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Full-Text Articles in Engineering
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou
Shi Xue Dou
Structural and magnetic properties of NdMn2−x Cu xSi2 compounds (x = 0-1.0) have been investigated by high intensity x-ray and resolution neutron diffraction (3-450 K), specific heat, dc magnetization, and differential scanning calorimetry measurements. Substitution of Cu for Mn leads to an increase in the lattice parameter a but a decrease in c at room temperature. Two magnetic phase transitions have been found for NdMn2−x Cu xSi2 compounds with TN for the antiferromagnetic ordering of Mn-sublatttice and TC for the Nd-sublattice ferromagnetic ordering, respectively. TC increases significantly with increasing Cu content from 36 K at x = 0 to 100 …
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou
Shi Xue Dou
The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect at the first order ferromagnetic phase transition at TC, has been investigated in detail. Under a …
Aging Effect Evolution During Ferroelectric-Ferroelectric Phase Transition: A Mechanism Study, Zuyong Feng, Zhenxiang Cheng, Dongqi Shi, S X. Dou
Aging Effect Evolution During Ferroelectric-Ferroelectric Phase Transition: A Mechanism Study, Zuyong Feng, Zhenxiang Cheng, Dongqi Shi, S X. Dou
Shi Xue Dou
Aging can significantly modify the dielectric, piezoelectric, and ferroelectric performance of ferroelectrics. However, little attention has been paid to the aging effect during ferroelectric-ferroelectric phase transitions that is essentially correlated with real applications. In this letter, the authors report the aging effect evolution between two ferroelectric phases in an acceptor-doped piezoceramics. The results show that aging-induced double hysteresis loops were exhibited in different ferroelectric phases, but disappeared during ferroelectric-ferroelectric phase transitions, suggesting the mechanism that the intrinsic restoring force for the reversible switching of domains caused by the alignment of defect dipoles was weakened due to ferroelectric dipole reorientation.
Re-Entrant Ferromagnet Prmn2ge0.8si1.2: Magnetocaloric Effect, S X. Dou, Jianli Wang, Rong Zeng, Chung-Kiak Poh, Stewart J. Campbell, S J. Kennedy
Re-Entrant Ferromagnet Prmn2ge0.8si1.2: Magnetocaloric Effect, S X. Dou, Jianli Wang, Rong Zeng, Chung-Kiak Poh, Stewart J. Campbell, S J. Kennedy
Shi Xue Dou
The structural and magnetic properties of the re-entrant ferromagnet PrMn2Ge0.8Si1.2 have been investigated by various experimental methods. Similar to the canonical re-entrant ferromagnet SmMn2Ge2, multiple magnetic phase transitions have been detected in PrMn2Ge0.8Si1.2 over the temperature range from 10 to 550 K with re-entrant ferromagnetism occurring around ∼ 54 K. The magnetocaloric effect has been measured in terms of the isothermal magnetocaloric entropy change and found to be positive at the re-entrant ferromagnetic transition with a maximum value of around 1.9 J/kg K at 58 K for a magnetic field change of 0–3 T. On the other hand, the entropy …
Correlation Between Structural Parameters And The Magnetocaloric Effect In Epitaxial La0.8ca0.2mno3/Laalo3 Thin Film, J C. Debnath, J H. Kim, Y Heo, A M. Strydom, S X. Dou
Correlation Between Structural Parameters And The Magnetocaloric Effect In Epitaxial La0.8ca0.2mno3/Laalo3 Thin Film, J C. Debnath, J H. Kim, Y Heo, A M. Strydom, S X. Dou
Shi Xue Dou
An epitaxial La0.8Ca0.2MnO3/LaAlO 3 (LCMO/LAO) thin film was fabricated using the pulsed laser deposition technique to evaluate the correlation between the crystal structure and the magnetocaloric effect. In our study, the LCMO film was 200 nm in thickness and appeared to have a strong out-of plane texture. We found that each column in the LCMO thin film layer is a domain which has a different ordering direction. These microscopic feature results in anisotropic properties of magnetization, entropy, and relative cooling power. The film exhibited a paramagnetic-to-ferromagnetic second order phase transition at 249 K. The lack of any hysteresis loss also …
