Open Access. Powered by Scholars. Published by Universities.®
Articles 31 - 58 of 58
Full-Text Articles in Engineering
Role Of Anions On Structure And Pseudocapacitive Performance Of Metal Double Hydroxides Decorated With Nitrogen-Doped Graphene, Nasir Mahmood, Muhammad Nawaz Tahir, Asif Mahmood, Wenlong Yang, Xingxing Gu, Chuanbao Cao, Yawen Zhang, Yanglong Hou
Role Of Anions On Structure And Pseudocapacitive Performance Of Metal Double Hydroxides Decorated With Nitrogen-Doped Graphene, Nasir Mahmood, Muhammad Nawaz Tahir, Asif Mahmood, Wenlong Yang, Xingxing Gu, Chuanbao Cao, Yawen Zhang, Yanglong Hou
Australian Institute for Innovative Materials - Papers
Electrochemical capacitors (EC) bear faster charge-discharge; however, their real applications are still on a long away due to lower capacitance and energy densities which mainly arise from simple surface charge accumulation or/and reaction. Here, a novel synthesis strategy was designed to obtain the purposeful hybrids of nickel cobalt double hydroxide (NiCoDH) with genetic morphology to improve their electrochemical performance as electrode of EC. Nanostructures of metal hydroxides were grown on t he nitrogen-doped graphene (NG) sheets by utilizing defects as nucleation sites and their composition was optimized both by tuning the ratio of Ni:Co as well as the counter halogen …
Mesoporous Hexagonal Co3o4 For High Performance Lithium Ion Batteries, Dawei Su, Xiuqiang Xie, Paul Munroe, S X. Dou, Guoxiu Wang
Mesoporous Hexagonal Co3o4 For High Performance Lithium Ion Batteries, Dawei Su, Xiuqiang Xie, Paul Munroe, S X. Dou, Guoxiu Wang
Australian Institute for Innovative Materials - Papers
Mesoporous Co3O4 nanoplates were successfully prepared by the conversion of hexagonal beta-Co(OH)(2) nanoplates. TEM, HRTEM and N-2 sorption analysis confirmed the facet crystal structure and inner mesoporous architecture. When applied as anode materials for lithium storage in lithium ion batteries, mesoporous Co3O4 nanocrystals delivered a high specific capacity. At 10 degrees C current rate, as-prepared mesoporous Co3O4 nanoplates delivered a specific capacity of 1203 mAh/g at first cycle and after 200 cycles it can still maintain a satisfied value (330 mAh/g). Fromex-situ TEM, SAED and FESEM observation, it was found that mesoporous Co3O4 nanoplates were reduced to Li2O and Co …
Sulfur-Graphene Nanostructured Cathodes Via Ball-Milling For High-Performance Lithium-Sulfur Batteries, Jiantie Xu, Jianglan Shui, Jianli Wang, Min Wang, Hua-Kun Liu, S X. Dou, In-Yup Jeon, Jeong-Min Seo, Jong-Beom Baek, Liming Dai
Sulfur-Graphene Nanostructured Cathodes Via Ball-Milling For High-Performance Lithium-Sulfur Batteries, Jiantie Xu, Jianglan Shui, Jianli Wang, Min Wang, Hua-Kun Liu, S X. Dou, In-Yup Jeon, Jeong-Min Seo, Jong-Beom Baek, Liming Dai
Australian Institute for Innovative Materials - Papers
Although much progress has been made to develop high-performance lithium-sulfur batteries (LSBs), the reported physical or chemical routes to sulfur cathode materials are often multistep/complex and even involve environmentally hazardous reagents, and hence are infeasible for mass production. Here, we report a simple ball-milling technique to combine both the physical and chemical routes into a one-step process for low-cost, scalable, and eco-friendly production of graphene nanoplatelets (GnPs) edge-functionalized with sulfur (S-GnPs) as highly efficient LSB cathode materials of practical significance. LSBs based on the S-GnP cathode materials, produced by ball-milling 70 wt % sulfur and 30 wt % graphite, delivered …
The Synergistic Effect Between Wo3 And G-C3n4 Towards Efficient Visible-Light-Driven Photocatalytic Performance, Imran Aslam, Chuanbao Cao, M Tanveer, Waheed S. Khan, Muhammad Nawaz Tahir, Muhammad Abid, Faryal Idrees, Faheem K. Butt, Zulfiqar Ali, Nasir Mahmood
The Synergistic Effect Between Wo3 And G-C3n4 Towards Efficient Visible-Light-Driven Photocatalytic Performance, Imran Aslam, Chuanbao Cao, M Tanveer, Waheed S. Khan, Muhammad Nawaz Tahir, Muhammad Abid, Faryal Idrees, Faheem K. Butt, Zulfiqar Ali, Nasir Mahmood
Australian Institute for Innovative Materials - Papers
