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Missouri University of Science and Technology

Doctoral Dissertations

Theses/Dissertations

1970

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Full-Text Articles in Engineering

Voids In Neutron Irradiated Aluminum, Nicholas H. Packan Jan 1970

Voids In Neutron Irradiated Aluminum, Nicholas H. Packan

Doctoral Dissertations

"Void formation in high purity aluminum resulting from irradiation to fluences between 1.5 x 10¹⁹ and 1.6 x 10²² neutrons/cm² (E > 0 .1 MeV) at a temperature of 55 ± 5ºC was studied, primarily by means of transmission electron microscopy. In particular the effects of neutron fluence and flux were examined, as well as the possible influences of both preexisting and transmutation-produced impurities. A very low concentration of voids (about 10¹²/cm³) resulted from irradiation to 1.5 x 10¹⁹ neutrons/cm²; they averaged about 150 Å in diameter. Void concentrations and sizes increased with fluence, reaching values of 6 x 10¹⁴ voids/cm³ …


Investigation Of Liquid Carryover In The Girdler-Sulfide Process For Production Of Heavy Water At The Aec Savannah River Plant, Samuel Clark Allen Jan 1970

Investigation Of Liquid Carryover In The Girdler-Sulfide Process For Production Of Heavy Water At The Aec Savannah River Plant, Samuel Clark Allen

Doctoral Dissertations

"An investigation of the causes of liquid carryover in the Girdler-Sulfide process for the production of heavy water was carried out using 12 samples of carbon collected over a one-year time period. Organic impurities from the feedwater were concentrated by adsorption on carbon. Studies of methods for the drying of carbon showed that freeze drying resulted in the minimum reproducible moisture retention without gross loss of the adsorbed organic materials. Rotary vacuum evaporation and air drying of beds of carbon were proven to be less efficient. A study was made of the variables which affect extraction efficiency by the Soxhlet …


Simulation Of A Gas Storage Reservoir With Leakage By A Two-Dimensional Layered Mathematical Model, Steven William Ohnimus Jan 1970

Simulation Of A Gas Storage Reservoir With Leakage By A Two-Dimensional Layered Mathematical Model, Steven William Ohnimus

Doctoral Dissertations

"A generalized mathematical model was developed for two-dimensional compressible fluid flow accounting for the effects of relative permeability capillary pressure, and gravity drainage in addition to the reservoir properties of rock heterogenity and reservoir geometry. The generalized model developed was applied to an aquifer gas storage reservoir in which vertical leakage occurred from the main reservoir to two adjacent overlaying zones. The experimental results of Thomas, et al. were utilized in applying the model to gas storage injection/withdrawal periods yielding reasonable results for the three layers"--Abstract, page ii.


An Sem Surface Study Of Nucleate Pool Boiling Heat Transfer To Saturated Liquid Nitrogen Reduced Pressures From 0.1 To 0.9, David Virgil Porchey Jan 1970

An Sem Surface Study Of Nucleate Pool Boiling Heat Transfer To Saturated Liquid Nitrogen Reduced Pressures From 0.1 To 0.9, David Virgil Porchey

Doctoral Dissertations

"This study constituted an examination of both nucleate boiling and maximum heat flux characteristics of liquid nitrogen boiling from characterized surfaces. Several textures of gold plated copper surfaces were studied in addition to silver and silver oxide surfaces. Data were taken over a wide range of reduced pressures. All surfaces were examined using a Scanning Electron Microscope (SEM). Data and micrograph comparison revealed that both surface chemistry and surface roughness affect the nucleate boiling characteristics of liquid nitrogen. These effects are separated from each other showing that nucleate boiling is a function of both surface chemistry and topography. Surface roughness …


Diffusion And Internal Friction In Sodium-Rubidium Silicate Glasses, Gary L. Mcvay Jan 1970

Diffusion And Internal Friction In Sodium-Rubidium Silicate Glasses, Gary L. Mcvay

