Engineering Commons^™

New Insights Into Disinfection Byproduct Formation And Control: Assessing Dissolved Organic Matter Diffusivity And Chemical Functionality, Ashley Pifer

Graduate Theses and Dissertations

Methods were developed for application of asymmetric flow field-flow fractionation (AF4) and fluorescence parallel factor (PARAFAC) analysis to raw and treated samples from drinking water sources to improve characterizations of dissolved organic matter (DOM) and discover DOM properties correlated to disinfection byproduct (DBP) formation potential (FP). Raw water samples were collected from a reservoir, adjusted to pH 6, 7, and 8 and subjected to (1) jar tests using aluminum sulfate (alum) and (2) treatment with magnetic ion exchange (MIEX^®) resin. Both treatments were followed by DBPFP tests at pH 7. AF4 was used to size DOM in raw …

Wheel Path Wandering Based On Field Data, Wenting Luo

Graduate Theses and Dissertations

The position and width of wheel path on a pavement lane is an important consideration in conducting pavement distress survey, especially for distinguishing longitudinal cracking from fatigue cracking. Currently, the widely used wheel path definition is derived from the LTPP distress manual with fixed width and position, in which the influence of traffic wander on wheel path was overlooked. This thesis attempts to develop a new wheel path definition based on the lateral placement investigation of heavy vehicles' wandering in the field. Generally, the factors influencing vehicle lateral placement can be divided into seven categories, but only four factors are …

Risk Analysis And Reliability Improvement Of Mechanistic-Empirical Pavement Design, Xingqiang Danny Xiao

Graduate Theses and Dissertations

Reliability used in the Mechanistic Empirical Pavement Design Guide (MEPDG) is a congregated indicator defined as the probability that each of the key distress types and smoothness will be less than a selected critical level over the design period. For such a complex system as the MEPDG which does not have closed-form design equations, classic reliability methods are not applicable. A robust reliability analysis can rely on Monte Carlo Simulation (MCS). The ultimate goal of this study was to improve the reliability model of the MEPDG using surrogate modeling techniques and Monte Carlo simulation.

To achieve this goal, four tasks …

Locating And Protecting Facilities Subject To Random Disruptions And Attacks, Hugh Medal

Graduate Theses and Dissertations

Recent events such as the 2011 Tohoku earthquake and tsunami in Japan have revealed the vulnerability of networks such as supply chains to disruptive events. In particular, it has become apparent that the failure of a few elements of an infrastructure system can cause a system-wide disruption. Thus, it is important to learn more about which elements of infrastructure systems are most critical and how to protect an infrastructure system from the effects of a disruption. This dissertation seeks to enhance the understanding of how to design and protect networked infrastructure systems from disruptions by developing new mathematical models and …

An Extension To Particle Polarizability To Predict Coupling Behavior In Periodic Nanoplasmonic Arrays, Drew Dejarnette

Graduate Theses and Dissertations

Plasmonic nanoparticles organized in arrays interact to create spectral patterns which are amplified by individual particle polarizability. It was hypothesized that particle polarizability could be used as a predictor of spectral behavior from far-field interactions within the array. Inter-particle coupling produced an extraordinary peak in extinction efficiency at wavelengths equal to or larger than the single particle plasmon resonance peak. Interactions that produced constructive coupling were found to mimic changes in the particle polarizability model. Testing of the hypothesis was performed using the coupled dipole approximation with parametric characterization of array geometries, giving specific particle size and lattice constant combinations …

A Silicon Carbide Linear Voltage Regulator For High Temperature Applications, Javier Antonio Valle Mayorga

Graduate Theses and Dissertations

Current market demands have pushed the capabilities of silicon to the edge. High temperature and high power applications require a semiconductor device to operate reliably in very harsh environments. This situation has awakened interests in other types of semiconductors, usually with a higher bandgap than silicon's, as the next venue for the fabrication of integrated circuits (IC) and power devices. Silicon Carbide (SiC) has so far proven to be one of the best options in the power devices field.