We have developed a facile, scaled up, efficient and morphology-based novel WO3-g-C3N4 photocatalyst with different mass ratios of WO3 and g-C3N4. It was used for the photodegradation of rhodamine B (RhB) under visible light irradiation and it showed excellent enhanced photocatalytic efficiency as compared to pure g-C3N4 and WO3. The apparent performance of the composite/hybrid was 3.65 times greater than pure WO3 and 3.72 times greater than pure g-C3N4 respectively, and it was also found to be much higher than the previously reported ones. Furthermore, the optical properties of composite samples were evaluated. The bandgap of composite samples lies in …
Ultra-High Performance, High-Temperature Superconducting Wires Via Cost-Effective, Scalable, Co-Evaporation Process, Ho-Sup Kim, Sang-Soo Oh, Hong-Soo Ha, Dojun Youm, Seung-Hyun Moon, Jung Ho Kim, S X. Dou, Yoon-Uk Heo, Sung-Hun Wee, Amit Goyal
Ultra-High Performance, High-Temperature Superconducting Wires Via Cost-Effective, Scalable, Co-Evaporation Process, Ho-Sup Kim, Sang-Soo Oh, Hong-Soo Ha, Dojun Youm, Seung-Hyun Moon, Jung Ho Kim, S X. Dou, Yoon-Uk Heo, Sung-Hun Wee, Amit Goyal
Australian Institute for Innovative Materials - Papers
Long-length, high-temperature superconducting (HTS) wires capable of carrying high critical current, Ic, are required for a wide range of applications. Here, we report extremely high performance HTS wires based on 5 μm thick SmBa2Cu3O7 − δ (SmBCO) single layer films on textured metallic templates. SmBCO layer wires over 20 meters long were deposited by a cost-effective, scalable co-evaporation process using a batch-type drum in a dual chamber. All deposition parameters influencing the composition, phase, and texture of the films were optimized via a unique combinatorial method that is broadly applicable for co-evaporation of other promising complex materials containing several cations. …
High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou
High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Sodium-ion energy storage, including sodium-ion batteries (NIBs) and electrochemical capacitive storage (NICs), is considered as a promising alternative to lithium-ion energy storage. It is an intriguing prospect, especially for large-scale applications, owing to its low cost and abundance. MoS2 sodiation/desodiation with Na ions is based on the conversion reaction, which is not only able to deliver higher capacity than the intercalation reaction, but can also be applied in capacitive storage owing to its typically sloping charge/discharge curves. Here, NIBs and NICs based on a graphene composite (MoS2/G) were constructed. The enlarged d-spacing, a contribution of the graphene matrix, and the …
Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Australian Institute for Innovative Materials - Papers
Structural phase transitions can be used to alter the properties of a material without adding any additional elements and are therefore of significant technological value. It was found that the hexagonal-SnS2 phase can be transformed into the orthorhombic-SnS phase after an annealing step in an argon atmosphere, and the thus transformed SnS shows enhanced sodium-ion storage performance over that of the SnS2, which is attributed to its structural advantages. Here, we provide the first report on a SnS@graphene architecture for application as a sodium-ion battery anode, which is built from two-dimensional SnS and graphene nanosheets as complementary building blocks. The …
Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Australian Institute for Innovative Materials - Papers
Lead chalcogenides (PbQ, Q = Te, Se, S) have proved to possess high thermoelectric efficiency for both n-type and p-type compounds. Recent success in tuning of electronic band structure, including manipulating the band gap, multiple bands, or introducing resonant states, has led to a significant improvement in the thermoelectric performance of p-type lead chalcogenides compared to the n-type ones. Here, the n-type quaternary composites of (PbTe)0.75(PbS)0.15(PbSe)0.1 are studied to evaluate the effects of nanostructuring on lattice thermal conductivity, carrier mobility, and effective mass variation. The results are compared with the similar ternary systems of (PbTe)1-x(PbSe)x, (PbSe) 1-x(PbS)x, and (PbS)1-x(PbTe)x. The …
