Engineering Commons^™

Long Period Fiber Grating, Thin Coating Of Graphene And Silver Nanowires, And Corrosion Sensing For Life-Cycle Assessment Of Steel Structures, Chuanrui Guo

Doctoral Dissertations

"This study aims to develop and validate a compact, integrated lab-on-sensor system for simultaneous measurement of strain, temperature and corrosion-induced mass loss in steel structures and concrete reinforcement elements in order to assess their life-cycle performance. The sensing system operates based on the principle of long period fiber gratings (LPFG) that are responsive to both thermal and mechanical deformation, and the change in refractive index of any medium surrounding the optical fiber. To fabricate a LPFG sensor for strain and temperature measurement, a CO₂ laser aided fiber grating system was assembled. To enable mass loss measurement, a low pressure …

Numerical Modeling Study Of A Neutron Depth Profiling (Ndp) System For The Missouri S&T Reactor, Mubarak Mohammed Albarqi

Doctoral Dissertations

”For decades, Neutron Depth Profiling has been used for the non-destructive analysis and quantification of boron in electronic materials and lithium in lithium ion batteries. NDP is one of the few non-destructive analytical techniques capable of measuring the depth profiles of light elements to depths of several microns with nanometer spatial resolution. The technique, however, is applicable only to a handful of light elements with large neutron absorption cross sections. This work discusses the possibility of coupling Particle Induced X-ray Emission spectroscopy with Neutron Depth Profiling to yield additional information about the depth profiles of other elements within a material. …

Building Shared Knowledge For Eor Technologies: Screening Guideline Constructions, Dashboards, And Advanced Data Analysis, Na Zhang

Doctoral Dissertations

"Successful implementation of enhanced oil recovery (EOR) technology requires comprehensive knowledge and experiences based on existing EOR projects. EOR screening guidelines and EOR reservoir analog are served as such knowledge which are considered as the first step for a reservoir engineer to determine the next step techniques to improve the ultimate oil recovery from their assets. The objective of this research work is to provide better assistance for EOR selection by using fundamental statistics methods and machine learning techniques.

In this dissertation, a total of 977 worldwide EOR projects with the most uniformed, high-quality, and comprehensive information were collected from …

Development Of Stage-I Tempered High Strength Cast Steel For Ground Engaging Tools, Viraj Ashok Athavale

Doctoral Dissertations

"Ground Engaging Tools (GET) are the expendable replacement parts used in heavy machinery used with mining or construction equipment. GET’s protect the expensive machine components from the wear and tear found common in high-impact or high-abrasion environments. The goal of this project is to develop advanced next-generation alloy choices that outperforms the existing GET materials. A method of predicting tempered hardness of mixed microstructures was formulated. Using this model, two alloy series viz. Cr-Ni-Mo and Mn-Si-Mo-V were proposed and experimented with the goal of obtaining a high strength and impact resistant cast steel. Cast iterations of Cr-Ni-Mo alloy series were …

Techno-Economic Optimization And Environmental Life Cycle Assessment Of Microgrids Using Genetic Algorithm And Artificial Neural Networks, Prashant Nagapurkar

Doctoral Dissertations

"This dissertation focuses primarily on techno-economic optimization and environmental life cycle assessment (LCA) of sustainable energy generation technologies. This work is divided into five papers. The first paper discusses the techno-economic optimization and environmental life cycle assessment of microgrids located in the USA using genetic algorithm. In this paper, a methodology was developed that assessed the techno-economic and environmental performance of a small scale microgrid located in US cities of Tucson, Lubbock and Dickinson. Providing uninterrupted power the microgrid was composed of seven components -- solar photovoltaics, wind-turbines, lead acid batteries, biodiesel generators, fuel cells, electrolyzers and H₂ tanks. …

Oxide Inclusion Evolution And Factors That Influence Their Size And Morphology, Obinna M. Adaba

Doctoral Dissertations

"The evolution of oxide inclusion size distribution and the shape of the distribution during steelmaking and casting and the process variables that influence the inclusion characteristics at different stages were investigated and documented. A statistical method for transforming the 2D size distribution to their actual 3D distributions and the application of a kinetic model to determine nucleation and growth mechanisms were tested. Finally, laboratory experiments were performed to study the effects of preexisting inclusions, steel active oxygen content, and supersaturation on the size and morphology of Al₂O₃ inclusions.

