Engineering Commons^™

Ti-6al-4v Β Phase Selective Dissolution: In Vitro Mechanism And Prediction, Michael A Kurtz

All Dissertations

Retrieval studies document Ti-6Al-4V β phase dissolution within total hip replacement systems. A gap persists in our mechanistic understanding and existing standards fail to reproduce this damage. This thesis aims to (1) elucidate the Ti-6Al-4V selective dissolution mechanism as functions of solution chemistry, electrode potential and temperature; (2) investigate the effects of adverse electrochemical conditions on additively manufactured (AM) titanium alloys and (3) apply machine learning to predict the Ti-6Al-4V dissolution state. We hypothesized that (1) cathodic activation and inflammatory species (H₂O₂) would degrade the Ti-6Al-4V oxide, promoting dissolution; (2) AM Ti-6Al-4V selective dissolution would occur …

Predicting Corrosion Damage In The Human Body Using Artificial Intelligence: In Vitro Progress And Future Applications Applications, Michael A. Kurtz, Ruoyu Yang, Mohan S. R. Elapolu, Audrey C. Wessinger, William Nelson, Kazzandra Alaniz, Rahul Rai, Jeremy L. Gilbert

Publications

Artificial intelligence (AI) is used in the clinic to improve patient care. While the successes illustrate the impact AI can have, few studies have led to improved clinical outcomes. A gap in translational studies, beginning at the basic science level, exists. In this review, we focus on how AI models implemented in non-orthopedic fields of corrosion science may apply to the study of orthopedic alloys. We first define and introduce fundamental AI concepts and models, as well as physiologically relevant corrosion damage modes. We then systematically review the corrosion/AI literature. Finally, we identify several AI models that may be Preprint …

The Influence Of Incorporation Of Mn On The Pitting Corrosion Performance Of Crfeconi High Entropy Alloy At Different Temperatures, H. Torbati-Sarraf, Mitra Shabani, Paul D. Jablonski, Garrett J. Pataky, A. Poursaee

Publications

The electrochemical behavior and susceptibility to pitting corrosion of CrFeCoNi and CrMnFeCoNi high entropy alloys were studied in a 0.1 M NaCl solution at temperatures ranging from 25 to 75 °C. Electrochemical measurements revealed that CrMnFeCoNi is more susceptible to oxide film breakdown and localized corrosion compared to CrFeCoNi. Post corrosion microscopic observations showed severe pitting corrosion for CrMnFeCoNi in higher temperatures compared to CrFeCoNi. Based on in-depth XPS profile measurements on the remaining oxide films, this behavior was attributed to the depletion of Cr in the oxide film and detrimental presence of Mn in the matrix solid solution of …

Mechanically- And Electrochemically- Induced Damage At Metal Interfaces Of Joint Replacements And The Biological Consequences, Pooja Panigrahi

All Dissertations

Retrieval analysis has emerged as one of the most direct and informative ways to analyze mechanisms of orthopaedic device failure. With a rising projected demand for revision joint arthroplasty, 268,200 revision total knee replacements (TKR) and 96,700 revision total hip replacements (THR) in 2030, metal interfaces in joint replacements are currently under intense scientific focus as the interactions among mechanical and electrochemical processes continue to challenge the orthopaedic device industry. The objective of these studies was to use implant retrieval and in in vitro analyses to determine the effects of material and mechanical properties on wear and corrosion, and to …

Corrosion Activity In Precast Concrete Elements And Cementitious Closure Pours, Shabi Abbas Udaipurwala

All Theses

The use of prefabricated elements in the construction of highway bridges has been a common practice in the United States since 1950s. Precast concrete adjacent box beam girder bridges are quite popular given that the precast elements not only have structural capacity to span across the supports, but also form the bridge deck. These bridges have generally performed well during the initial years after construction, but recent failures in Pennsylvania and Indiana have aroused a nationwide alarm to investigate the causes of failure and find solutions to repair these bridges or develop design for new replacement bridges. It was found …

Durability Of Reinforced Concrete Incorporating Crushed Waste Brick As Coarse Aggregate, Matthew Adamson

All Theses

Using crushed bricks as aggregates in concrete is of particular interest to preserve natural aggregate sources as well as to reduce waste, as it has been estimated that 10% to 30% of all waste in landfills in the united States comes from construction and demolition wastes. By recycling some of these wastes, the sustainability of a project can be improved. However, it is important concrete incorporating these wastes is as durable or more durable then conventional concrete, or will it have a shorter service life. Durability of concrete is its ability to resist deterioration from its external environment such as …

Study On Corrosion Activity Of Carbon Steel In Concrete Simulated Pore Solution Under Static Tensile And Compressive Stresses, Yujie Zhang

All Theses

Reinforced concrete is a structure material made up of concrete with relatively lower tensile strength containing reinforcements with higher tensile strength and better ductility, which are embedded into fresh concrete to resist tensile stress in certain regions of concrete. Steel reinforced concrete is most widely used around the world in civil engineering structures, water conservancy and highway construction due to its durability strength and reasonable cost.
However, reinforced concrete structures such as bridges and parking lots slabs inevitably experience variable loads and constant degradation from the aggressive environments, such as marine and deicing salts. Therefore, it is imperative to study …

Simulation And Behavior Of Corrosion Deteriorated Reinforced Concrete Members, M. A. Shayanfar, Amir Safiey

Publications

Several reinforced concrete (RC) infrastructures are now crumbling from corrosion of steel bars in concrete. The paper presents the recent advancements in analytical simulation of corrosion aftereffects on behavior of RC members. The model juxtaposes the experimental findings with analytical relationships. The implementation of the model into a nonlinear finite element formulation as well as the experimental and analytical backgrounds are discussed. The abilities of the resulted program have been studied by modeling some experimental specimens showing a reasonable agreement between the analytical and experimental findings.

A New Approach For Nonlinear Finite Element Analysis Of Reinforced Concrete Structures With Corroded Reinforcements, Mohsen A. Shayanfar, Amir Safiey

Publications

A new approach for nonlinear finite element analysis of corroded reinforcements in reinforced concrete (RC) structures is elaborated in the article. An algorithmic procedure for producing the tension-stiffening curve of

RC elements taking into consideration most of effective parameters, e.g.: the rate of steel bar corrosion, bond-slip behavior, concrete cover and amount of reinforcement, is illustrated. This has been established on both experimental and analytical bases. This algorithm is implemented into a nonlinear finite element analysis program. The abilities of the resulted program have been studied by modeling some experimental specimens showing a reasonable agreement between the analytical and experimental …

Corrosion Effects On Tension Stiffening Behavior Of Reinforced Concrete, M. A. Shayanfar, M. Ghalehnovi, Amir Safiey

Publications

The investigation of corrosion effects on the tensile behavior of reinforced concrete (RC) members is very important in region prone to high corrosion conditions. In this article, an experimental study concerning corrosion effects on tensile behavior of RC members is presented. For this purpose, a comprehensive experimental program including 58 cylindrical reinforced concrete specimens under various levels of corrosion is conducted. Some of the specimens (44) are located in large tub containing water and salt (5% salt solution); an electrical supplier has been utilized for the accelerated corrosion program. Afterwards, the tensile behavior of the specimens was studied by means …