Doctoral Dissertations

"The internal friction and self diffusion coefficients of sodium and rubidium ions for (1 - X) Na₂O·X Rb₂O·3 SiO₂ glasses have been measured. The diffusion measurements employed radioactive isotopes and a thin sectioning technique and extended from 350 to 500°C. Internal friction measurements were made from -150 to 500°C and at frequencies of 0.05 to 6000 Hz. The maximum height for the mixed alkali internal friction peak occurs at the composition where the sodium and rubidium diffusion coefficients are equal. It is concluded that the mechanism responsible for the mixed alkali peak is a cooperative rearrangement of sodium-rubidium ions and …


A Computer Simulation Of Mine Air Shaft Thermodynamics, Ambyo Sumopandhi Mangunwidjojo Jan 1970

A Computer Simulation Of Mine Air Shaft Thermodynamics, Ambyo Sumopandhi Mangunwidjojo

Doctoral Dissertations

"Several earlier investigations have been conducted into various aspects of heat problems in underground mines. The application of general gas laws and thermodynamics in the approach of mine ventilation has been helpful in elucidating certain difficulties associated with the subject. By combining several of the techniques perfected by these researchers and applying Carrier's method of calculation for heat flow from exposed rock strata into a workable plan, a method was developed whereby it is possible to accurately and conveniently predict the quality of working environment at any point within a deep mine. The findings of this study may be of …


Effect Of Axial Dispersion On Interphase Mass Transfer In Packed Absorption Columns, Virendra Kumar Mathur Jan 1970

Effect Of Axial Dispersion On Interphase Mass Transfer In Packed Absorption Columns, Virendra Kumar Mathur

Doctoral Dissertations

"A steady state approach was followed in this investigation to determine the effects of liquid and gas flow rates, packing size and packing height on the interphase mass transfer coefficient and gas phase axial mixing Peclet numbers. Experiments were performed on the absorption of carbon dioxide from a mixture of carbon dioxide and nitrogen in a packed column. Absorption was performed using 1/4, 3/8 and l/2 inch Raschig rings, with a packing height of 3 feet and also using 3/8 inch Raschig rings with a packing height of 5 feet. The liquid and gas flow ranges used were 2865 to …


Use Of The Turbulence Kinetic Energy Equation In Prediction Of Nonequilibrium Turbulent Boundary Layers, William Madison Byrne Jr. Jan 1970

Use Of The Turbulence Kinetic Energy Equation In Prediction Of Nonequilibrium Turbulent Boundary Layers, William Madison Byrne Jr.

Doctoral Dissertations

"A differential method is proposed for the prediction of a broad range of turbulent boundary layers of engineering and scientific interest. A digital computer program is presented which is applicable to boundary layers with positive, negative, and zero pressure gradient in the main-stream direction as well as boundary layers with suction, blowing or zero mass addition at the wall. The turbulence kinetic energy equation is solved simultaneously with the longitudinal momentum and continuity equations to provide an independent means for determining the effective viscosity which makes allowance for "history" effects in the flow. It is shown that the prediction method …


An Investigation Of The Stiffness Of Shafts With Integral Disks, Richard King Riley Jan 1970

An Investigation Of The Stiffness Of Shafts With Integral Disks, Richard King Riley

Doctoral Dissertations

"The results of an investigation of the effect of an integral disk on the torsional elastic stiffness of an axisymmetric shaft are presented. Various configurations of disk diameters and widths on a shaft of specified diameter were investigated, using a finite element method of calculation verified by experimentation. The finite element method is presented for the elastic solution of a general axisymmetric body under all possible axisymmetric load conditions. The axisymmetric body is idealized as an assemblage of triangular cross-sectioned torii representing both the normal and shear properties. The elastic stiffness is used to obtain the equilibrium equations of the …


Discrimination Of Signal And Noise Events On Seismic Recordings By Linear Threshold Estimation Theory, David Nuse Peacock Jan 1970

Discrimination Of Signal And Noise Events On Seismic Recordings By Linear Threshold Estimation Theory, David Nuse Peacock

