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Full-Text Articles in Engineering

Self-Organized Nanolayers Of Organosilane Molecules, Ocelio V. Lima Dec 2009

Self-Organized Nanolayers Of Organosilane Molecules, Ocelio V. Lima

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

There is a high degree of interest in organic thin films for lightweight, low power, rugged and flexible electronics. Conjugated organic molecules with polycyclic rings are being considered a major enabler of such applications. Due to a surface tension mismatch between the organic molecule with the inorganic support (mainly silicon oxides), molecular packing inside these thin films is often disordered, which suppresses the device performance. There are major efforts focused on modifying the bulk properties, for instance, maximizing orbital overlaps in the solid state, little attention was paid to receive long-range ordered thin films. A novel approach to afford conjugated …


Thermodynamically Consistent Large Deformation Constitutive Model For Glassy Polymers, Ashwani Kumar Goel Dec 2009

Thermodynamically Consistent Large Deformation Constitutive Model For Glassy Polymers, Ashwani Kumar Goel

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Polycarbonate(PC), like most glassy polymers when undergoing large deformations exhibits a very complex thermo-mechanical response. We look at PC as a model glassy polymer and examine its response to changes in loading rate, loading direction and temperature. We show that plastic flow in compression is accompanied by a change in the elastic response of PC from isotropic to anisotropic. This provides the necessity to introduce a new modeling method that can capture these changes. A finite deformation plasticity like thermodynamically consistent model is developed to capture this and the observed rate and temperature dependence. For this modeling method, we need …


The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala Aug 2009

The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Physical aging and plastic flow are known to cause changes in the properties of glassy polycarbonate (PC). Although the individual effects of physical aging and plastic flow have been studied, the combined mechanical and thermal effects have yet to be evaluated for PC at large plastic strains. This work is the first characterization of the combined effects in PC of large plastic flow followed by thermal (physical) aging. To conduct this study, samples were prepared with different extents of plastic compressive strain, up to approximately 50% engineering strain, followed by thermal aging up to 135 °C, with various …


Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira Jun 2009

Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

New applications for polymer composite materials are occurring at a rapid pace today. These include structural components in the energy, transportation, and biomedical fields. Many if not all of these new applications will require that part performance is insured with some degree of sustainable damage. With the growth in the use of composite structures comes the necessity of improved methodologies that can predict more accurately the life and serviceability conditions of composite parts. Damage mechanics in two-phase composite materials is a very complex problem that has challenged researchers for many years. However, most of the available models perform only a …


Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza Apr 2009

Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Multiscale computational techniques play a major role in solving problems related to viscoelastic composite materials due to the complexities inherent to these materials. In the present work, a numerical procedure for multiscale modeling of impact on heterogeneous viscoelastic solids containing evolving microcracks is proposed in which the (global scale) homogenized viscoelastic incremental constitutive equations have the same form as the local scale viscoelastic incremental constitutive equations, but the homogenized tangent constitutive tensor and the homogenized incremental history dependent stress tensor depend on the amount of damage accumulated at the local scale. Furthermore, the developed technique allows the computation of the …