This dissertation presents the first attempt to fabricate a SiC linear voltage regulator. This circuit would provide a power management option …

Atomistic Simulations Of Defect Nucleation And Intralayer Fracture In Molybdenum Disulphide During Nanoindentation, James A. Stewart

Graduate Theses and Dissertations

Molybdenum disulphide (MoS2) is a layered, hexagonal crystal that has a very low coefficient of friction. Due to this low coefficient of friction, MoS2 has become a well-known solid lubricant and liquid lubricant additive. As such, nanoparticles of MoS2 have been proposed as an additive to traditional liquid lubricants to provide frictional properties that are sensitive to different temperature and pressure regimes. However, to properly design these MoS2 nanoparticles to be sensitive to different temperature and pressure regimes, it is necessary to understand the mechanical response of crystalline MoS2 under mechanical loading. Specifically, the fundamental mechanism associated with the nucleation …

Flexible Circuits For Aerospace Applications With Special Emphasis On Rf Connectors, Abhishek Nareshraj Singh

Graduate Theses and Dissertations

The current work focused on the study of flexible electronic circuits for use in aerospace applications with emphasis on RF Connectors. The electrical and mechanical performance of the flexible circuits was studied and compared to a standard coaxial cable for feasibility study in avionics space. Also, Anisotropic Conductive Films (ACF) are studied for connecting the flexible RF connectors and their performance studied for electrical and mechanical behavior with change in bonding parameters.

Comparison Of Various Pipelined And Non-Pipelined Scl 8051 Alus, Jingyi Zhao

Graduate Theses and Dissertations

This paper describes the development of an 8-bit SCL 8051 ALU with two versions: SCL 8051 ALU with nsleep and sleep signals and SCL 8051 ALU without nsleep. Both versions have combinational logic (C/L), registers, and completion components, which all utilize slept gates. Both three-stage pipelined and non-pipelined designs were examined for both versions. The four designs were compared in terms of area, speed, leakage power, average power and energy per operation. The SCL 8051 ALU without nsleep is smaller and faster, but it has greater leakage power. It also has lower average power, and less energy consumption than …

Ultra-Low Voltage Digital Circuits And Extreme Temperature Electronics Design, Aaron J. Arthurs

Graduate Theses and Dissertations

Certain applications require digital electronics to operate under extreme conditions e.g., large swings in ambient temperature, very low supply voltage, high radiation. Such applications include sensor networks, wearable electronics, unmanned aerial vehicles, spacecraft, and energyharvesting systems. This dissertation splits into two projects that study digital electronics supplied by ultra-low voltages and build an electronic system for extreme temperatures. The first project introduces techniques that improve circuit reliability at deep subthreshold voltages as well as determine the minimum required supply voltage. These techniques address digital electronic design at several levels: the physical process, gate design, and system architecture. This dissertation analyzes …

Dynamical Properties Of Ferroelectric Perovskites (Ba,Sr)Tio3 And Pb(Zr,Ti)O3 Systems From First Principles, Jeevaka Weerasinghe

Graduate Theses and Dissertations

A first-principles-based effective Hamiltonian scheme which incorporates coupling between ferroelectric (FE) and antiferrodistortive (AFD) motions is applied to Pb(Zr,Ti)O₃ alloys. It validates the existence of two modes of E symmetry (rather than the single E(1TO) soft mode) in the 50-75 cm^-1 range for temperatures smaller than 200 K and for compositions falling within the Rhombohedral R3c phase. Coupling between long-range-ordered FE and AFD motions is shown to be the cause of the additional mode and more insight into its nature is provided. This scheme is further used to reveal a field-induced anticrossing involving FE and AFD degrees of …

Characterization And Quantification Of Monomers, Oligomers, And By-Products From Xylan During Biomass Pretreatment, Ching-Shuan Lau

Graduate Theses and Dissertations

Biomass pretreatment generates inhibitory products, which reduce the overall yield of xylose for ethanol production. Understanding of hemicellulose depolymerization into xylose is essential to identify the pretreatment conditions that maximize xylose formation, but minimize the generation of these inhibitory products, such as formic acid and furfural. Thus, the goal of this project is to understand how dilute acid pretreatment parameters affect hemicellulose depolymerization, maximize xylose concentrations, and minimize by-products formation.