The inclusion size, composition, and morphology following steel deoxidation …

Deep Understanding Of Degradation In Lithium Ion Batteries Through Experimental And First-Principles Study, Yufang He

Doctoral Dissertations

"The growing interests in Lithium-ion Batteries (LIBs) have significantly accelerated the development of active materials. However, the key challenge is that electrode materials suffer from degradation, which include transition metal dissolution, solid electrolyte interphase (SEI) layer formation, and mechanical fracture. To address these issues, applying an ultrathin coating onto active materials via Atomic Layer Deposition (ALD) is an efficient way. Although numerious works have been done for active material performance improvement via ALD technology, the fundamental enhancement mechanisms of ALD coating on battery performance improvement are not yet known. Therefore, this dissertation consists of four papers, which focused on the …

Three-Dimensional Nanotube Arrays For Solar Energy Harvesting And Production Of Solar Fuels, Wipula P. R. Liyanage

Doctoral Dissertations

"Over the past decade extensive research has been carried out on photovoltaic semiconductors to provide a solution towards a renewable energy future. Fabricating high-efficiency photovoltaic devices largely rely on nanostructuring the photoabsorber layers due to the ability of improving photoabsorption, photocurrent generation and transport in nanometer scale. Vertically aligned, highly uniform nanorods and nanowire arrays for solar energy conversion have been explored as potential candidates for solar energy conversion and solar-fuel generation owing to their enhanced photoconversion efficiencies.

However, controlled fabrication of nanorod and especially nanotube arrays with uniform size and shape and a pre-determined distribution density is still a …

Volumetric Error Compensation For Industrial Robots And Machine Tools, Le Ma

Doctoral Dissertations

“A more efficient and increasingly popular volumetric error compensation method for machine tools is to compute compensation tables in axis space with tool tip volumetric measurements. However, machine tools have high-order geometric errors and some workspace is not reachable by measurement devices, the compensation method suffers a curve-fitting challenge, overfitting measurements in measured space and losing accuracy around and out of the measured space. Paper I presents a novel method that aims to uniformly interpolate and extrapolate the compensation tables throughout the entire workspace. By using a uniform constraint to bound the tool tip error slopes, an optimal model with …

Atomistic Simulations Of Deformation In Metallic Nanolayered Composites, Sixie Huang

Doctoral Dissertations

"The mechanical behavior of Metallic Nanolayered Composites (MNCs) is governed by their underlying microstructure. In this dissertation, the roles of the interlayer spacing (grain size, d) and the intralayer biphase spacing (layer thickness, h) on mechanical response of Cu/Nb MNCs are examined by Molecular Dynamics (MD) simulations. The study of the strength of MNCs show that small changes in both d and h play a profound role in the relative plastic contributions from grain boundary sliding and dislocation glide. The interplay of d and h leads to a very broad transition region from grain boundary sliding dominated flow, where the …

Underwater Acoustic Communications And Adaptive Signal Processing, Mohammadhossein Behgam

Doctoral Dissertations

"This dissertation proposes three new algorithms for underwater acoustic wireless communications. One is a new tail-biting circular MAP decoder for full tail-biting convolution (FTBC) codes for very short data blocks intended for Internet of Underwater Things (IoUT). The proposed algorithm was evaluated by ocean experiments and computer simulations on both Physical (PHY) and Media access control (MAC) layers. The ocean experimental results show that without channel equalization, the full tail-biting convolution (FTBC) codes with short packet lengths not only can perform similarly to zero-tailing convolution (ZTC) codes in terms of bit error rate (BER) in the PHY layer. Computer simulation …

Build Strategy Investigation Of Ti-6al-4v Produced Via A Hybrid Additive Manufacturing Process, Lei Yan

Doctoral Dissertations

“Till now, laser metal deposition (LMD) has been developed with the capability of near-net shape high-performance metal parts fabrication, especially complicated titanium alloys, nickel alloys, and aluminum alloys. However, LMD processed parts usually do not meet end-use requirements without post treatments. In-process part quality inspection and inner features machining are impossible within a single LMD process. Hybrid additive manufacturing (HAM), which integrates additive and subtractive manufacturing in one process, has been proposed to increase the feasibility of complex parts fabrication. This dissertation aims to improve the applications of Ti-6Al-4V parts fabricated via a HAM technique. The first research topic is …

