Engineering Commons^™

Rational Design Of Multifunctional Nanocatalysts For Environmental Remediation And Energy Conversion Technologies, Md Ariful Ahsan

Open Access Theses & Dissertations

The discovery of efficient and sustainable carbon-based nanotechnologies to solve both the scarcity of drinking water and global energy crisis has become a paramount task in the last decades. Owed to the fast population growth and industrialization of the modern society, access to potable water and clean energy technologies is becoming very hard around the globe. Water pollutants have become a serious threat to the environment and ecology because of their toxic nature. Parallelly, the current hydrocarbon-based fuel industries are generating high levels of contamination across the planet, making imperative the development of cleaner energy technologies. In this regard, the …

Thermodynamic Modeling Of Aqueous Fe-Cu-As-Sb-Bi-H2so4 Solutions And Its Application For Redox Potential Determination In Copper Electrorefining From 25°C To 70°C, Yongteng Dong

Open Access Theses & Dissertations

Impurity elements in copper electrorefining (ER) electrolyte have been becoming a crucial issue on purity of copper cathode. The objective of this doctoral research is to develop a speciation model to understand impurity behavior in aqueous ER solutions.

A thermodynamic model of Fe(II)-Fe(III)-Cu(II)-H2SO4-H2O system is developed and shown to reliably simulate the species distribution in industrial copper electrorefining electrolyte from 25°C to 70°C. The previously developed model of Fe(II)-Fe(III)-H2SO4-H2O system under leaching conditions was first evaluated. It has proved that its applicability can be extended to much higher acid concentration (185 g/L) and high amount of copper (40-50 g/L). Cu(II) …

Synthesis And Characterization Of Tin (Sn) Incorporated Ga2o3, Guillermo Nicolas Gutierrez

Open Access Theses & Dissertations

In this work, we report on the synthesis, characterization of tin (Sn) incorporated gallium oxide Ga2O3 compounds, also included in this work is the effect of tin concentration related to the optical and electrochemical properties. The Sn incorporation into Ga2O3 creates a significant reduction in the bandgap and causes a nonlinear optical activity as the concentration varies. Substantial investigation performed to the structure, phase, and morphology of the mixed compounds governed by the stoichiometry equation Ga2−2xSnxO3-ɗ indicates that the Sn incorporation from 0.00 ≤ x ≤ 0.30 has a significant effect on these properties. To synthesize the Ga-Sn-O compounds a …

Synthesis, Characterization, And Direct-Ink-Writing Of Syntactic Foams, Andrea Irigoyen

Open Access Theses & Dissertations

This project encompasses three different methods to fabricate syntactic foams using a PDMS matrix i.e., hollow spheres inclusion, pore generator leaching by solvent, and emulsion. The foam formation by using polysiloxane hollow spheres is done in a 3-step process. The first step is to create a core of polystyrene following a dispersion polymerization process. The goal for the size of the pore is to monodisperse and have an average diameter of 5-10 μm, so the polystyrene core must be as well within that range. After that, the cores are coated with a polysiloxane shell by following a polymerization by condensation …

Phase Transformation And Strain Hardening Mechanisms In Advanced Engineering Steels, Hangyu Dong

Open Access Theses & Dissertations

Strain hardening and associated deformation mechanisms play a determining role in the performance of metallic materials. The objective of the doctoral research was to explore and fundamentally understand the strain hardening mechanisms in the next generation of advanced engineering steels. Two main work hardening mechanisms, notably, twinning-induced plasticity (TWIP) and transformation-induced plasticity (TRIP)) were identified that governed strength and ductility. In the nanograined austenitic steel with high strength-high ductility combination, processed by the novel phase reversion concept, twinning-induced plasticity (TWIP) was the governing deformation mechanism and contributed to good ductility. In striking contrast, transformation-induced plasticity (TRIP) was the deformation mechanism …

Microstructure And Hardness Comparison Of Inconel 625 Alloy Of Various Additive Manufacturing Processes Following Heat Treatments, Ariel Gamon

Open Access Theses & Dissertations

This research study presents experimental examples of as-built microstructures and associated microindentation hardnesses (HV) for a variety of metal additive manufacturing (AM) methods for Inconel 625 alloy. Cold spray (CS), laser powder bed fusion (L-PBF), wire arc additive manufacturing (WAAM), electron beam directed energy deposition (EB-DED), laser hot wire (LHW), binder jetting (BJT), and laser power directed energy deposition (LP-DED), laser wire directed energy deposition (LW-DED) and electron beam melting (EBM) were among the techniques employed. Microstructures varied from impact-bonded, flattened grains containing microdendrites and dislocations with a microindentation hardness of HV 590 for cold spray to large, equiaxed grains …