Doctoral Dissertations

"The object of this study is the investigation of a linear threshold element technique for identifying surface multiples on a single seismic trace. Traces of seismic events were generated which contained primaries, surface multiples, and various levels of Gaussian random noise. Since it was necessary to separate the events as much as possible, the traces were subjected to pulse-compression deconvolution processing prior to LTE analysis. Mean frequency, peak frequency, amplitude spectrum variance, periodicity, and polarity were employed as pattern parameters. A set of weights was found that would maximize the moment of inertia of the S line distribution of the …


Penetration In Granite By Shaped Charge Liners Of Various Metals, Hemendra Nath Kalia Jan 1970

Penetration In Granite By Shaped Charge Liners Of Various Metals, Hemendra Nath Kalia

Doctoral Dissertations

"The penetration in Missouri red granite by cylindrical charges with metal liners of aluminum 2011 (T-3), aluminum 7075 (T-6), yellow brass, monel, maraging steel (vascomax 250), and copper was measured. Metals having high ductility and moderate compressive strength penetrated deeper than high strength maraging steel. Aluminum required a greater standoff for optimum penetration than the other metal liners tested. Preliminary metallographic studies of the liner metals and slugs showed that the grains had elongated along the slug axis. The metals containing zinc formed very small or no slugs. The granite grains were highly fractured. The holes were discolored and coated …


Development And Application Of Cartesian Tensor Mathematics For Kinematic Analysis Of Spatial Mechanisms, Robert Myrl Crane Jan 1970

Development And Application Of Cartesian Tensor Mathematics For Kinematic Analysis Of Spatial Mechanisms, Robert Myrl Crane

Doctoral Dissertations

"The complexity of spatial mechanisms in themselves and the absence of an attractive analytical tool for their study has left this field of engineering analysis largely unexplored. In recent years several analytic methods have emerged. One of the most attractive of these is the tensor method. Literature surveys reveal that the tensor method is largely unexploited in the U.S.A., with regard to spatial mechanisms as well as simpler kinematic problems. The purpose of this work is to develop tensor mathematics for application to the kinematic analysis of spatial mechanisms. Methods are developed for position solutions and the determination of velocities …


The Cathodic Reduction Of Maleic Acid, Show Yih Hsieh Jan 1970

The Cathodic Reduction Of Maleic Acid, Show Yih Hsieh

Doctoral Dissertations

"The electrochemical reduction of maleic acid (0.0003 to 0.3 M) was studied on Hg, 0.5% Bi(Hg) amalgam, 5.0% Bi(Hg) amalgam, and Bi cathodes in 1 n H₂SO₄-K₂SO₄-KOH electrolytes (pH 0.3 to 4.0) at 60°C. The maleic acid was converted to succinic acid with high efficiencies (86 to 100%) on all cathodes. Polarization curves with linear Tafel sections were found. All the cathodes had similar kinetic parameters...A reaction mechanism consistent with the experimental observations is proposed..."--Abstract, pages ii-iii.


The Oxidation Kinetics Of Liquid Lead And Lead Alloys, Thomas Edward Weyand Jan 1970

The Oxidation Kinetics Of Liquid Lead And Lead Alloys, Thomas Edward Weyand

Doctoral Dissertations

"Liquid lead and lead-silver alloys were investigated to determine the rates and products of oxidation in pure oxygen at temperatures of 350 to 600°C. The kinetic data were determined using a Cahn electro-balance. Liquid lead was found to follow a cubic rate of oxidation between 350 and 400°C. A parabolic rate was found at temperatures above 400°C. 0.496% silver and 2.258% silver alloys followed a cubic rate of oxidation from 350 to 550°C and tended to approach a parabolic rate of oxidation above this temperature. Silver additions were found to increase the rate of oxidation as compared to the pure …


A Simulation And Diagnosis System Incorporating Various Time Delay Models And Functional Elements, David Michael Rouse Jan 1970

A Simulation And Diagnosis System Incorporating Various Time Delay Models And Functional Elements, David Michael Rouse

Doctoral Dissertations

"The application of digital simulation to all phases of digital network design is considered here as oppossed [sic] to development of simulation for one or two restricted parts of the digital process. For this reason a simulator is presented which can be consistent by varying the level of expression from the simulation of architectural structures to such detailed simulation requirements as race analysis of asynchronous sequential circuits. In order to make system simulation more than just an idea, it must be capable of handling large circuits in reasonable times. It is demonstrated that functional simulation has the potential to increase …