High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang
High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang
Australian Institute for Innovative Materials - Papers
Honeycomb-like pure sulfur architectures were synthesized by a cooperative self-assembly strategy, in which a soft template is used to form the porous structure. Their electrochemical performance is significantly improved comparing with the commercial sulfur powder and the as-prepared sulfur without honeycomb morphology. There has been no report on using a soft template to prepare honeycomb-like sulfur particles.
Performance Enhancement Of Single-Walled Nanotube-Microwave Exfoliated Graphene Oxide Composite Electrodes Using A Stacked Electrode Configuration, Dennis Antiohos, Mark S. Romano, Joselito M. Razal, Stephen Beirne, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Jun Chen
Performance Enhancement Of Single-Walled Nanotube-Microwave Exfoliated Graphene Oxide Composite Electrodes Using A Stacked Electrode Configuration, Dennis Antiohos, Mark S. Romano, Joselito M. Razal, Stephen Beirne, Phil Aitchison, Andrew I. Minett, Gordon G. Wallace, Jun Chen
Australian Institute for Innovative Materials - Papers
We report the development of a stacked electrode supercapacitor cell using stainless steel meshes as the current collectors and optimised single walled nanotubes (SWNT)-microwave exfoliated graphene oxide (mw rGO) composites as the electrode material. The introduction of mw rGO into a SWNT matrix creates an intertwined porous structure that enhances the electroactive surface area and capacitive performance due to the 3-D hierarchical structure that is formed. The composite structure was optimised by varying the weight ratio of the SWNTs and mw rGO. The best performing ratio was the 90% SWNT-10% mw rGO electrode which achieved a specific capacitance of 306 …
Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder
Australian Institute for Innovative Materials - Papers
A long-standing technological challenge to the widespread application of thermoelectric generators is obtaining high-performance thermoelectric materials from abundant elements. Intensive study on PbTe alloys has resulted in a high figure of merit for the single-phase ternary PbTe-PbSe system through band structure engineering, and the low thermal conductivity achieved due to nanostructuring leads to high thermoelectric performance for ternary PbTe-PbS compounds. Recently, the single-phase p-type quaternary PbTe-PbSe-PbS alloys have been shown to provide thermoelectric performance superior to the binary and ternary lead chalcogenides. This occurs via tuning of the band structure and from an extraordinary low thermal conductivity resulting from high-contrast …
Mechanically Strong High Performance Layered Polypyrrole Nano Fibre/Graphene Film For Flexible Solid State Supercapacitor, Sha Li, Chen Zhao, Kewei Shu, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu
Mechanically Strong High Performance Layered Polypyrrole Nano Fibre/Graphene Film For Flexible Solid State Supercapacitor, Sha Li, Chen Zhao, Kewei Shu, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Paper like flexible electrode becomes one of the most important research objects recently in request of the fast expanding market of portable electronics. Flexible solid state supercapacitors are shortlisted as one of the most promising energy devices to power electronics with medium to high power density requirements. In this work, we developed a simple but effective way to produce a mechanically strong and electrochemically active RGO/polypyrrole (PPy) fibre paper. A well-bedded microstructure was created with interlaced polypyrrole fibres evenly distributed between the graphene layers. Such microstructure can create enormous amount of pores and therefore provides larger interfaces for charge carrier …
Enhanced Performance Of Dye-Sensitized Solar Cells Using Carbazole-Substituted Di-Chromophoric Porphyrin Dyes, Long Zhao, Pawel Wagner, Anastasia Elliott, Matthew Griffith, Tracey M. Clarke, Keith C. Gordon, Shogo Mori, Attila Mozer
Enhanced Performance Of Dye-Sensitized Solar Cells Using Carbazole-Substituted Di-Chromophoric Porphyrin Dyes, Long Zhao, Pawel Wagner, Anastasia Elliott, Matthew Griffith, Tracey M. Clarke, Keith C. Gordon, Shogo Mori, Attila Mozer