Feasibility And Assessment Of Using Recycled Rubber For Infrastructure Applications, Ahmed A. Gheni

Doctoral Dissertations

“The United States needs to mine billions of tons of raw natural aggregate each year. At the same time, millions of scrap tires are stockpiled every year. Therefore, replacing natural aggregate with recycled crumb rubber aggregate will be beneficial to the construction industry and environment. This research aimed to investigate the feasibility of using recycled rubber in new construction applications. Based on size, recycled rubber was selected to match its natural counterpart. Different ratios of recycled crumb rubber were used as a fine aggregate replacement in concrete masonry units (CMUs) where the rubberized units showed a lower unit weight, higher …

Design, Fabrication, And Characterization Of Functionally Graded Materials, Sreekar Karnati

Doctoral Dissertations

“The aim of this research was to investigate the feasibility of fabricating custom designed, graded materials using Laser Metal Deposition (LMD) that will cater for functionality and unconventional repair. The ultimate goal of the project is to establish the versatility of LMD for fabricating advanced materials and tackling problems that have been conventionally difficult or in cases infeasible. In order to accomplish these goals, this research involved investigations into, the feasibility of using elemental powders as modular feedstocks, the feasibility of fabricating tailored gradients with these custom compositions, and finally leveraging the advantages of grading materials using LMD to successfully …

On Developing A Graphitic White Iron For Metal-To-Metal Wear Systems, Jie Wan

Doctoral Dissertations

"This research addressed heat dissipation issues related to the adhesive wear observed in metal-to-metal wear systems, by developing a graphitic white iron to increase thermal diffusivity of the wear components. One of the premium materials commonly used in current metal-to-metal wear systems is Fe15Mo18Cr and field returned parts were characterized as part of this study. Failure analysis showed that white layers were formed on the wearing surface due to frictional heating and surface deformation. These white layers were extremely brittle and could be fractured easily during use, which in turn led to micro-galling defects that caused parts leakage. Increasing thermal …

Improving Base Metal Electrowinning, Charles Ebenezer Abbey

Doctoral Dissertations

"In zinc electrowinning, Mn oxidizes to form MnO₂ on Pb-Ag anodes, cell walls and pipes. MnO₂ reduces anode corrosion but also leads to short circuits and maintenance issues. MnO₂ is thought to interact with chloride ions and produce oxidized chlorine species. The interactions between Mn and Cl are not well understood. Bench scale experiments were conducted to investigate the effects of the manganese to chloride ratio on anode corrosion rate and electrolyte chemistry using rolled Pb-Ag anodes. Increasing the average Mn/Cl^- ratio from ~7:1 to ~11:1 reduced the anode corrosion rate. Anode scales produced with Mn/Cl …

Detection And Elimination Of Rock Face Vegetation From Terrestrial Lidar Data Using The Virtual Articulating Conical Probe Algorithm, Kenneth John Boyko

Doctoral Dissertations

"A common use of terrestrial lidar is to conduct studies involving change detection of natural or engineered surfaces. Change detection involves many technical steps beyond the initial data acquisition: data structuring, registration, and elimination of data artifacts such as parallax errors, near-field obstructions, and vegetation. Of these, vegetation detection and elimination with terrestrial lidar scanning (TLS) presents a completely different set of issues when compared to vegetation elimination from aerial lidar scanning (ALS). With ALS, the ground footprint of the lidar laser beam is very large, and the data acquisition hardware supports multi-return waveforms. Also, the underlying surface topography is …

Investigating Blast Fume Propagation, Concentration And Clearance In Underground Mines Using Computational Fluid Dynamics (Cfd), Raymond Ninnang Tiile

Doctoral Dissertations

"Blasting activities using standard industry explosives is an essential component of underground hard rock mining operations. Blasting operations result in the release of noxious gases, presenting both safety and productivity threats. Overestimation of post-blast re-entry time results in production losses, while underestimation leads to injuries and fatalities. Research shows that most underground mines simply standardize post-blast re-entry times based on experiences and observations. Few underground mines use theoretical methods for calculating post-blast re-entry time. These theoretical methods, however, are unable to account for the variations in the blasting conditions. Literature review shows that: (i) there is currently no means of …