Optimizing Diesel Engine Efficiency Using The Controllability Of A Variable Ratio Hydrostatic Transmission, Gordon Wright Jan 1970

Optimizing Diesel Engine Efficiency Using The Controllability Of A Variable Ratio Hydrostatic Transmission, Gordon Wright

Doctoral Dissertations

"A linear mathematical model of a diesel engine, hydrostatic transmission, and electric dynamometer system was developed. This model was used as an aid in designing a single input controller which regulates engine speed to optimize efficiency while maintaining constant transmission output speed under changing load conditions. Compensation was necessary to stabilize the system because of positive feedback in the engine control system. The compensated system's response was compared to that which was predicted analytically. The analytical model was then extended to design the control system parameters to operate the engine and transmission in a representative vehicle"--Abstract, page ii.


Anodic Dissolution Of Zinc In Potassium Iodide-Potassium Iodate Solutions, Chi-Chiu Yao Jan 1970

Anodic Dissolution Of Zinc In Potassium Iodide-Potassium Iodate Solutions, Chi-Chiu Yao

Doctoral Dissertations

"The anodic dissolution of Zn was studied in KI-KIO₃ solutions at 25ºC. In I⁻ solutions, it was found that the apparent valence of Zn ions going into solution is approximately two. Smaller values are obtained in IO₃⁻ solutions, with the most pronounced changes occurring in the higher concentrations. An empirical equation is derived relating the apparent valence (or anode efficiency) to the current density and concentrations of IO₃⁻ and I⁻. An anodic dissolution mechanism is proposed"--Abstract, page 1.


Temperature Variation In Distribution Of Relaxation Times In Aluminosilicate Glasses, David Wayne Moore Jan 1970

Temperature Variation In Distribution Of Relaxation Times In Aluminosilicate Glasses, David Wayne Moore

Doctoral Dissertations

"The distribution of relaxation times for the alkali peak in a Li₂ O·A1₂O₃ ·2.0SiO₂ glass and for the mixed alkali peak in a 0.5Li₂O·0.5Na₂O·A1₂O₃·2.OSiO₂ glass was studied using the internal friction technique. A lognormal distribution of relaxation times provided the best agreement with the experimental data. The ß parameter of the lognormal distribution function, which is related to the half-height peak width, varied with temperature, indicating that the distribution of relaxation times is dependent upon the activation energy and the activation entropy of the relaxation mechanism. The major contributor to the distribution of relaxation times is a wide distribution in …


A Model For Predicting The Energizing Transients Of Station Capacitor Banks, Dennis Oliver Wiitanen Jan 1970

A Model For Predicting The Energizing Transients Of Station Capacitor Banks, Dennis Oliver Wiitanen

Doctoral Dissertations

"A model for predicting the transients associated with energizing ungrounded wye-connected station capacitor banks was developed. The model has the capability of simulating non-simultaneous operation of the breaker poles, pre-insertion resistors, and the presence of previously energized capacitor banks at the same station. To investigate various system representations, a computer solution of the transient response of an arbitrary network and the computer solution of the generalized Thevenin impedance of a complex network are presented. A simple power system is defined and used to investigate the modeling of various system components, using the computer solution methods. Simplification of the model due …


Mass Transfer From Spherical Gas Bubbles And Liquid Droplets Moving Through Power-Law Fluids In The Laminar Flow Regime, Cheng-Chun Huang Jan 1970

Mass Transfer From Spherical Gas Bubbles And Liquid Droplets Moving Through Power-Law Fluids In The Laminar Flow Regime, Cheng-Chun Huang

Doctoral Dissertations

"Continuous phase mass transfer coefficients are presented for internally circulating spheres of a Newtonian fluid traveling through a power-law type continuous phase in to so-called creeping-flow region. The Nakano and Tien stream functions allow the Sherwood number to be determined as a function of the Peclet number, power-law index, and a viscosity ratio parameter. The Hirose and Moo-Young relation is shown to be a limiting case of this solution. Mass transfer rates increase as the fluids become more pseudoplastic and/or the continuous phase consistency index increases, all other factors held constant"--Abstract, page ii.