To progress towards this goal, rates and mechanisms of hemicellulose release must be determined. Birchwood xylan was used as the starting material to produce xylose oligomers. The hydrolyzed birchwood xylan …

Semiconductor Nanocrystals: From Quantum Dots To Quantum Disks, Zheng Li

Graduate Theses and Dissertations

The bottom-up colloidal synthesis opened up the possibility of finely tuning and tailoring the semiconductor nanocrystals. Numerous recipes were developed for the preparation of colloidal semiconductor nanocrystals, especially the traditional quantum dots. However, due to the lack of thorough understanding to those systems, the synthesis chemistry is still on the empirical level. CdS quantum dots synthesis in non-coordinating solvent were taken as a model system to investigate its molecular mechanism and formation process, ODE was identified as the reducing agent for the preparation of CdS nanocrystals, non-injection and low-temperature synthesis methods developed. In this model system, we not only proved …

Modeling The Adoption Of Identification Standards Within The Healthcare Supply Chain, Angelica Burbano

Graduate Theses and Dissertations

The adoption of identification standards and its associated technology in the healthcare supply chain has been slow over the past twenty five years, despite the evidence of the benefits that can be achieved. The widespread use of identification standards in the form of barcode labeled medical products can contribute to the reduction of point of care errors and can increase the efficiency of healthcare supply chain related processes. This research is focused on the analysis of the adoption of identification standards in the healthcare supply chain with a particular focus on the healthcare provider adoption challenges. The research is divided …

Peptoid Based Slide Coatings For Disease Detection Via Elisa Microarray Analysis, Melissa Lea Hebert

Graduate Theses and Dissertations

Poly-N-substituted glycines (peptoids) are a very versatile family of synthetic molecules that can be customized for any number of applications. In this study, we chose to use peptoids as a foundation for sandwich ELISA microarray analysis with a long term goal of creating an early detection device for complex diseases such as cancer. The peptoids were designed to self-assemble into microspheres to be used in coatings on the surface of the microarray substrates to increase the surface area available for antibody attachment. This increased antibody density would lead to an increase in the microarray analysis sensitivity and dynamic range. Studies …

Plasmonic Pervaporation Via Gold Nanoparticle-Functionalized Nanocomposite Membranes, Aaron Russell

Graduate Theses and Dissertations

Butanol derived from biological feedstocks has significant potential as a liquid fuel source, but the separation methods used in its production can be prohibitively expensive and are therefore currently the subject of extensive research. Pervaporation is a promising membrane process that is effective in butanol separations, but involves a large energy demand. This study examines the possibility of increasing flux and energy efficiency in pervaporation via plasmonic heating of gold nanoparticle-functionalized, polymer nanocomposite membranes (AuNCMs) in lieu of conventional feed heating. An economic analysis demonstrated that plasmonic pervaporation could achieve significant reductions in energy usage and utility cost in butanol …

Optimization Of A Dynamic Hot Water Pretreatment Of Switchgrass Using Catalysis By Carbonation To Maximize Carbochemical Yields, Rohit Tanaji Dhamdere

Graduate Theses and Dissertations

A bio-refinery is a facility that converts renewable bio-resources into value-added chemicals and products. In this context of a bio-refinery, the production of the carbochemicals such as HMF, furfural and organic acids illustrate that multiple products can be produced from a renewable source such as lignocellulosic biomass (switchgrass). Traditionally, carbochemicals such as furfural and HMF are produced using inorganic acids such as H2SO4, HCL, and H3PO4. The use of such acids requires the application of high cost materials of construction such as Hastelloy-C, titanium etc.