Australian Institute for Innovative Materials - Papers
The purpose of this work is to investigate the origin of improved photovoltaic performance of a series of di-chromophoric carbazole-substituted porphyrin dyes employed as sensitizers in dye-sensitized solar cells. Five di-chromophoric zinc porphyrin dyes with the same porphyrin core, a carbazole unit attached in the meso-position through a phenylethenyl linkage, and substituents spanning a range of electron affinities, in an attempt to tune the electronic level of the carbazole unit, have been synthesized (CZPs). Density functional theory (DFT) calculations predicted the nature of the electronic transitions observed in the CZP systems, showing a large degree of orbital mixing. In contrast, …
A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace
A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
A conducting polymer (CP) based bioelectric battery provides a promising alternative to commercial lithium batteries to drive biomedical devices. However, the low power density limits practical application. Here, we synthesize a polypyrrole (PPy)/anthraquinone sulfonate (AQS)/reduced graphene oxide (r-GO) composite via a facile electrochemical route, and use this as a novel cathode material for bioelectric batteries. The presence of r-GO significantly enhanced the electrochemical properties of PPy and led to greatly improved cell performance compared to that of PPy/AQS. The resultant PPy/AQS/r-GO composite delivered a maximum power density of 6240.5 mW m(-2), 14.2 times higher than that of PPy/p-toluenesulfonate (pTS) as …
Fabrication Of Graphene Foam Supported Carbon Nanotube/Polyaniline Hybrids For High-Performance Supercapacitor Applications, Hongxia Yang, Nan Wang, Qun Xu, Zhimin Chen, Yumei Ren, Joselito M. Razal, Jun Chen
Fabrication Of Graphene Foam Supported Carbon Nanotube/Polyaniline Hybrids For High-Performance Supercapacitor Applications, Hongxia Yang, Nan Wang, Qun Xu, Zhimin Chen, Yumei Ren, Joselito M. Razal, Jun Chen
Australian Institute for Innovative Materials - Papers
A large-scale, high-powered energy storage system is crucial for addressing the energy problem. The development of high-performance materials is a key issue in realizing the grid-scale applications of energy-storage devices. In this work, we describe a simple and scalable method for fabricating hybrids (graphenepyrrole/ carbon nanotube-polyaniline (GPCP)) using graphene foam as the supporting template. Graphene-pyrrole (G-Py) aerogels are prepared via a green hydrothermal route from two-dimensional materials such as graphene sheets, while a carbon nanotube/polyaniline (CNT/PANI) composite dispersion is obtained via the in situ polymerization method. The functional nanohybrid materials of GPCP can be assembled by simply dipping the prepared …
Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou
Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou
Australian Institute for Innovative Materials - Papers
We propose an economical fabrication concept, the localized internal magnesium diffusion (IMD) method. Instead of using a single magnesium (Mg) rod in the center of a metal sheath tube, we use large-sized Mg particles (20-50 mesh) mixed well with cheap 97% crystalline boron powder to fill the metal sheath tube. After a repeated drawing process, the coarse Mg is elongated along the core wire axis of the metal sheath tube. Textured MgB2 grains are then formed during the sintering process. In the localized IMD process, however, there is still a need to improve the overall density. In order to increase …
A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou
A Significant Improvement In Both Low- And High-Field Performance Of Mgb2 Superconductors Through Graphene Oxide Doping, K S B De Silva, S H Aboutalebi, Xun Xu, Xiaolin Wang, W X Li, Konstantin Konstantinov, S X. Dou
Australian Institute for Innovative Materials - Papers