Efficient Estimation And Mitigation For Radio-Frequency Interference, Qiaolei Huang

Doctoral Dissertations

"With rapid innovations in Internet of Things (IoT) and wireless technology, more and more consumer electronic devices around the world are now connected to the internet. In a small form factor electronic device, there are plenty of potential noise sources such as System On Chip (SoC), high speed traces, flexible cables and power converters, etc. Those noise sources can possibly introduce radio frequency interference (RFI) issues. In this dissertation, a transfer function based calculation method is proposed to estimate radio frequency interference (RFI) problems. The derived equations can clearly decompose the RFI problem into two parts: the noise source and …

Investigating The Performance Of High Viscosity Friction Reducers Used For Proppant Transport During Hydraulic Fracturing, Mohammed Salem Ba Geri

Doctoral Dissertations

"Over the last few recent years, high viscosity friction reducers (HVFRs) have been successfully used in the oil and gas industry across all premier shale plays in North America including Permian, Bakken, and Eagle Ford. However, selecting the most suitable fracture fluid system plays an essential role in proppant transport and minimizing or eliminating formation damage.

This study investigates the influence of the use of produced water on the rheological behavior of HVFRs compared to a traditional linear guar gel. Experimental rheological characterization was studied to investigate the viscoelastic property of HVFRs on proppant transport. In addition, the successful implication …

Smart Control Architecture For Microgrid Application, Vikram Roy Chowdhury

Doctoral Dissertations

"This research proposes non-linear control architectures dedicated towards improving transient response, reliability and computational burden for grid connected inverters applicable for ac micro-grids. Also this work proposes an optimization procedure applied to a small microgrid to reduce the billing cost for power incorporating battery degradation mechanism.

Three works are discussed in this research that discusses methodologies to improve the operation of a three phase grid connected inverters. The first work discusses a globally stable estimation architecture for estimating the plant parameters for a grid connected inverter during its operation. Then a Lyapunov based control architecture is utilized and online parameter …

The Behavior Of Suas Under Explosive Loading Conditions And Implications For Safe Operating Procedures, Ashok Em Sudhakar

Doctoral Dissertations

"Drones are increasingly being used for tasks previously unimagined and the beneficial uses are evolving. The United States Congress has envisioned the possible uses of drones for both combating and conveying explosive threats and other harmful and destructive activities. Congress' intent is reflected in new laws (2018) and policies (2019).

All civilian available Small Unmanned Aerial Systems sUASs (Drones), weighing less than 55 pounds, in the current market are not designed for operations in explosive environments. This first of a kind research focuses on further understanding of sUASs response to explosive loading and the public policy implications. This research measured …

Insights Into Well Performance And Completion Optimization Using A Coupled Fracfocus And Drillinginfo Database, Mustafa A. Al-Alwani

Doctoral Dissertations

“The hydraulic fracturing designs, drilling, and completion trends are undergoing continuous change as the oil and gas industry pushing the boundaries of the traditional designs to increase wells productivity and meet the energy demand. The lateral length in addition to the amount of proppant and water used in well stimulation have witnessed a paradigm shift over the past few years. The motivation for this work began with a desire to better understand well performance as a function of the type of fracturing fluid treatment applied. An early objective was to compare whether East Texas Cotton Valley wells stimulated with water …

Design And Performance Of Fiber-Reinforced Concrete With Adapted Rheology For Construction And Repair Of Bridge Structures, Ahmed Abdelrazik

Doctoral Dissertations

“The objective of this document is to design high-performance fiber-reinforced self-consolidating concrete (FR-SCC) for infrastructure repair and fiber-reinforced super-workable concrete (FR-SWC) for bridge construction. The investigated fibers included propylene synthetic fibers, hooked steel fibers, double and triple hooked steel fibers, hybrid crimped steel fiber and polypropylene multifilament fibers, and micro-macro steel fibers. The fiber volume varied between 0 and 0.75%. An expansive agent (EA) was incorporated to compensate for shrinkage and induce compression in the concrete at early age. Two types of EA (G and K) were employed at 0 to 8%, by mass of binder. The investigated FRSCC and …

Nanoscale Solidification Of Metals By Atomistic Simulations: From Nucleation To Nanostructural Evolution, Avik Mahata

Doctoral Dissertations

"Homogeneous nucleation during solidification in Al (fcc), Fe (bcc) and Mg (hcp) is studied by million-atom molecular dynamics (MD) utilizing the second nearest neighbor modified embedded atom method (2NN-MEAM) potentials. Spontaneous homogenous nucleation from the melt was produced without any influence of pressure, free surface effects and impurities. We also study the effect on the simulation size on homogenous nucleation and the heterogeneity in homogenous nucleation. The heterogeneity in homogenous nucleation originates from the twins, grain boundaries and short range order in the liquid during the initial stages of solidification.