The Deformation Mechanisms In Sublimed Magnesium Under Cyclic Loading, Babu Narian Thakur Jan 1970

The Deformation Mechanisms In Sublimed Magnesium Under Cyclic Loading, Babu Narian Thakur

Doctoral Dissertations

"A detailed study of the deformation processes in sublimed magnesium under reverse bending fatigue in air at room temperature has been undertaken utilizing the light, scanning and transmission electron microscopy. The Principal deformation modes are the basal slip and {10Ī2} twinning. The proportion of twinning increases markedly with the increasing stress level and the number of cycles. The evidence for cross slip is seen on the basal slip bands. The extrusions are seen not only along the basal slip lines but also along the {10Ī2} twin boundaries. In the later stages of fatigue, the extrusions chip off producing a notch …


A Study Of The Anodic Oxidation Of 1, 3-Butadiene On Platinum And Gold Electrodes, Arun Kumar Agrawal Jan 1970

A Study Of The Anodic Oxidation Of 1, 3-Butadiene On Platinum And Gold Electrodes, Arun Kumar Agrawal

Doctoral Dissertations

"The anodic oxidation of 1,3-butadiene on Pt and Au electrodes was studied at 70°C in solutions of H₂SO₄, K₂SO₄, K₂CO₃, and KOH with pH's ranging from 0.35 to 12.5. Reaction rates (current) were measured as a function of potential, pH, temperature, and butadiene partial pressure. A transition region (apparently a shift in the rate determining step) in case of Pt was observed in the Tafel plots. The coulombic efficiencies of oxidation to CO₂ were 85 percent in 1 N H₂SO₄ on Pt, 93 percent in 1 N KOH on Pt, and 72 percent in 1 N KOH on Au"--Abstract, Page …


A Three-Dimensional Mathematical Simulator Of Multiphase Systems In A Petroleum Reservoir, Leonard Koederitz Jan 1970

A Three-Dimensional Mathematical Simulator Of Multiphase Systems In A Petroleum Reservoir, Leonard Koederitz

Doctoral Dissertations

"A generalized digital analysis for calculating three phase, three dimensional flow in reservoirs is developed. The computerized mathematical model is applicable to depletion drive, gas injection, water injection, and/or aquifer drive systems with modifications specific to the simulation criterion of that type of drive and includes fluid compressibility effects, gravity drainage and capillary pressure. The simulation allows arbitrary consideration of reservoir heterogeneity, geometry, well locations and rates of production. An innovation to the alternating direction technique for linear differential equations discussed by Brian is developed and employed in order to render the method of solution applicable to non-linear differential equations. …


An Investigation Of Nucleate And Film Boiling Heat Transfer From Copper Spheres, William David Hardin Jan 1970

An Investigation Of Nucleate And Film Boiling Heat Transfer From Copper Spheres, William David Hardin

Doctoral Dissertations

"This study consisted primarily of a laboratory investigation involving nucleate and film boiling heat transfer from copper spheres with saturated liquid nitrogen at atmospheric pressure. An initial study was directed towards obtaining reproducible boiling heat flux versus ΔT curves in the nucleate boiling region from surface conditions created by single and/or multiple glass bead peenings. The variables of bead size, nozzle line operating pressure, and distance a copper surface should be placed from the nozzle outlet were checked. The results indicated that a final peening of the surface with 0.0017-0.0035 inch diameter glass beads, a nozzle line pressure of approximately …