The effects of graphene oxide (GO) doping on the superconducting properties of MgB2 were studied using bulk samples made by the diffusion method. Homogeneous dispersions of GO in tetrahydrofuran were obtained through a novel synthesis method, which is then chemically doped with MgB2. It was found that GO doping significantly improves the critical current density, under both low and high magnetic fields, which distinguishes GO from all the other elements doped into MgB2 so far. 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou
A Facile Route To Synthesize Transition Metal Oxide/Reduced Graphene Oxide Composites And Their Lithium Storage Performance, Chongjun Zhao, Shulei Chou, Yunxiao Wang, Cuifeng Zhou, Hua-Kun Liu, S X. Dou
Australian Institute for Innovative Materials - Papers
Transition metal oxide (Mn3O4, Fe2O3, Co3O4, and ZnO) and reduced graphene oxide (RGO) composites were successfully synthesized via a hydrothermal method using the direct reaction between the corresponding metal powder and graphene oxide (GO). In this process, the GO can be reduced by transition metal powder in water, and the nanosized metal oxide can be obtained, and homogeneously mixed with and wrapped by RGO to form a metal oxide/RGO composite at the same time. X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopy were used to characterize the as-prepared materials. The different experimental parameters, including reactants, …
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Simple Synthesis Of Yolk-Shelled Znco2o4 Microspheres Towards Enhancing The Electrochemical Performance Of Lithium-Ion Batteries In Conjunction With A Sodium Carboxymethyl Cellulose Binder, Jingfa Li, Jiazhao Wang, David Wexler, Dongqi Shi, Jianwen Liang, Hua-Kun Liu, Shenglin Xiong, Yitai Qian
Australian Institute for Innovative Materials - Papers
Mixed metal oxides have been attracting more and more attention recently because of their advantages and superiorities, which can improve the electrochemical performance of single metal oxides. These advantages include structural stability, good electronic conductivity, and reversible capacity. In this work, uniform yolk-shelled ZnCo2O4 microspheres were synthesized by pyrolysis of ZnCo-glycolate microsphere precursors which were prepared via a simple refluxing route without any precipitant or surfactant. The formation process of the yolk-shelled microsphere structure during the thermal decomposition of ZnCo-glycolate is discussed, which is mainly based on the heterogeneous contraction caused by non-equilibrium heat treatment. The performances of the as-prepared …
Cation Exchange At Semiconducting Oxide Surfaces: Origin Of Light-Induced Performance Increases In Porphyrin Dye-Sensitized Solar Cells, Matthew J. Griffith, Kenji Sunahara, Akihiro Furube, Attila J. Mozer, David L. Officer, Pawel Wagner, Gordon G. Wallace, Shogo Mori
Cation Exchange At Semiconducting Oxide Surfaces: Origin Of Light-Induced Performance Increases In Porphyrin Dye-Sensitized Solar Cells, Matthew J. Griffith, Kenji Sunahara, Akihiro Furube, Attila J. Mozer, David L. Officer, Pawel Wagner, Gordon G. Wallace, Shogo Mori
Australian Institute for Innovative Materials - Papers
The origin of simultaneous improvements in the short-circuit current density (Jsc) and open-circuit voltage (Voc) of porphyrin dye-sensitized TiO2 solar cells following white light illumination was studied by systematic variation of several different device parameters. Reduction of the dye surface loading resulted in greater relative performance enhancements, suggesting open space at the TiO2 surface expedites the process. Variation of the electrolyte composition and subsequent analysis of the conduction band potential shifts suggested that a light-induced replacement of surface-adsorbed lithium (Li+) ions with dimethylpropylimidazolium (DMPIm+) ions was responsible for an increased electron lifetime by decreasing the recombination with the redox mediator. …
Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton
Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton
Australian Institute for Innovative Materials - Papers
Aqueous dispersions of reduced graphene oxide (rGO) and multi walled carbon nanotubes (MWCNT) were fabricated through a modified chemical reduction method. The significant advantage of the method developed here is the omission of any stabilising compound or organic solvent to obtain stable rGO-MWCNT dispersions. Significantly biological entities, in this case the enzyme glucose oxidase (GOx), can be successfully incorporated into the dispersion. These dispersions were characterised using XPS, SEM, zeta potential and particle size measurements which showed that the dispersion stability is not sacrificed with the addition of GOx, and significantly, the electrical properties of the rGO and MWCNTs are …