The Magnetocaloric Effect And Critical Behaviour Of The Mn0.94ti0.06coge Alloy, P Shamba, Jianli Wang, J C. Debnath, S J. Kennedy, Rong Zeng, M F Md Din, F Hong, Z X. Cheng, A J. Studer, S X. Dou
The Magnetocaloric Effect And Critical Behaviour Of The Mn0.94ti0.06coge Alloy, P Shamba, Jianli Wang, J C. Debnath, S J. Kennedy, Rong Zeng, M F Md Din, F Hong, Z X. Cheng, A J. Studer, S X. Dou
Shi Xue Dou
Structural, magnetic and magnetocaloric properties of the Mn0.94Ti0.06CoGe alloy have been investigated using x-ray diffraction, DC magnetization and neutron diffraction measurements. Two phase transitions have been detected, at T-str = 235 K and T-C = 270 K. A giant magnetocaloric effect has been obtained at around Tstr associated with a structural phase transition from the low temperature orthorhombic TiNiSi-type structure to the high temperature hexagonal Ni2In-type structure, which is confirmed by neutron study. In the vicinity of the structural transition, at T-str, the magnetic entropy change, -Delta S-M reached a maximum value of 14.8 J kg(-1) K-1 under a magnetic …
Peak Effect In The Critical Current Of Type Ii Superconductors With Strong Magnetic Vortex Pinning, X B. Xu, H Fangohr, X N. Xu, M Gu, Z H Wang, S M. Ji, Shichao Ding, Dongqi Shi, S. X. Dou
Peak Effect In The Critical Current Of Type Ii Superconductors With Strong Magnetic Vortex Pinning, X B. Xu, H Fangohr, X N. Xu, M Gu, Z H Wang, S M. Ji, Shichao Ding, Dongqi Shi, S. X. Dou
Shi Xue Dou
We perform 2D Langevin simulations studying the peak effect (PE) of the critical current taking into account the temperature dependence of the competing forces. We observe and report that the PE results from the competition of vortex-vortex interactions and vortex-pin interactions which have different temperature dependencies. The simulations reveal that the PE can take place only for certain pinning strengths, densities of pinning centres, and driving forces, which is in good agreement with experiments. No apparent vortex order-disorder transition is observed across the PE regime. In addition, the PE is a dynamical phenomenon, and thermal fluctuations can speed up the …
Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou
Effect Of Frozen Spin On The Magnetocaloric Property Of La0.7ca0.3coo3 Polycrystalline And Single Crystal Samples, J C. Debnath, R Zeng, J H. Kim, P Shamba, Dapeng Chen, S X. Dou
Shi Xue Dou
Polycrystalline (PC) and single crystalline (SC) samples of La0.7Ca0.3CoO3 (LCCO) with the perovskite structure were synthesized by conventional solid-state reaction and the floating-zone growth method. We conducted isothermal magnetization measurements of the PC and SC samples at temperatures from 2.8 K to 140 K, and evaluated the magnetic entropy change (−ΔSM) under zero field cooling (ZFC) and field cooling (FC) to 2.8 K. An interesting result has been obtained, where the −ΔSM–T curves in the low temperature range show totally different features between the ZFC and FC cooling procedures. The −ΔSM shows a large inverse irreversibility value for the ZFC …
Multifunctionality From Coexistence Of Large Magnetoresistance And Magnetocaloric Effect In La0.7ca0.3mno3, J. C. Debnath, R. Zeng, J. H. Kim, S. X. Dou
Multifunctionality From Coexistence Of Large Magnetoresistance And Magnetocaloric Effect In La0.7ca0.3mno3, J. C. Debnath, R. Zeng, J. H. Kim, S. X. Dou
Shi Xue Dou