Validation Of Computational Model Of A Piezoelectric Flow Rate Sensor, Eben Roberto Escobedo

Open Access Theses & Dissertations

This study validates a computational simulation of a piezoelectric cantilever beam undergoing different loads by showing a comparison of its results against theoretical calculations. The objective of the computational model is to simulate the behavior of a beam made of a piezoelectric material which can be used as a flow rate sensor due to the ability of the material to convert a mechanical load into an electrical load. After validating the model, different geometries, material properties and loads can be simulated to observe the different behaviors and bring the possibility of selecting the most convenient options according to the needs …

Mechanical Properties And Microstructure Evolution Of Thermally Treated Laser Powder Bed Fusion Alsi10mg, Jorge Merino-Gomez

Open Access Theses & Dissertations

The optimization of mechanical properties with thermal postprocessing treatments was investigated in this study across a wide variety of variants. The relationship between heat treatments and the impacts on the mechanical properties and microstructure of printed materials is a crucial part of additive manufacturing. As a result, the current paper provides a comprehensive overview of postprocess heat treatments for Laser Powder Bed Fusion fabricated AlSi10Mg alloy, including stress relief anneals at 190 and 285 degrees Celsius for 2 hours, hot isostatic pressing at 515 degrees Celsius for 3 hours, hot isostatic pressing + T6 treatment for 6 hours, and final …

Magnesiothermic Combustion Synthesis Of Nanocrystalline Silicon And Oxidation Kinetics Of Magnesium Particles, Sergio Cordova

Open Access Theses & Dissertations

Magnesium (Mg) is a well-known reduction agent in metallurgy (more specifically, in metallothermy). Recently, magnesiothermic reduction of oxides has been used in self-propagating high-temperature synThesis (SHS) of advanced materials such as ultrahigh-temperature ceramics (UHTC). The magnesiothermic SHS has also been used for the conversion of silica (SiO2) to silicon-based materials for thermoelectric applications. However, since oxidation of Mg releases a lot of heat, the direct use of it as the reduction agent leads to excessively high temperatures and undesirable sintering of the products. We have proposed to use magnesium silicide (Mg2Si) instead of Mg in the SHS of nanostructured silicon. …

Structure-Property Relationship In High Strength- High Ductility Combination Austenitic Stainless Steels, Chengyang Hu

Open Access Theses & Dissertations

Austenitic stainless steels are widely used in our daily life, but their mechanical strength is low. In order to improve their yield strength via grain refinement, an investigation was carried out involving phase reversion annealing concept comprising of severe cold roll reduction followed by annealing at different temperatures for short durations. During annealing reversion of deformation-induced martensite to austenite occurred by shear mechanism, leading to fine-grained structure and high strength-high ductility combination.Nanoscale deformation studies suggested that the deformation mechanism of nanograined structure was different from the coarse-grained counterpart. Post-mortem electron microscopy of plastic zone surrounding the indent indicated that the …

Design, Synthesis, And Optimization Of Additively Manufactured Functional Ceramics And Its Composites, Anabel Renteria Marquez

Open Access Theses & Dissertations

The goal of this research consist in the design, synThesis and optimization of functional piezoelectric ceramics and composites that can be fabricated by Direct Ink Write (DIW) 3D printing technique for the use of sensors and energy storage applications. The synThesis optimization of lead-free ceramics for printing was evaluated by analyzing the impact of raw particle size of BaTiO3. A novel approach to evaluate the effect of bimodal distribution raw particle size of BaTiO3 ceramics is presented and their influence on packing density, piezoelectric coefficient and dielectric relative permittivity. Additionally, multi-material DIW printing was adapted as a novel method to …

High Frequency Electron Spin Resonance Investigations On Quasi-Two-Dimensional Chromium Halide Magnets, Christian Saiz

Open Access Theses & Dissertations

Broadening the knowledge and understanding on the magnetic correlations in van der Waals layered magnets is critical in realizing their potential next-generation applications in devices such as spintronics. In this study, we employ high frequency (ν = 120 GHz, 240 GHz) electron spin resonance (ESR) spectroscopy on plate-like CrX3 (where X = Cl, Br, I) to gain insight into the magnetic interactions as a function of temperature (200 – 4.4 K) and the angle of rotation θ (degrees). We find that the temperature dependence of the ESR linewidth is well described by the Ginzburg-Landau critical model, indicative of antiferromagnetic correlations …