Evaluation Of Encapsulating Coatings On The Performance Of Polypyrrole Actuators, Sina Naficy, Nicholas Stoboi, Philip G. Whitten, Geoffrey M. Spinks, Gordon G. Wallace
Evaluation Of Encapsulating Coatings On The Performance Of Polypyrrole Actuators, Sina Naficy, Nicholas Stoboi, Philip G. Whitten, Geoffrey M. Spinks, Gordon G. Wallace
Australian Institute for Innovative Materials - Papers
Conjugated polymer actuators are electroactive materials capable of generating force and movement in response to an applied external voltage. Many potential biomedical and industrial applications require these actuators to operate in a liquid environment. However, immersion of uncoated conducting polymer actuators in non-electrolyte liquids greatly reduces their operating lifetime. Here, we demonstrate the use of spray coating as an effective and simple method to encapsulate polypyrrole (PPy) tri-layer bending actuators. Poly(styrene-b-isobutylene-b-styrene) (SIBS) was used as an encapsulating, compliant spray coating on PPy actuators. A significant enhancement in actuator lifetime in both air and water was observed by encapsulating the actuators. …
Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng
Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng
Australian Institute for Innovative Materials - Papers
Highly uniform, relatively large area TiO2/SnO 2/carbon hybrid nanofibers were synthesized by a simple method based on thermal pyrolysis and oxidation of an as-spun titanium-tin/polyacrylonitrile nanoweb composite in an argon atmosphere. This novel composite features the uniform dispersion and encapsulation of highly uniform nanoscale TiO 2/SnO2 crystals in a porous carbon matrix. The high porosity of the nanofiber composite material, together with the conductive carbon matrix, enhanced the electrochemical performance of the TiO 2/SnO2/carbon nanofiber electrode. The TiO 2/SnO2/carbon nanofiber electrode displays a reversible capacity of 442.8 mA h g-1 for up to 100 cycles, and exhibits excellent rate capability. …
Improved Photovoltaic Performance Of Dye-Sensitized Solar Cells With Modified Self-Assembling Highly Ordered Mesoporous Tio2 Photoanodes, Ziqi Sun, Jung Ho Kim, Yue Zhao, Fargol Bijarbooneh, Victor Malgras, S X. Dou
Improved Photovoltaic Performance Of Dye-Sensitized Solar Cells With Modified Self-Assembling Highly Ordered Mesoporous Tio2 Photoanodes, Ziqi Sun, Jung Ho Kim, Yue Zhao, Fargol Bijarbooneh, Victor Malgras, S X. Dou
Australian Institute for Innovative Materials - Papers
Strategies for improving the photovoltaic performance of dye-sensitized solar cells (DSSCs) are proposed by modifying highly transparent and highly ordered multilayer mesoporous TiO2 photoanodes through nitrogen-doping and top-coating with a light-scattering layer. The mesoporous TiO2 photoanodes were fabricated by an evaporation-induced self-assembly method. In regard to the modification methods, the light-scattering layer as a top-coating was proved to be superior to nitrogen-doping in enhancing not only the power conversion efficiency but also the fill factor of DSSCs. The optimized bifunctional photoanode consisted of a 30-layer mesoporous TiO2 thin film (4.15 mm) and a Degussa P25 light-scattering top-layer (4 mm), which …
Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani
Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani
Australian Institute for Innovative Materials - Papers
"The application of thin titania films by atomic layer deposition on top of a low temperature nanoparticulate TiO2 electrode was found to enhance the performance of dye sensitized solar cells. Dynamic measurements of photoinduced charge extraction showed that the atomic layer deposited top coat increased the electron lifetime at the same electron density. This was attributed to an increased electron trap concentration, which resulted in slower charge transport and increased charge carrier lifetimes.