We report the existence of multifunctionality involving large magnetoresistance (MR) and magnetocaloric effect (MCE) near room temperature in La0.7Ca0.3MnO3. A peak in the temperature dependence of the magnetoresistance and a change in the magnetic entropy (ΔSM) are observed at 251 K, with a maximum magnetoresistance MR (defined as ρ(0)∕ρ(H)−1) of about 206% and a maximum ΔSM of approximately 7.54 J∕kgK, at a field of 5 T, where the Curie temperature (TC) and metal‐insulator transition coexist at 251 K. The magnetic entropy change is measured on the basis of resistive measurements, which are close to the values obtained from the M‐H …
A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou
A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou
Shi Xue Dou
We report the synthesis of β−Co(OH)2 nanosheets using microwave assisted hydrothermal and conventional chemical reaction methods. A magnetic transition at an onset temperature, T1 ~ 96 K, and a sign of antiferromagnetic state transition at the Néel temperature, TN=9~10 K, can be determined from M-T curves and M-H curves magnetic properties investigation. It is found that a sign of field-induced first order transition below 9 K, act as a role of reversing the magnetocaloric effect from negative to positive value. The large reversible magnetic-entropy change (∆SM) of 17 J/kg K around 11 K for a field change of 5 T …
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
The Effect Of Reduced Graphene Oxide Addition On The Superconductivity Of Mgb2, K S. B De Silva, S Gambhir, Xiaolin Wang, X Xu, W X. Li, David L. Officer, D Wexler, G G. Wallace, S. X. Dou
Shi Xue Dou
Reduced graphene oxide (rGO) and highly reduced chemically converted graphene (ICCO) samples were prepared under different processing condition! and were doped into MgBz by a diffusion process at 800 °C for 10 houn. It was demonstrated that a small addition rCCG can significantly improve the supcn;onducting properties of MgBz. Doping of M8B2 with 1 mol% of rCCG resulted in a Ie of 5.45 X lOS A cm-2 at 20 K in self-fields, which il nearly 32% improvement over that of the undopcd sample. This is a significant improvement as most carbon sources adversely affect the Ie performance: at the zero …
Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou
Magnetocapacitance Effect In Nonmultiferroic Yfe03 Single Crystal, Z X. Cheng, H Shen, J Xu, Peng Liu, S J. Zhang, Jianli Wang, Xiaolin Wang, S X. Dou
Shi Xue Dou
YFeO3 single crystal displays two relaxor-like dielectric relaxations, one at low temperature (170300 K) and one at high temperature (370520 K), which are attributed to the activation of electrons and oxygen vacancies, respectively. Above the temperature at which electrons are activated, the sample displays a large magnetocapacitance effect. Comparison of the impedance Cole-Cole plots measured with and without applied magnetic field reveals that the occurrence of magnetocapacitance effect is accompanied with an increasing in DC conductivity under magnetic field after the activation of electrons, which is explained by the enhancement of electron jumping in Fe2b-O-Fe3b chains by magnetic field. Thus …
Effect Of Gallium Doping And Ball Milling Process On The Thermoelectric Performance Of N-Type Zno, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou
Effect Of Gallium Doping And Ball Milling Process On The Thermoelectric Performance Of N-Type Zno, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou
Shi Xue Dou
We report a systematic investigation of the thermoelectric properties of n-type Ga-doped ZnO synthesized using different ball milling conditions. Samples fabricated by the high-energy ball milling resulted in a highly dense layered structure with randomly distributed voids. These samples measured the lowest room temperature thermal conductivity, i.e., 27 W/mK due to increased phonon scattering. Furthermore, the Ga:ZnO system showed a metal–semiconductor transition above 300 K with transition temperature decreasing with increasing doping level. Measurement of the activation energy revealed the presence of one donor level around 3.9–7.8 meV and a deeper donor level around 15.4–18.1 meV below the conduction band …