New Generation Of Performance-Engineered Asphalt Mixtures Based On Balanced Mix Design Concept, Victor Manuel Garcia

Open Access Theses & Dissertations

Asphalt mixtures must ideally exhibit long-lasting durability and stability to perform wellin the field. However, improving the stability and durability of asphalt mixtures has become a major concern. Given that available design approaches rely mainly on stringent volumetric criteria for asphalt mixtures, design approaches and specifications that incorporate performance tests are needed to follow a performance-engineered mix design (PEMD) process, especially with the introduction of the balanced mix design (BMD) concept

This Dissertation study presents a comprehensive investigation of a feasible designapproach that can be implemented to develop PEMD specifications and produce BMD mixtures. An experimental evaluation of different mix …

Development And Testing Of Nanostructured Materials For Extreme Environment Applications, Nanthakishore Makeswaran

Open Access Theses & Dissertations

Nanostructured materials have many potential applications in the fields of power generation and transportation technologies, particularly in the areas of gas sensing technology, industrial gas turbines and protective coatings. In the former case β-Ga2O3 represents a promising candidate due to its high degree of stability and functionality for oxygen sensing at higher temperatures (>700oC). In the latter case, the application of Y-Si-Fe compounds acting as environmental barrier coatings for gas turbine and aerospace engine applications to protect from corrosion effects has been demonstrated in recent years. In both cases, however, there is room for improvement whether it is in …

Post Processing Of Electron Beam Melted Ti-6al-4v And Binder Jetted 17-4 Stainless Steel, Ahmad Omar Abu-Issa

Open Access Theses & Dissertations

An extensive assortment of HIP parameters have been altered on EBM fabricated Ti-6Al-4V and have shown that cooling rates of 103 oC/min from temperatures above and below the beta transus produced acicular alpha-prime martensite characteristic elongations < 10 %. Optimum yield strength (0.9 GPa), UTS (1.0 GPa) and elongation (~14 %) were achieved for slow cooling (at 102 oC/min) from 850 oC HIP which produced a dense, Widmanstatten alpha structure within the retained, as-fabricated columnar grains by alpha-prime decomposition. These results suggest that manipulation of AM process parameters to produce a small-grain, equiaxed microstructure, HIPed below the beta transus and slow cooled, will have a wide range of superior, isotropic mechanical properties corresponding to a Widmanstatten alpha microstructure within the equiaxed grains. Also, Binder Jetting printing parameters for differing PSD's of low-cost water-atomized 17-4 Stainless Steel were optimized in order to produce high dense parts. Densities ranging from 94-97.5% were achieved, and issues of inhomogeneous porosity were addressed using a fumed silica flow additive.

Synthesis And Characterization Of Functiona Materials For 3d Printed Composites, Elizabeth Irene Reza

Open Access Theses & Dissertations

The following body of work encompasses the synThesis, upscaling, additive manufacturing, and characterization of microspheres as functional fillers incorporated into polymer syntactic foams. Synthesizing microspheres permits control over morphology, dispersion of particles, and size while the use of direct write manufacturing allowed for the controllability of filler orientation. Two different syntactic foams were developed from similar methodologies: (1) a silicone syntactic foam (2) epoxy syntactic foam. The silicone epoxy foam showed an increasing in damping and elastic modulus. The epoxy syntactic foams showed an enhanced thermal and electrical properties.

A Study Of The Frustrated Honeycomb Battery Material Na2ni2teo6, Nathan Christopher Episcopo

Open Access Theses & Dissertations

The P2-type layered hexagonal compound Na2Ni2TeO6 with Ni2+ on a honeycomb lattice was synthesized by the standard solid-state route. Structural characterization chemical phase purity was confirmed by Rietveld refinement of laboratory and synchrotron data. The crystal structure refines well in the P63/mcm space group. Single crystal growth trials using the self-flux-melt method were conducted with limited success. The magnetic transition temperature pertaining to Ni2+ lattice was confirmed by analysis of specific heat capacity to be . The magnetic susceptibility remains largely unchanged in magnetic field of and external pressure of . There is an almost linear response in isothermal magnetization …

Supercritical Processed Decellularized Extracellualr Matrix As Regeneration Therapeutics Applying 3d Printing, Seungwon Chung