Preparation, Characterization, And Electrochemical Performance Of Li2cusno4 And Li2cusnsio6 Electrodes For Lithium Batteries, Atef Y. Shenouda, Hua-Kun Liu
Preparation, Characterization, And Electrochemical Performance Of Li2cusno4 And Li2cusnsio6 Electrodes For Lithium Batteries, Atef Y. Shenouda, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Lithium copper tin silicon oxide was prepared from their precursor compounds using Brij surfactant and different sources of Si such as SiO2, SiC, and Si3N4. A hydrothermal autoclave method was used in the first stage of the preparation. X-ray diffraction characterization revealed that the crystal structures of these compounds were tetragonal. Scanning electron microscope investigation showed that the particle size morphology of Li2CuSnSiO6 is larger than that of Li2CuSnO4. Electrochemical impedance spectroscopy explained that the cell prepared from the Li2CuSnSiO6 electrode using Si3 …
High Field Performance Of Nano-Diamond Doped Mgb2 Superconductor, Arpita Vajpayee, V P. Awana, H Kishan, Anant Narlikar, G L. Bhalla, Xiaolin Wang
High Field Performance Of Nano-Diamond Doped Mgb2 Superconductor, Arpita Vajpayee, V P. Awana, H Kishan, Anant Narlikar, G L. Bhalla, Xiaolin Wang
Australian Institute for Innovative Materials - Papers
The results from magnetotransport and magnetization of nanodiamond doped MgB2-nDx are reported. Superconducting transition temperature (Tc) is not affected significantly by x up to x =0.05 and latter decreases slightly for higher x>0.05. R(T) vs H measurements show higher Tc values under same applied magnetic fields for the nanodiamond added samples, resulting in higher estimated Hc2 values. From the magnetization measurements, it was found that irreversibility field value Hirr for the pristine sample is 7.5 T at 4 K and the same is increased to 13.5 T for 3 wt % …
Influence Of Inductance Variation On Performance Of A Permanent Magnet Claw Pole Soft Magnetic Composite Motor, Youguang Guo, Jian Zhu, Zhi Lin, Haiyan Lu, Xiaolin Wang, Jiaxin Chen
Influence Of Inductance Variation On Performance Of A Permanent Magnet Claw Pole Soft Magnetic Composite Motor, Youguang Guo, Jian Zhu, Zhi Lin, Haiyan Lu, Xiaolin Wang, Jiaxin Chen
Australian Institute for Innovative Materials - Papers
Winding inductance is an important parameter in determining the performance of electrical machines, particularly those with large inductance variation. This paper investigates the influence of winding inductance variation on the performance of a three-phase three-stack claw pole permanent magnet motor with soft magnetic composite (SMC) stator by using an improved phase variable model. The winding inductances of the machine are computed by using a modified incremental energy method, based on three-dimensional nonlinear time-stepping magnetic field finite element analyses. The inductance computation and performance simulation are verified by the experimental results of an SMC claw pole motor prototype.