The objective of this study is to develop a semi-continuous process for the conversion of …

Optimization Models And Algorithms For Truckload Relay Network Design, Hector Andres Vergara Arteaga

Graduate Theses and Dissertations

Driver turnover is a significant problem for full truckload (TL) carriers that operate using point-to-point (PtP) dispatching. The low quality of life of drivers due to the long periods of time they spend away from home is usually identified as one of the main reasons for the high turnover. In contrast, driver turnover is not as significant for less-than-truckload (LTL) carriers that use hub-and-spoke transportation networks which allow drivers to return home more frequently. Based on the differences between TL and LTL, the use of a relay network (RN) has been proposed as an alternative dispatching method for TL transportation …

Fabrication And Characterization Of Thinner Solid-State Nanopores, Denis Forbi Tita

Graduate Theses and Dissertations

Solid State nanopores that are fabricated by the ion beam sculpting process and electron beam drilling have shown great promise as a sensing device for DNA and protein molecules. Even though biological pores such as the alpha-Haemolysin have been in use for quite some time, the use of solid state Nanopores in single biomolecule detection has been on the rise since the mid 1990s. Solid State nanopores have an advantage over biological pores in that they are more robust, stable, and can be sculpted to any desired size for use in translocation experiments. One of the major challenges in Nanopore …

Delay Insensitive Ternary Logic Utilizing Cmos And Cntfet, Ravi Sankar Parameswaran Nair

Graduate Theses and Dissertations

As digital circuit design continues to evolve due to progress of semiconductor processes well into the sub 100nm range, clocked architectures face limitations in a number of cases where clockless asynchronous architectures require substantially less power, generate less noise, and produce less electromagnetic interference (EMI). This dissertation develops the Delay Insensitive Ternary Logic (DITL) asynchronous design paradigm that combines the designs aspects of similar Dual-Rail asynchronous paradigms and Boolean logic to create a single wire per bit, three voltage signaling and logic scheme.

DITL is designed at the transistor level using multi-threshold CMOS and carbon nanotube (CNT) FETs to develop …

Efficacy Of Geosynthetic Separators And Filters: An Evaluation Of Test Sections In Marked Tree, Arkansas, Ashique Ali Boga

Graduate Theses and Dissertations

Field and laboratory tests were conducted on 18 full-scale, geosynthetic reinforced, roadway test sections located in Marked Tree, Arkansas. Base course, geosynthetic, and subgrade samples were collected, and pavement depth, in-situ density and in-situ hydraulic conductivity measurements were obtained during a geotechnical site investigation. The performance of sections containing geotextile products being used for separation and filtration (Carthage Mills FX-66, Mirafi 570, Propex 2006, Propex 2044, and Propex 4553) was investigated.

Moisture content, sieve analysis, Atterberg limits, modified proctor, specific gravity, and hydraulic conductivity tests were performed on the acquired soil samples. Transmissivity and permittivity testing was conducted on the …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Computer Modeling Of The Influence Of Structure Plan Areas On Tornado Forces, Nashmi Hassan M Alrasheedi

Graduate Theses and Dissertations

The study of the conventional Straight Line (SL) wind flow dominates research into wind loads on structures. Most structure design takes into account only research into SL flow. Few researchers have studied tornado forces on buildings and attempted to distinguish between tornadic wind loads and SL flow loads. Using a computer simulation, this research addresses and distinguishes between the tornadic forces and SL forces on structures. In the numerical simulation, tornado forces and SL forces will be compared on large structure plan areas and on thin structure plan areas. Additionally this research investigates how the increase in the vortex strength …

Design And Implementation Of A Small Electric Motor Dynamometer For Mechanical Engineering Undergraduate Laboratory, Aaron Farley

Graduate Theses and Dissertations

This thesis set out to design and implement a new experiment for use in the second lab of the laboratory curriculum in the Mechanical Engineering Department at the University of Arkansas in Fayetteville, AR. The second of three labs typically consists of data acquisition and the real world measurements of concepts learned in the classes at the freshman and sophomore level. This small electric motor dynamometer was designed to be a table top lab setup allowing students to familiarize themselves with forces, torques, angular velocity and the sensors used to measure those quantities, i.e. load cells and optical encoders. The …

