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Enhanced Performance Of 3d Electroactive Polymer Transducers Via Hierarchical Structures, Frederick B. Holness
Enhanced Performance Of 3d Electroactive Polymer Transducers Via Hierarchical Structures, Frederick B. Holness
Electronic Thesis and Dissertation Repository
Conjugated polymers (CPs) are a class of polymers that exhibit a change in size or shape in response to electrical stimuli. The unique combination of electrical and mechanical properties facilitates the fabrication of novel devices in a broad range of applications including: sensors, actuators, and lab-on-a-chip systems. The alternating single and double bonds along the polymer chain of CPs enables their electroactive properties but is also responsible for processability associated with CPs that has limited fabrication methods. Recently a photosensitive CP composite enabling additive manufacturing (AM) of 3D CP structures was developed. However, the introduction of a copolymer for mechanical …
Fabrication Of 3d Conjugated Polymer Structures Via Vat Polymerization Additive Manufacturing, Andrew T. Cullen
Fabrication Of 3d Conjugated Polymer Structures Via Vat Polymerization Additive Manufacturing, Andrew T. Cullen
Electronic Thesis and Dissertation Repository
Conjugated polymers are a class of electromechanically active materials that can produce motion in response to an electric potential. This motion can be harnessed to perform mechanical work, and therefore these materials are particularly well suited for use as sensors and actuators in microelectromechanical systems. Conventional methods to fabricate conjugated polymer actuators result in planar morphologies that limit fabricated devices to simplistic linear or bending actuation modes. To overcome this limitation, this work develops a conjugated polymer formulation and associated additive manufacturing method capable of realizing three-dimensional conductive polymer structures. A light-based additive manufacturing technique known as vat polymerization is …
Additive Manufacturing Process Of 3d Polyaniline Transducers Via Direct Ink Writing, Frederick Benjamin Holness
Additive Manufacturing Process Of 3d Polyaniline Transducers Via Direct Ink Writing, Frederick Benjamin Holness
Electronic Thesis and Dissertation Repository
Electroactive polymers exhibit a change in properties, typically size or shape, in response to electrical stimuli. One class of electroactive polymer of particular interest are the conjugated polymers, whose conjugated backbone structure imparts electrical conductivity. However, this structure imposes processing limitations restricting their form to 2D structures. To overcome this, we develop specially formulated polyaniline- based blends via counter-ion induced thermal doping for the fabrication of 3D conductive structures via direct ink writing. This approach employs multi-material extrusion for the production of structures with passive and active features, rapid device fabrication, and improved design freedom. A model of the thermal …