To study the solid-liquid coexistence in binary Al alloys, interatomic …

Intelligent Data-Driven Decision-Making To Mitigate Or Stop Lost Circulation, Husam Hasan Alkinani

Doctoral Dissertations

”Lost circulation is a challenging problem in the oil and gas industry. Each year, millions of dollars are spent to mitigate or stop this problem. The aim of this work is to utilize machine learning and other intelligent solutions to help to make better decision to mitigate or stop lost circulation. A detailed literature review on the applications of decision tree analysis, expected monetary value, and artificial neural networks in the oil and gas industry was provided. Data for more than 3000 wells were gathered from many sources around the world. Detailed economics and probability analyses for lost circulation treatments’ …

Design And Characterization Of A Strong Positron Source At The Mstr Beam Port, Raed Atiah Alsulami

Doctoral Dissertations

“For many years, slow positron sources have found uses in diverse fields including medical physics, nuclear physics, biology, surface science, exotic atom research and space science. The purpose of this work is to design and optimize a reactor-based positron source at the Missouri University of Science and Technology Reactor (MSTR) beam port and quantify its intensity. Monte Carlo simulations using the MCNP6 code were used to model the positron production and moderation processes at the MSTR beam port. The thermal neutron flux at the beam port was determined experimentally and used in the source definition of the radiation transport simulations. …

Mass Spectrometry Analysis Of Contaminants Of Emerging Concern: Nanoparticles, Algal Toxins, And Cyanotoxins In Natural Waters And Their Potential Health Impacts, Ariel R. Donovan

Doctoral Dissertations

“The analysis of contaminants of emerging concern is critical to protecting environmental health. In the presented dissertation, two groups of contaminants of emerging concern were assessed using mass spectrometry methods: nanoparticles and algal and cyanotoxins.

Analysis of metal oxide nanoparticles in environmental matrices has been a challenging issue, as most traditional methods require complicated sample preparation methods or that can alter or destroy the nanoparticles in the system. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) methods were used to detect metal oxide nanoparticles in surface waters and their removal through drinking water treatment simulations while retaining all information regarding …

Development Of Functional Ionic Liquids For Separation And Recovery Of Rare Earth Elements, Mostafa Khodakarami

Doctoral Dissertations

“This research focused on the design and synthesis of task-specific ionic liquids for enhanced extraction and separation of rare earth elements (REEs). Two novel ammonium-based functional ionic liquids (FILs) with oxygen donating groups: trioctyl(2-ethoxy-2-oxoethyl)ammonium dihexyl diglycolamate, [OcGBOEt][DHDGA], and tricaprylmethylammonium dihexyl diglycolamate, [A336][DHDGA] were synthesized and tested for the recovery and separation of selected REEs from aqueous solutions. Functionalities with different denticities were incorporated into both anionic and cationic parts of ionic liquids, which are solely composed of incinerable atoms including C, H, O, and N. The structural, physical, and chemical properties of the synthesized FILs were studied using nuclear magnetic …

Designing Bifunctional Materials For In-Situ Capture And Conversion Of Volatile Organic Compounds, Anirudh Krishnamurthy

Doctoral Dissertations

”Volatile organic compounds (VOCs) are a class of organic liquid compounds with low vapor pressures, which enables them to vaporize at ambient conditions. VOCs are largely toxic, carcinogenic, and mutagenic, and have profound adverse effects on human health and the ecological environment. Many VOCs cause ruinous health effects even at very low concentrations (ppm) and therefore control of these organic compounds is essential for ensuring good air quality. A large portion of VOCs cause catastrophic health effects such as cancer or liver damage even at very low concentrations (ppm), and the control of these compounds is vital in ensuring good …