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Full-Text Articles in Engineering

3d-Printed Boron Nitride Catalytic Monoliths For Oxidative Dehydrogenation Of Propane, Theodore Agbi, Wei Shang Lo, Khaled Baamran, Taekyung Ryu, Christine Cheung, Fateme Rezaei, Ive Hermans Jan 2023

3d-Printed Boron Nitride Catalytic Monoliths For Oxidative Dehydrogenation Of Propane, Theodore Agbi, Wei Shang Lo, Khaled Baamran, Taekyung Ryu, Christine Cheung, Fateme Rezaei, Ive Hermans

Chemical and Biochemical Engineering Faculty Research & Creative Works

Boron-containing materials are efficient catalysts for the oxidative dehydrogenation of propane to propylene, proceeding via radical intermediates. The radical mechanism is initiated by the solid surface and propagated in the gas phase. It has been hypothesized that the propylene selectivity could be increased by enhancing the gas-phase contributions by favoring the formation of iso- over n-propyl radical intermediates. Indeed, whereas n-propyl radicals can be converted to both propylene and ethylene, iso-propyl radicals yield exclusively propylene. In this contribution, we explore 3D printing to structure the hexagonal boron nitride (hBN) heterogeneous catalyst with high void space. 3D-printed hBN monoliths were found …


3d-Printed Hydrogels Dressings With Bioactive Borate Glass For Continuous Hydration And Treatment Of Second-Degree Burns, Fateme Fayyazbakhsh, Michael J. Khayat, Candy Sadler, Delbert Day, Yue-Wern Huang, Ming-Chuan Leu Jan 2023

3d-Printed Hydrogels Dressings With Bioactive Borate Glass For Continuous Hydration And Treatment Of Second-Degree Burns, Fateme Fayyazbakhsh, Michael J. Khayat, Candy Sadler, Delbert Day, Yue-Wern Huang, Ming-Chuan Leu

Biological Sciences Faculty Research & Creative Works

Recent advances in additive manufacturing have led to the development of innovative solutions for tissue regeneration. Hydrogel materials have gained significant attention for burn wound treatment in clinical practice among various advanced dressings due to their soothing and moisturizing activity. However, prolonged healing, pain, and traumatic removal due to the lack of long-term wound hydration are some of the challenges in the treatment of second-degree burn wounds. In this study, 3D-printed dressings were fabricated using gelatin, alginate, and bioactive borate glass (BBG) using an extrusion-based bioprinter. After ionic crosslinking, the 3D-printed dressings were characterized for mechanical properties, degradation rate, hydration …


Additive Manufacturing Of Sic-Sialon Refractory With Excellent Properties By Direct Ink Writing, Ruoyu Chen, Saisai Li, Xinxin Jin, Haiming Wen Jan 2023

Additive Manufacturing Of Sic-Sialon Refractory With Excellent Properties By Direct Ink Writing, Ruoyu Chen, Saisai Li, Xinxin Jin, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

Additive manufacturing of SiC-Sialon refractory with complex geometries was achieved using direct ink writing processes, followed by pressure less sintering under nitrogen. The effects of particle size of SiC powders, solid content of slurries and additives on the rheology, thixotropy and viscoelasticity of ceramic slurries were investigated. The optimal slurry with a high solid content was composed of 81 wt% SiC (3.5 µm+0.65 µm), Al2O3 and SiO2 powders, 0.2 wt% dispersant, and 2.8 wt% binder. Furthermore, the accuracy of the structure of specimens was improved via adjustment of the printing parameters, including nozzle size, extrusion pressure, and layer height. The …