Design Of Orbital Maneuvers With Aeroassisted Cubesatellites, Stephanie Clark

Graduate Theses and Dissertations

Recent advances within the field of cube satellite technology has allowed for the possible development of a maneuver that utilizes a satellite's Low Earth Orbit (LEO) and increased atmospheric density to effectively use lift and drag to implement a noncoplanar orbital maneuver. Noncoplanar maneuvers typically require large quantities of propellant due to the large delta-v that is required. However, similar maneuvers using perturbing forces require little or no propellant to create the delta-v required. This research reported here studied on the effects of lift on orbital changes, those of noncoplanar types in particular, for small satellites without orbital maneuvering thrusters. …

Cross-Linked Pdms Expansion Due To Submersion In Liquid And Supercritical Co2, Teng Yang

Graduate Theses and Dissertations

Characterization of micro/nano-copper particles impregnated Polydimethylsiloxane (PDMS) submersed in supercritical carbon dioxide (scCO2) was studied. The purpose of this investigation was to advance micro-corrosion sensor technology utilizing PDMS and micro-metal particle composite as the sensing element currently under-development. One of the key challenges encountered was the removal of the native oxides inherently existing on the metal particles. Numerous techniques were experimented with to counter this problem at the UA Engineered Micro/Nano Systems Laboratory (EMNSL), with swell-based protocols being identified as the most promising solution. In terms of compatibility to Micro-electro-mechanical Systems (MEMS) fabrication, CO2 is often used in the release …

Energy Consumption And Greenhouse Gas Emissions From Commercial And Manufacturing Sectors Specific Studies On Hvac Equipment And Dairy Processing, Aik Jong Tan

Graduate Theses and Dissertations

Commercial and manufacturing sectors in United States consumed approximately 50% of the total End use energy in 2010. In 2009, 81.5% of the greenhouse gas (GHG) emitted in the United States was energy related. From the broad aspects of commercial and manufacturing sectors; two relatively narrow and specific topics, commercial building's HVAC equipment and dairy processing were chosen to increase the understanding of the energy use and GHG emission in these two sectors. Few published studies related to these two specific areas are available. The first study in this thesis discussed the energy use and GHG emissions by HVAC equipment …

Slope Stability Monitoring Using Remote Sensing Techniques, Omar Alberto Conte Robles

Graduate Theses and Dissertations

During the past six years the Arkansas State Highway and Transportation Department (AHTD) has spent over nine million dollars repairing slope failures that have occurred in the state of Arkansas. Specifically, higher than average precipitation in 2004 and 2008 led to large quantities of slides, all of which were repaired. Two highways, within the state of Arkansas, with known historical movements along or across the highways are being monitored using traditional surveying techniques and advanced remote sensing techniques. These slides, both of which are located in fill slopes. One a 500-foot long slide located north of Chester, Arkansas, within the …

Molecular Dynamics Study Of Diffusion Of O2 Penetrates In Uncrosslinked Polydimethysiloxane (Pdms), Crosslinked Pdms, And Pdms-Based Nanocomposites, Varun Ullal

Graduate Theses and Dissertations

Molecular dynamics simulations are used to study diffusion of O₂ molecules in pure polydimethysiloxane (PDMS), crosslinked PDMS, and PDMS-based nanocomposites. The PDMS chains and penetrates are modeled using a hybrid interatomic potential which treats the Si-O atoms along the chain backbone explicitly while coarse-graining the methyl side groups and penetrates. By tracking the diffusion of penetrates in the system and subsequently computing their mean-squared displacement, diffusion coefficients are obtained. In pure PDMS models of varying molecular weight, diffusivity of the O₂2 penetrates is found to have an inverse relationship with chain length. Simulation models with longer chains …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …