Engineering Commons^™

Supercapacitors With Gate Electrodes, Tazima Selim Chowdhury

Dissertations

A new approach to improve the capacitance of supercapacitors (SC) is proposed in this study. A typical SC is composed of an anode and a cathode; a separator in between them assures an unintentional discharge of the capacitor. The study focuses on a family of structured separators, either electronically active or passive which are called gates. An active structured separator layer has been fabricated and analyzed. The structured separator has characteristics of electrical diode and is fabricated out of functionalized carbon nanotubes (CNT). Improvement of the overall capacitance of SC, equipped with either active or passive structured separators demonstrated a …

Minimizing Vehicular Traffic Via Optimized Land Use Development For A Sustainable And Equitable Future, Babu Veeregowda

Dissertations

Mixed-use developments and transit-oriented developments are becoming very common in urban areas in an effort to reduce sprawl. Numerous studies have shown that such programs would not be successful unless the mix of land uses and sizes is well-balanced and integrated with the surrounding neighborhood. Developers often ignore this aspect in favor of immediate financial gain and do not realize that there are sustainable financial benefits in land use optimization. In addition, professionals often work with limited logistics, resources, and technical knowledge and therefore struggle in setting goals and suggesting land uses that have less auto dependency based on travel …

Dual Modality Optical Coherence Tomography : Technology Development And Biomedical Applications, Farzana Rahmat Zaki

Dissertations

Optical coherence tomography (OCT) is a cross-sectional imaging modality that is widely used in clinical ophthalmology and interventional cardiology. It is highly promising for in situ characterization of tumor tissues. OCT has high spatial resolution and high imaging speed to assist clinical decision making in real-time.

OCT can be used in both structural imaging and mechanical characterization. Malignant tumor tissue alters morphology. Additionally, structural OCT imaging has limited tissue differentiation capability because of the complex and noisy nature of the OCT signal. Moreover, the contrast of structural OCT signal derived from tissue’s light scattering properties has little chemical specificity. Hence, …

High-Performance Learning Systems Using Low-Precision Nanoscale Devices, Nandakumar Sasidharan Rajalekshmi

Dissertations

Brain-inspired computation promises a paradigm shift in information processing, both in terms of its parallel processing architecture and the ability to learn to tackle problems deemed unsolvable by traditional algorithmic approaches. The computational capability of the human brain is believed to stem from an interconnected network of 100 billion compute nodes (neurons) that interact with each other through approximately 10¹⁵ adjustable memory junctions (synapses). The conductance of synapses is modifiable allowing the network to learn and perform various cognitive functions. Artificial neural networks inspired by this architecture have demonstrated even super-human performance in many complex tasks.

Computational systems based …

Speciation Of Gaseous Oxidized Mercury Molecules Relevant To Atmospheric And Combustion Environments, Francisco J. Guzman

Dissertations

Mercury is a pervasive and highly toxic environmental pollutant. Major anthropogenic sources of mercury emissions include artisanal gold mining, cement production, and combustion of coal. These sources release mostly gaseous elemental mercury (GEM), which upon entering the atmosphere can travel long distances before depositing to environmental waters and landforms. The deposition of GEM is relatively slow, but becomes greatly accelerated when GEM is converted to gaseous oxidized mercury (GOM) because the latter has significantly higher water solubility and lower volatility. Modeling GOM deposition requires the knowledge of its molecular identities, which are poorly known because ultra-trace (tens to hundreds part …

Interventions Of Waterjet Technology In Skin Incisions, Nadi Atalla

Dissertations

This research explores the use of waterjet (WJ) technology in performing skin incisions. The study defines the analytical relationships between the skin properties and the operating parameters of the WJ which include the skin thickness, its elastic modulus, the WJ pressure, the nozzle’s orifice diameter, its stand-off distance and the traverse speed of the WJ as well as the duration of applying the WJ pressure. An analytical model is developed to measure the depth incision of the skin, the water pressure and the water velocity, while using a WJ. Systemization and optimization models that determine the optimal operating parameters levels …

Epitaxial Growth Of Iii-Nitride Nanostructures And Their Optoelectronic Applications, Moab Rajan Philip

Dissertations

Light-emitting diodes (LEDs) using III-nitride nanowire heterostructures have been intensively studied as promising candidates for future phosphor-free solid-state lighting and full-color displays. Compared to conventional GaN-based planar LEDs, III-nitride nanowire LEDs exhibit numerous advantages including greatly reduced dislocation densities, polarization fields, and quantum-confined Stark effect due to the effective lateral stress relaxation, promising high efficiency full-color LEDs. Beside these advantages, however, several factors have been identified as the limiting factors for further enhancing the nanowire LED quantum efficiency and light output power. Some of the most probable causes have been identified as due to the lack of carrier confinement in …

N8- Polynitrogen Stabilized On Carbon-Based Supports As Metal-Free Electrocatalyst For Oxygen Reduction Reaction In Fuel Cells, Zhenhua Yao

Dissertations

The sluggish oxygen reduction reaction (ORR) kinetics at the cathode is one of the key factors limiting the performance of polymer electrolyte membrane fuel cell (PEMFC). Platinum-based materials are the most widely studied catalysts for this ORR reaction while their large-scale practical application in fuel cells is hindered due to their scarcity and low stability. Therefore, highly active, low cost and robust non-Pt catalysts are being developed to overcome the drawbacks. Recently, a novel polynitrogen N8- (PN) stabilized on multiwall carbon nanotube (MWNT) was synthesized under ambient condition for the first time by our group and demonstrated high ORR activities. …

Surface-Enhanced Raman Detection Of Glucose On Several Novel Substrates For Biosensing Applications, Laila Saad Alqarni

Dissertations

The small normal Raman cross-section of glucose is considered to be a major challenge for its detection by Surface Enhanced Raman Spectroscopy (SERS) for medical applications. These applications include blood glucose level monitoring of diabetic patients and evaluation of patients with other medical conditions, since glucose is a marker for many human diseases. This dissertation focuses on Surface-Enhanced Raman Scattering primarily for the detection of glucose. Some experiments also are carried out for the detection of the corresponding enzyme glucose oxidase that is used in electrochemical glucose sensors and in biofuel cells. This project explores the possibility of utilizing Surface …

Workload Allocation In Mobile Edge Computing Empowered Internet Of Things, Qiang Fan

Dissertations

In the past few years, a tremendous number of smart devices and objects, such as smart phones, wearable devices, industrial and utility components, are equipped with sensors to sense the real-time physical information from the environment. Hence, Internet of Things (IoT) is introduced, where various smart devices are connected with each other via the internet and empowered with data analytics. Owing to the high volume and fast velocity of data streams generated by IoT devices, the cloud that can provision flexible and efficient computing resources is employed as a smart "brain" to process and store the big data generated from …

Fouling And Aging In Membrane Filtration : Hybrid Afm-Based Characterization, Modelling And Reactive Membrane Design, Wanyi Fu

Dissertations

Membrane filtration has been extensively used in water and wastewater treatment, desalination, dairy making, and biomass/water separation. However, membrane fouling, aging and insufficient removal efficiency for dissolved organic matters remain major challenges for wider industrial applications. In order to tackle these challenges, this doctoral dissertation investigates mechanisms of membrane fouling and development of antifouling membrane filtration technologies. Specifically, four major research areas are explored: (i) nanoscale physicochemical characterization of the chemically modified polymeric membranes; (ii) quantitative modelling between membrane properties and membrane fouling and defouling kinetics; (iii) development of quantitative structure-activity relationships for membranes that undergo thermal and chemical aging …

“Polysoaps” Via Raft Copolymerization To Form Well-Defined Micelles For Water Remediation And Targeted Drug Delivery Applications, Phillip Pickett

Dissertations

Amphiphilic copolymers have become increasingly important for environmental and biological applications due to their behavioral characteristics in aqueous solution. For example, structurally-tailored statistical amphiphilic copolymers or “polysoaps” can self-assemble into micelles or other architectures in water at various concentrations. Polysoaps may be differentiated from small molecule surfactant micelles in their capability to self-assemble into unimolecular associates (unimolecular micelles) with no dependence on concentration. Such micelles offer enormous potential for dispersion of hydrophobic species in water at high dilution. Importantly, each polymer chain forms its own micelle and upon dilution, these micelles remain intact and capable of dispersing hydrocarbon material in …

Engineering Multifunctional And Morphologically Diverse Polymer Brush Surfaces, Cassandra M. Reese

Dissertations

The combination of surface-initiated polymerization (SIP) and post-polymerization (PPM) serves as a powerful approach to fabricate complex, multifunctional polymer films, which can be precisely tuned for desired surface engineering applications. Careful manipulation of PPM parameters such as reaction conditions, the tethered brush parameters, and the physical properties of the unbound post-modifier greatly influence the depth of penetration of the post-modifier and the polymer brush compositional heterogeneity. This dissertation focuses on engineering polymer brush surfaces with multifunctional chemistries and tunable morphologies by investigating the PPM parameters that dictate the distribution of post-modifiers on grafted polymer brush surfaces.

The first chapter of …

Chemical And Physical Modification Of Thiol-Ene And Epoxy-Amine Networks For Advanced Control Of Gas Transport And Flame Retardant Behavior, Vivek Vasagar

Dissertations

Crosslinked polymers are widely used due to its several advantages not limited to high mechanical strength combined with the easy processability. Despite of its popular usage, the fundamental understanding of polymer structure affecting the desired properties is still lacking. This PhD thesis is in two parts, the first part is devoted to the design and developing a basic understanding of structure and chemical composition dependencies of gas transport, whereas in the second part a fundamental relationship between structure to the fire-retardant properties is established.

Membrane based gas separation technique has attracted interest of selective removal of carbon dioxide gas from …

Bioinspired Glycopolymers: Models To Investigate The Effect Of Saccharide Structure And Concentration On Amyloid Beta Aggregation, Pradipta Kumar Das

Dissertations

Aggregation and subsequent deposition of amyloid-β (Aβ) peptide on neuronal cell membranes have been implicated as a cause of Alzheimer’s disease. Gangliosides in their clustered form seed and promote the Aβ aggregation process. However, the effects of the structure and the concentration of ganglioside saccharides on Aβ aggregation are not well understood. We investigated how the specific structure of saccharides (β-D-galactose and β-D-glucose) affect the aggregation pathways, kinetics, and the aggregated structures of Aβ via in vitro experiments. The effects of the local concentration of saccharides on the Aβ aggregation were also investigated.

To mimic the multivalent effect of the …

Dual-Battery Empowered Green Cellular Networks, Xilong Liu

Dissertations

With awareness of the potential harmful effects to the environment and climate change, on-grid brown energy consumption of information and communications technology (ICT) has drawn much attention. Cellular base stations (BSs) are among the major energy guzzlers in ICT, and their contributions to the global carbon emissions increase sustainedly. It is essential to leverage green energy to power BSs to reduce their on-grid brown energy consumption. However, in order to furthest save on-grid brown energy and decrease the on-grid brown energy electricity expenses, most existing green energy related works only pursue to maximize the green energy utilization while compromising the …

Hardware/Software Co-Design Of A Reconfigurable Accelerator Platform For Fuzzy Logic-Based Spatial Image Processing Filters, Aous Hammad Kurdi

Dissertations

Rapid development in the architecture and fabrication technology of field programmable gate array (FPGA) and system on a chip (SoC) in the last two decades is dramatically increasing the reliability of those devices as a cost-effective alternative for traditional real-time image processing systems. Module reusability nature of FPGA and SoC development decreases design and implementation time noticeably. On-site reconfigurability allows for intensive design alterations to occur at a small cost. This study is presenting the design and implementation of a new hardware accelerator for an edge detector on Xilinx 7 series FPGA devices based on a fuzzy logic approach. The …

Parameter Determination And Modeling Of Transformer Windings For Fast Transients Including Frequency Dependent Effects, Yazid Al-Kraimeen

Dissertations

Power transformers are static devices capable of transferring energy from one electrical circuit to another by means of electromagnetic induction at the same frequency. The most common application of transformers in an electric power system is to step up or down the voltage level of an electric grid. This is essential for the efficient transmission and distribution of electricity from generating plants to different types of consumers. Electrical energy used in residential, commercial and industrial settings is delivered to consumers by means of transformers, which normally operate 24 hours a day, 365 days a year. Therefore, design improvements that result …

Network Equivalents Applied To Transient Analysis Of Large Distribution Systems, Ghassan Abdul-Hussein Bilal

Dissertations

Frequency domain (FD) methods for electromagnetic transient analysis of electric power systems offer outstanding simplicity and accuracy when dealing with distributed parameter elements and components that exhibit frequency-dependent behavior. However, the use of FD methods is usually restricted to the simulation of small and simple networks, since it is commonly believed that their application implies a very large computational burden when compared to time domain methods. This study demonstrates that FD methods can accommodate the detailed simulation of large distribution networks within acceptable computer times and in a very straightforward manner, thus offering an attractive complement or alternative to common …

Embedded Fault Class Detection Methodology For Condition-Based Machine Monitoring And Predictive Maintenance, Nagdev Amruthnath

Dissertations

Ever since the Second Industrial Revolution, manufacturing firms have continuously been working on minimizing the inefficiencies and maximizing the productivity of their system. This objective led to the creation of the Toyota Production System which follows the motto of “making [the] highest quality products at the least cost in the shortest lead time. (Ohno, 1988)” This philosophy is widely recognized and is utilized by various industries today.

Currently, we are going through the Fourth Industrial Revolution (also called, Industry 4.0) where internet technologies are utilized to additionally maximize the productivity in the production processes. Process synchronization is one of the …

Development Of Piezoelectric Sensors And Methodology For Noninvasive Simultaneous Detection Of Multiple Vital Signs, Areen Abdallah Romi Allataifeh

Dissertations

The activity of piezoelectric material linked the applied electric field with the strain generated that can be translated into geometrical variations. Flexible steel substrate exhibits fascinating mechanical properties which enable their integration into the emerging field of flexible microelectronics. This work presents an extended technique based on capacitance-voltage dependency to extract the geometrical variations in thin-film piezoelectric materials deposited on a flexible steel. A 50 μm flexible steel sheet has been sandwiched by two PZT film layers, each of 2.4 μm in thickness deposited by sputtering. An aluminum layer of 370 nm has been deposited above each PZT layer to …