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Civil and Environmental Engineering Faculty Research and Publications

Emerging contaminants

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Full-Text Articles in Engineering

Adsorption Of Organic Micropollutants Onto Biochar: A Review Of Relevant Kinetics, Mechanisms And Equilibrium, Yiran Tong, Patrick J. Mcnamara, Brooke K. Mayer Mar 2019

Adsorption Of Organic Micropollutants Onto Biochar: A Review Of Relevant Kinetics, Mechanisms And Equilibrium, Yiran Tong, Patrick J. Mcnamara, Brooke K. Mayer

Civil and Environmental Engineering Faculty Research and Publications

As an alternative to activated carbon, biochar has been considered for removal of organic micropollutants from water and wastewater via adsorption. This review elaborates on the fundamental basis of adsorption kinetics, mechanisms, and equilibrium with respect to biochar-based adsorption of micropollutants. The objectives include: 1) linking biochar surface properties with adsorption abilities, 2) categorizing the kinetics of adsorption of aqueous-phase organic compounds onto biochar, 3) categorizing the molecular-scale interactions between organic micropollutants and biochar, and 4) reviewing existing quantitative methods for characterizing adsorption equilibrium of organic micropollutants from water onto an adsorbent surface. To fulfill these goals, the relationships among …


Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick Jul 2013

Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick

Civil and Environmental Engineering Faculty Research and Publications

Triclosan is an antimicrobial agent that is discharged to soils with land-applied wastewater biosolids, is persistent under anaerobic conditions, and yet its impact on anaerobic microbial communities in soils is largely unknown. We hypothesized that triclosan enriches for Dehalococcoides-like Chloroflexi because these bacteria respire organochlorides and are likely less sensitive, relative to other bacteria, to the antimicrobial effects of triclosan. Triplicate anaerobic soil microcosms were seeded with agricultural soil, which was not previously exposed to triclosan, and were amended with 1 mg kg−1 of triclosan. Triplicate control microcosms did not receive triclosan, and the experiment was run for …