Open Access Theses & Dissertations

Extracellular matrix has been broadly applied and show great promise in medical applications and tissue engineering. Product of extracellular matrix (ECM) should be treated with decellularization and purification process. Supercritical carbon dioxide treatment is of particular interest for purifying ECM because of its medically available and rapid speed of process. However, it is not fully researched in treatment of biomaterials for tissue engineering. Therefore, we investigated optimal conditions of supercritical carbon dioxide processing in different extracting parameters from porcine adipose tissue. The 3-day, dual treatment including enzymatic decellularization and supercritical fluid extraction of pork adipose tissue were performed. Two types …

Investigation Of Iron Doped Gallium Oxide (Ga-Fe-O) System: Structure Property Relationship And Performance Evaluation For Optical And Catalytic Applications, Swadipta Roy

Open Access Theses & Dissertations

From September 2012 to May 2015, a phenocam monitored the seaward edge of a protected mangrove forest. Calculated GCC revealed seasonal greening patterns of a mangrove species, Rhizophoa apiculata, and an overall increase in the GCC, suggesting mangrove expansion. In comparing temperature and precipitation effects, it was found that this particular mangrove species had a greening optima at temperatures between 28°C and 28.5°C, and greening and canopy development response lag time of 10 weeks in response to precipitation. Tree saplings were monitored and showed to grow by 50%, mostly during a three month period during the rainy season. The establishment …

Synthesis And Characterization Of Novel Lithium Gallium Phosphate (Ligap2o7) For Extreme Environment Applications, Mohan Raj Rajkumar

Open Access Theses & Dissertations

In this work, we report on the synthesis, characterization, and performance of LiGaP2O7 (LGP), a novel material and fairly new to the scientific & engineering community. LiGaP2O7 materials were was synthesized using the conventional high-temperature, solid-state ceramic reaction. Calcination was done in three steps at the temperatures of 300 °C, 500 °C, and 650 °C for 8 h each to ensure a single phase. Utilizing this, different green pellets were sintered at 800 °C for varying times of 3 h, 6 h, 12 h, and 24 h. The structure, phase, and morphology were analyzed using X-ray diffraction (XRD) and scanning …

Evaluation Of Cyclo Olefin Polymer As Sabot Material For High-Density Projectiles, Estebanne Tarango

Open Access Theses & Dissertations

Assuring the integrity of spacecraft and its occupants are a priority in the field of space exploration. Micrometeoroids and orbital debris are one of the primary threats that affect spacecraft materials due to the high kinetic energies involved with hypervelocity impacts. Improvement of projectile launching capabilities prompts the investigation of adequate materials for the manufacturing of sabots able to carry high-density projectiles without catastrophic failure. Polycarbonate (PC) has been the chosen material by the Hypervelocity Team at White Sands Test Facility for sabots on the 0.50 caliber launcher; however, there is a material constraint when the projectile becomes significantly dense …

Development Of Software Tools And Experimental In Situ Electron Spin Resonance For Characterizing The Magnetic And Electrocatalytic Properties Of Transition Metal Chalcogenide Crystals, Jose Armando Delgado

Open Access Theses & Dissertations

Studying the magnetic properties and crystal defects of transition metal chalcogenide crystals is of paramount importance for utilizing them for next generation spintronics devices and hydrogen evolution reaction catalysts. Hydrothermally grown transition metal chalcogenide nanocrystals (MoS2, Ru2S3, Rh2S3, Co2S8) were chosen as catalysts for the hydrogen evolution reaction due to their low dimensionality and previous utilization as catalysts for hydrodesulfurization. The relationship between crystal defect sites and catalytic activity must be discerned to maximize the efficiency of hydrogen production during the hydrogen evolution reaction. ESR spectroscopy was utilized as a spin sensitive technique to study the defects and local changes …

The Study Of Non-Permanent Tattoo Ink Using Nano Silver Compounds And Untact 3d Printing Technology, Jisu Lee

Open Access Theses & Dissertations

Due to a recent epidemic of COVID 19, the possibility of 3D tattoo printing technology using the Internet of Things (IoT) control system developed in a non-face-to-face contact process was identified. A non-surgical tattoo process and hygiene safety differentiated with silver tattoo ink was used to solve the health problems arising from the surgical tattoo process and to identify 3D tattoo printing techniques through a non-personal contact concept. During the tattoo processing, the image selected by the customer is sent to a designated printer via an IoT control system in a separate location. A piston-type extruder (PTE) printing technique was …

Fabrication, Development, And Characterization Of Hipco Swcnt - Alginate Hydrogel Composites For Cellular Product Applications, Fabian Armando Alvarez-Primo

