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Full-Text Articles in Engineering
Centrifugally-Spun Ceramic/Carbon Composite Fibers And Their Use As Anode Materials In Li-Ion Batteries, Gabriel Gonzalez
Centrifugally-Spun Ceramic/Carbon Composite Fibers And Their Use As Anode Materials In Li-Ion Batteries, Gabriel Gonzalez
Theses and Dissertations
The work in this thesis focuses in the study of Centrifugally Spun Short Fiber Composites and their Implementation as Alternate Anode Material in Li-Ion Batteries. Due to their high theoretical capacity, abundance, and environmental friendliness, metal oxides have been widely studied as alternate anode materials for lithium ion batteries (LIBs). In this research work, the processing of SnO2 and SnO2/TiO2 ceramic short fibers as well as flexible and porous metal oxide carbon fibers (FPMOCFs) by centrifugal spinning followed by an optimized coating technique is reported. In addition, the electrochemical performance of the composites was also investigated and is provided.
The Use Of Succinonitrile As An Electrolyte Additive For Composite-Fiber Membranes In Lithium-Ion Batteries, Jahaziel Villarreal, Roberto Orrostieta Chavez, Sujay A. Chopade, Timothy P. Lodge, Mataz Alcoutlabi
The Use Of Succinonitrile As An Electrolyte Additive For Composite-Fiber Membranes In Lithium-Ion Batteries, Jahaziel Villarreal, Roberto Orrostieta Chavez, Sujay A. Chopade, Timothy P. Lodge, Mataz Alcoutlabi
Mechanical Engineering Faculty Publications and Presentations
In the present work, the effect of temperature and additives on the ionic conductivity of mixed organic/ionic liquid electrolytes (MOILEs) was investigated by conducting galvanostatic charge/discharge and ionic conductivity experiments. The mixed electrolyte is based on the ionic liquid (IL) (EMI/TFSI/LiTFSI) and organic solvents EC/DMC (1:1 v/v). The effect of electrolyte type on the electrochemical performance of a LiCoO2 cathode and a SnO2/C composite anode in lithium anode (or cathode) half-cells was also investigated. The results demonstrated that the addition of 5 wt.% succinonitrile (SN) resulted in enhanced ionic conductivity of a 60% EMI-TFSI 40% EC/DMC MOILE …
Synthesis And Design Of Metals Sulfide/Carbon Composite-Fibers Anodes For Lithium Ion Batteries, Jorge Lopez
Synthesis And Design Of Metals Sulfide/Carbon Composite-Fibers Anodes For Lithium Ion Batteries, Jorge Lopez
Theses and Dissertations
In this study, Forcespinning is used to produce Titanium sulfide (TiS2)/carbon composite fibers for use as lithium-ion battery anodes. The high surface area to volume ratio of the composite fibers can have a high impact on the ionic and electronic conductivity of the active materials leading to improved electrochemical performance of the battery. TiS2 nanoparticles were chosen as the active materials to produce Metal-Li-alloys/C composite fibers due to their high theoretical capacity and low volume change during charge/discharge cycles. The use of a 2-D layered structure of TiS2 nanoparticles in the carbon fiber matrix can greatly accommodate more Li-ions between …
Forcespinning®: An Alternative Method To Fabricate Metal Oxide/Carbon Composite Nanofiber Anodes For Li-Ion Batteries, Luis Zuniga
Forcespinning®: An Alternative Method To Fabricate Metal Oxide/Carbon Composite Nanofiber Anodes For Li-Ion Batteries, Luis Zuniga
Theses and Dissertations
Metals and their respective oxides have been highly regarded as next generation anode materials for lithium-ion batteries (LIBs). In this research work the electrochemical performance of Sn, SnO2, and TiO2. With the advantages of nanotechnology and the Forcespinning® method of fabricating micro and nanofibers, binder-free anodes are produced from metal or metal oxide/carbon composite microfibers. Through these microfibers the electrochemical performance of the above mentioned materials are significantly improved due to the increased surface area per volume providing a large number of reaction sites for the anode materials. Further performance enhancement was achieved by also modifying the fiber microstructure to …