Effect Of Mg/B Ratio On The Superconductivity Of Mgb2 Bulk With Sic Addition, Yun Zhang, S X. Dou, Cheng Lu, Sihai Zhou, Wenxian Li
Effect Of Mg/B Ratio On The Superconductivity Of Mgb2 Bulk With Sic Addition, Yun Zhang, S X. Dou, Cheng Lu, Sihai Zhou, Wenxian Li
Shi Xue Dou
To improve the self-field critical current density (Jc) and critical temperature (Tc) in SiC-doped MgB2, optimization of the nominal Mg/B mixing ratio has been performed. The effects of the nominal Mg/B mixing ratio (x:2) on the superconductivity, Raman spectra, current transport properties, and flux pinning mechanisms in MgB2 with 10 wt.% SiC doping were investigated systematically, with x varied from 1 to 1.2. It has been found that the sample with the Mg/B ratio of 1.15:2 exhibited the best Jc performance for all fields (0–8.5 T), and its Tc was also enhanced. The optimized Mg/B ratio diminished the interband scattering …
Effect Of Boron Powder Purity On Superconducting Properties Of Bulk Mgb2, Xun Xu, Dayse Dos Santos, Jung Ho Kim, Wai Kong Yeoh, Meng J. Qin, Konstantin K. Konstantinov, S. X. Dou
Effect Of Boron Powder Purity On Superconducting Properties Of Bulk Mgb2, Xun Xu, Dayse Dos Santos, Jung Ho Kim, Wai Kong Yeoh, Meng J. Qin, Konstantin K. Konstantinov, S. X. Dou
Shi Xue Dou
In order to study the influence of the amorphous Boron powder on the superconducting properties, MgB2 bulk samples were prepared using 96% and 99% pure commercial Boron powder as well as 92% commercial Boron powder after purification process. The results showed that the original 96% and the purified 92% powders have larger particle size compared to the pure 99% Boron powder, which leads to reduce magnetic critical current densities. In order to get higher performance MgB2, the purified low grade Boron powder need further control of their microstructure such as smaller particle size to enhance flux pinning from the grain …
Effect Of Different Additives On The Hydrogen Storage Properties Of The Mgh 2-Lialh 4 Destabilized System, S X. Dou, Yue Zhao, Xuebin Yu, Mohammad Ismail
Effect Of Different Additives On The Hydrogen Storage Properties Of The Mgh 2-Lialh 4 Destabilized System, S X. Dou, Yue Zhao, Xuebin Yu, Mohammad Ismail
Shi Xue Dou
The hydrogen storage properties of the MgH2-LiAlH4 (4 : 1) composite system with and withoutadditives were studied. 5 wt.% of TiF3, NbF5, NiF2, CrF2, YF3, TiCl3?1/3AlCl3, HfCl4, LaCl3, CeCl3,and NdCl3, respectively, was added to the MgH2-LiAlH4 (4 : 1) mixture, and their catalytic effect wasinvestigated. Temperature programmed desorption results show that addition of metal halides to theMgH2-LiAlH4 (4 : 1) composite system improves the onset desorption temperature. The hydrogendesorption properties of metal halide-doped MgH2-LiAlH4 (4 : 1) composites were also improved ascompared to the undoped MgH2-LiAlH4 (4 : 1) composite. Furthermore, the activation energy andthe change in enthalpy in the …
Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou
Temperature Effect On Microstructure And Electromagnetic Performance Of Polycarbosilane And Sugar-Doped Mgb2 Wires, Andrey V. Shcherbakov, Josip Horvat, Olga V. Shcherbakova, Nikolina Novosel, Emil Babic, S. X. Dou
Shi Xue Dou
The effect of processing temperature on structural and superconducting properties of 10 wt.% sugar- and 10 wt.% PCS-doped MgB2 wires is systematically investigated. It is demonstrated that these dopants significantly enhance the electromagnetic performance of Fe-clad MgB2 superconductor and increase its potential for practical application. The enhancement of in-field critical current density (Jc(Ba)) and upper critical field (Bc2) is due to formation of a large amount of lattice defects caused by impurities and C substitution into the MgB2 crystal lattice. High temperature sintering of sugar-doped sample results in as high Bc2 value as 37 T (at 5 K), which correlates …
