, Spencer Faltin, Lauryn Jamison, Christina Papadimitrio, Mccall Rogers

Senior Theses

Six chemical engineering undergraduates at the University of South Carolina formed a team to compete in the 2014 AIChE Chem-E-Car competition at the Southern Regional Student Conference in San Juan, Puerto Rico, in March. In the Chem-E-Car competition, students must design and build a vehicle powered by an unconventional form of chemical energy to carry a specified weight over a given distance (1). The group used knowledge gained through undergraduate study to construct a small-scale vehicle that is powered by a set of thermoelectric generators utilizing a heat gradient between boiling water and an ethanol-dry ice mixture (2). An iodine …

Analytical Performance Evaluation Of Thermoelectric Modules Using Effective Material Properties, Sean Lwe Leslie Weera

Masters Theses

Designers often face the predicament of non-standardized forms of performance data provided by thermoelectric module manufacturers. Other than experimental means the only method to evaluate the performance of a product would be through analytical modeling using material properties that are usually undisclosed and unknown. This work studies the theoretical approach of obtaining such material properties using the maximum operating parameters reported by the manufacturers. These values are then analytically employed to evaluate the performances of these thermoelectric modules. Experimental means are also devised and carried out on these test samples to validate the integrity of the results. Three-way comparisons between …

Studies On Structure And Property Of Polymer-Based Nano-Composite Materials, Yun Zhai

University of New Orleans Theses and Dissertations

The mixing of polymers and nanoparticles makes it possible to give advantageous macroscopic material performance by tailoring the microstructure of composites. In this thesis, five combinations of nano inclusion and polymer matrix have been investigated.

The first type of composites is titanium dioxide/ polyaniline combination. The effects of 4 different doping-acids on the microstructure, morphology, thermal stability and thermoelectric properties were discussed, showing that the sample with HCl and sulfosalicylic dual acids gave a better thermoelectric property. The second combination is titanium dioxide/polystyrene composite. Avrami equation was used to investigate the crystallization process. The best fit of the mass derivative …

Novel Automotive Waste Heat Recovery Techniques, John Randall Armstead

Dissertations, Master's Theses and Master's Reports - Open

The United States transportation industry is predicted to consume approximately 13 million barrels of liquid fuel per day by 2025. If one percent of the fuel energy were salvaged through waste heat recovery, there would be a reduction of 130 thousand barrels of liquid fuel per day. This dissertation focuses on automotive waste heat recovery techniques with an emphasis on two novel techniques.

The first technique investigated was a combination coolant and exhaust-based Rankine cycle system, which utilized a patented piston-in-piston engine technology. The research scope included a simulation of the maximum mass flow rate of steam (700 K and …

Synthesis And Physical Properties Of Group 14 Intermetallic Clathrates, Stevce Stefanoski

USF Tampa Graduate Theses and Dissertations

The search of materials relevant for thermoelectric and magnetocaloric applications, as well as materials that interact with light, is an important aspect of the materials science. Such materials can be used for solid-state power generation and refrigeration, as light sources, detectors, or controllers. Intermetallic clathrates have long been of interest for the materials science research. The promise these materials hold for useful applications ranges from thermoelectrics to photovoltaics and optoelectronics to potentially ultra-hard materials and magnetic cooling applications. Their unique physical properties are intimately related to their intriguing structural properties. Thus a fundamental understanding of the chemistry and physics of …

Growth And Characterization Of Functional Nanoparticulate Films By A Microwave Plasma-Assisted Spray Deposition Process, Ted Wangensteen

USF Tampa Graduate Theses and Dissertations

Nanoparticle and nanoparticulate films have been grown by a unique approach combining a microwave and nebulized droplets where the concentration and thus the resulting particle size can be controlled. The goal of such a scalable approach was to achieve it with the least number of steps, and without using expensive high purity chemicals or the precautions necessary to work with such chemicals. This approach was developed as a result of first using a laser unsuccessfully to achieve the desired films and particles. Some problems with the laser approach for growing desired films were solved by substituting the higher energy microwave …

Thermoelectric Properties Of Nickel And Titanium Co-Intercalated Titanium Diselenide, Timothy Holgate

All Dissertations

Thermoelectric materials are involved in the direct conversion between thermal and electrical energy. They may be used to generate power from a thermal gradient or to pump heat in or out of a system when driven with DC power. Much of the recent advances in thermoelectric research have been in materials whose thermoelectric efficiency has been optimized at temperatures above room temperature where power generation is the main application.
The question that I seek to answer in this dissertation is to use our standard experimental techniques in order to assess the possibility of a class of transition metal dichalcogenides bases …

Analytical Modeling And Optimization Of A Thermoelectric Heat Conversion System Operating Betweeen Fluid Streams, Stephen H. Taylor

Theses and Dissertations

Analytical, closed-form solutions governing thermoelectric behavior are derived. An analytical model utilizing a thermal circuit is presented involving heat transfer into, through, out of, and around a thermoelectric device. A nondimensionalization of the model is presented. Linear heat transfer theory is applied to the model to obtain a series of closed form equations predicting net power output for the thermoelectric device. Fluid streams flowing through shrouded heat sinks with square pin fins are considered for the thermal pathways to and from the device. Heat transfer and pressure drop are characterized in a manner conducive to an analytical model using previously …