Ionization Of Air Produced By Strong Shocks, Howard Sajon Joyner Jan 1970

Ionization Of Air Produced By Strong Shocks, Howard Sajon Joyner

Doctoral Dissertations

"This dissertation provides theoretical predictions along with experimental results for electron concentrations behind a shock as a function of Mach number over a range from 11 to 20 using a combustion driven shock tube operating in air. These theoretical predictions represent an upper bound for chemical equilibrium. The model for air was 78.0880% nitrogen, 20.949% oxygen, 0.0300% carbon dioxide, 0 .9300% argon, 0.0025%neon, and 0.0005% helium. Also the theory of a double diaphragm shock tube with corresponding pressure ratio vs. Mach number relationships is provided. A computor [sic] program using iterative techniques for a succinct presentation covering the modifications and …


Linear Regression Models Of Sound Velocity In The North Atlantic Ocean Below A Critical Depth, Richard Roland Kunkel Jan 1970

Linear Regression Models Of Sound Velocity In The North Atlantic Ocean Below A Critical Depth, Richard Roland Kunkel

Doctoral Dissertations

"Sound velocity models currently in use by the U. S. Navy require difficult data sampling at great expense. This study is to investigate the feasibility of a sound velocity model dependent only upon position that would be valid for a selected, reasonably large, near homogeneous area of the ocean. The most important position parameters are latitude, longitude, and depth. To accomplish this objective a critical depth of 2500 meters was established for an 8° by 20° rectangle of the Sargasso Sea which lies within the North Atlantic Ocean. The critical depth is defined as the depth at which the characteristics …


Numerical Simulation Of Forward Combustion In A Radial System, Tommie C. Wilson Jan 1970

Numerical Simulation Of Forward Combustion In A Radial System, Tommie C. Wilson

Doctoral Dissertations

"A generalized mathematical model is described for the thermal recovery of oil in a radial system in which there are conductive heat losses to the surrounding formations, three phase fluid flow, conductive-convective heat transfer within the producing formation, combustion, and aqueous-phase changes considered. The mathematical form of the temperature equation requires that numerical solutions be obtained with a digital computer for which the numerical approximations of the partial differential equations are presented and the results discussed. The analysis is applied to field size simulations of a forward combustion project to permit direct field analyses of significant importance for accurate reproductions …


Some Effects Of Oh Groups On Sodium Silicate Glasses, Mokhtar Sayed Maklad Jan 1970

Some Effects Of Oh Groups On Sodium Silicate Glasses, Mokhtar Sayed Maklad

Doctoral Dissertations

"Glasses of various compositions in the Na₂O-SiO₂ system were prepared with different levels of OH concentration. Phase separation kinetics, thermal expansion, radiation induced optical absorption, and internal friction of these glasses were studied. The increase in OH content in these glasses was found to (a) enhance the rate of phase separation; (b) increase thermal expansion above the glass temperature and change the dilatometric softening temperature in a way that depends on microstructure; (c) increase the radiation induced optical absorption bands associated with positive hole centers and decrease those associated with electron trap centers; and, (d) decrease the low temperature alkali …


Electrode Reactions In Zinc Electrolysis, Ernest R. Cole Jan 1970

Electrode Reactions In Zinc Electrolysis, Ernest R. Cole

Doctoral Dissertations

"The effects of temperatures from 0°C to 50°C and current densities from 10 asf to 200 asf on the current efficiency in the electrolysis of pure zinc sulfate solutions (65 gpl Zn⁺⁺ - 200 gpl H₂SO₄) were determined. Pure platinum and platinum coated titanium anodes were used with an aluminum cathode. Platinum anodes were not inert at certain combinations of temperature and current density, and platinum acted as a low overvoltage impurity causing resolution of the cathode deposit. Orientation of the zinc deposits was found to vary with temperature and to have a distinct relationship to current efficiency. Preconditioning of …


Iddap -- Interactive Computer Assistance For Creative Digital Design, Richard Franklin Crall Jan 1970

Iddap -- Interactive Computer Assistance For Creative Digital Design, Richard Franklin Crall

Doctoral Dissertations

"A new computer-aided design program to assist in the initial phases of logical design is described. The program, intended for use via an on-line remote terminal, will allow the designer to study and experiment with design alternatives during the initial creative design phases. An ALGOL-like language is used for specifying the system being designed. In addition to simulating the design, the program allows the user to perform on-line design changes, reorganize data and generate timing diagram information"--Abstract, page ii.