Abnormal Magnetic Behaviors And Large Magnetocaloric Effect In Mnps3 Nanoparticles, R Zeng, S Q. Wang, G D. Du, Jianli Wang, J C. Debnath, Precious Shamba, Z Y. Fang, S. X. Dou
Abnormal Magnetic Behaviors And Large Magnetocaloric Effect In Mnps3 Nanoparticles, R Zeng, S Q. Wang, G D. Du, Jianli Wang, J C. Debnath, Precious Shamba, Z Y. Fang, S. X. Dou
Shi Xue Dou
A nanostructured honeycomb lattice consisting of MnPS3 nanoparticles synthesized via the ion-exchange technique was found to have restacked molecular layers stabilized by H2O insertion between the layers. Susceptibility (χ) and heat capacity measurements showed the absence of long range magnetic ordering, at least down to 2 K. However, the χ data showed that the system possesses a high effective Curie temperature, suggesting that the system is in a high spin lattice disordered state. Evaluation of the magnetocaloric effect indicates that the system has a large reversible magnetic-entropy change (−ΔSm) of 6.8 and 12.8 J/kg K and an adiabatic temperature change …
Magnetovolume Effect In Ho2fe17-Xmnx Compounds, Jianli Wang, A J. Studer, S J. Kennedy, R Zeng, S. X. Dou, S J. Campbell
Magnetovolume Effect In Ho2fe17-Xmnx Compounds, Jianli Wang, A J. Studer, S J. Kennedy, R Zeng, S. X. Dou, S J. Campbell
Shi Xue Dou
The structural and magnetic properties of seven compounds in the Ho2Fe17-xMnx series (x = 0-5) have been investigated. The spontaneous magnetization Ms at 10 K exhibits a minimum at x ≈ 3.8 while the 3d-sublattice magnetization MT is found to decrease at ∼ −3.4 μB/per Mn atom compared with the rate of ∼−2.0 μB/per Mn atom expected from a simple dilution model. All of the Ho2Fe17-xMnx compounds exhibit anisotropic thermal expansion below their Curie temperatures leading to the presence of strong magnetovolume effects and Invar-type behavior below TC. An approximately zero volume thermal expansion has been detected between 10 K …
Magnetocaloric Effect In Layered Ndmn2ge0.4si1.6, Jianli Wang, S.J Campbell, J.M Cadogan, A J Studer, Rong Zeng, S. X. Dou
Magnetocaloric Effect In Layered Ndmn2ge0.4si1.6, Jianli Wang, S.J Campbell, J.M Cadogan, A J Studer, Rong Zeng, S. X. Dou
Shi Xue Dou
A giant magnetocaloric effect has been observed in NdMn2Ge0.4Si1.6 associated with the first-order magnetic phase transition from antiferromagnetism to ferromagnetism around TC = 36 K. The magnetic entropy change –ΔSM and adiabatic temperature change ΔTad have been determined from magnetization and specific heat measurements (B = 0–5 T) with –ΔSM calculated by the Maxwell relation and Clausius–Clapeyron method. The values –ΔSMmax = 12.3 J kg−1 K−1 and refrigerant capacity ∼ 95 J/kg for ΔB = 0–2 T as derived from the Maxwell relation, together with the small hysteresis (thermal 2Ge0.4Si1.6 for refrigeration applications.
Magnetic Properties And Magnetocaloric Effect Of (Mn1-Xnix)3sn2(X=0-0.5) Compounds, Rong Zeng, Lin Lu, Jung Ho Kim, Dongqi Shi, Hua-Kun Liu, S. X. Dou, Jianli Wang, Stewart J. Campbell, Zhaoxiang Wang, Y Li, Wenxian Li, M Y. Zhu, Chuanqi Feng
Magnetic Properties And Magnetocaloric Effect Of (Mn1-Xnix)3sn2(X=0-0.5) Compounds, Rong Zeng, Lin Lu, Jung Ho Kim, Dongqi Shi, Hua-Kun Liu, S. X. Dou, Jianli Wang, Stewart J. Campbell, Zhaoxiang Wang, Y Li, Wenxian Li, M Y. Zhu, Chuanqi Feng
Shi Xue Dou
The effects of Ni substitution on the magnetic properties and magnetocaloric effect (MCE) of (Mn1−xNix)3Sn2 compounds (x = 0–0.5) have been investigated by x-ray diffraction and magnetization measurements. It was found that Ni substitution decreases the crystal cell volume and the magnetic transition temperatures compared with pure Mn3Sn2. The MCE for all samples has been calculated from the magnetization data in terms of the isothermal magnetic entropy change ΔSM. The maximum values of ΔSMmax at the magnetic phase transition temperatures resulting from a change in magnetic field of ΔH = 5 T were found to be 28.2 mJ/cm3 K for …