Open Access Theses & Dissertations

In this study, we designed, synthesized, and characterized ultrahigh purity single-walled carbon nanotube (SWCNT)-alginate hydrogel composites. Among the parameters of importance in the formation of an alginate-based hydrogel composite with single-walled carbon nanotubes, are their varying degrees of purity, their particulate agglomeration and their dose-dependent correlation to cell viability, all of which have an impact on the resultant compositeâ??s efficiency and effectiveness towards biomedical applications. To promote their homogenous dispersion by preventing agglomeration of the SWCNT, at first, we used three different surfactants-sodium dodecyl sulfate (SDS-anionic), cetyltrimethylammonium bromide (CTAB-cationic), and Pluronic F108 (nonionic). After experimentation and corroboration through evidence obtained …

Effect Of Flow Velocity And Geometry On The Signal From A Piezoelectric Flow Rate Sensor, Jad Gerges Aboud

Open Access Theses & Dissertations

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Synthesis And Characterization Of Material Systems For 3d Printed Smart Structures, Hilda Fontes

Open Access Theses & Dissertations

The silica hollow spheres have demonstrated excellent results in multiple applications such as light-weight composites, and optical applications as a glass coating. This material also exhibits excellent thermal, shock impact, and hydrophilic properties extremely useful for industrial applications. However, a controllable size of the particle is desired to further increase the number of applications of the silica hollow spheres.

This Thesis aims a method to fabricate silica hollow spheres in a single step with a controlled diameter size. A study was developed to demonstrate the particle size change when adjusting the molecular weight of the medium by using different alcohol …

Additive Manufacturing Of Engineered Material Systems For Energy Applications, Luis Angel Chavez

Open Access Theses & Dissertations

Despite increasing efforts to use renewable electricity generation techniques in the last couple of decades, the world is still heavily reliant on traditional power generation techniques. This creates the need to make such systems cheaper and less pollutant through improvements to their efficiency. Increasing the efficiency and reliability of energy conversion systems, specially those based on combustion processes has been of interest for many years. However, material limitations have brought these systems to a stagnant condition.

A novel approach to help increase the efficiency of such systems is to closely monitor their operating conditions and therefore be able to increase …

Cmas/Volcanic Ash Infiltration Performance Of Yttria Rich-Zirconia Thermal Barrier Coatings Produced By Electron Beam Physical Vapor Deposition, Juan Jose Gomez Chavez

Open Access Theses & Dissertations

For many years the use of thermal barrier coatings (TBC) in gas turbine engines has allowed a significant increase in engine operating temperatures which are above the Ni-based super alloys' melting point. The base material for TBCs is the state of the art 7 wt % yttria stabilized zirconia (YSZ) which provides the thermal protection. Current industry demands for increased engine efficiency has pushed TBCs to the limits where significant technological constrains have been identified. One of the main ones represents the high temperature corrosion of the TBC material due to the ingestion of silicate based airborne particles commonly referred …

Understanding Of Deformation And Fracture Behavior In Next Generation High Strength-High Ductility Steels, Venkata Sai Yashwanth Injeti

Open Access Theses & Dissertations

The industrial demand for low density high strength steels without compromising on ductility in is endless. In this regards, grain refinement and austenitic stability considered to the practical approach in order to meet the needs. The concept of phase reversion involving sever cold deformation of metastable austenite to generate strain-induced martensite, followed by time-temperature annealing sequence, was used to obtain varying grain size from nanograined/ultrafine-grained (NG/UFG) to coarse-grained (CG) regime. This concept was used to obtain "high strength-high ductility" combination in nano/ultrafine-grained (NG/UFG) austenite stainless steel. Using this concept, the objective of the study here is to elucidate the dependence …

Tailoring The Mechanical And Optical Properties Of Silicon-Niobium-Nitride Composite Coatings, Cristian Orozco

Open Access Theses & Dissertations

Nitride nanocomposite thin films have generated significant attention as a result of their robust mechanical properties, excellent triobology, and good chemical (corrosion) stability. Due to their excellent hardness and high wear resistance NbN coatings have found use in a wide variety of applications such as the coating of cutting tools and to strengthen the surface mechanical properties of superconducting cavities. The mechanical properties of NbN can be further improved through mixing with Si3N4, leading to the formation of a nanocomposite structure. NbN-Si3N4 nanocomposite coatings have been actively studied due to their high hardness, high elastic modulus, and high resistance to …