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Full-Text Articles in Engineering

Glass Bubbles Grafted With Polymer Brushes For Liquid Hydrocarbon Fire Extinguishment, Randall Snipes Aug 2023

Glass Bubbles Grafted With Polymer Brushes For Liquid Hydrocarbon Fire Extinguishment, Randall Snipes

All Dissertations

The current most efficient solution to fighting liquid pool fires involves the use of firefighting foams containing fluorinated surfactants. The physiochemical properties of these foams are considerably different to all other currently available firefighting foams. Fluorinated surfactants lower the surface tension to a point where the foam solution draining from the foam structure forms a continuous aqueous film on the surface of a volatile hydrocarbon fuel, adding an additional barrier to fuel vapor diffusion to the burning fire. For this reason, these foams qualify as aqueous film forming foams (AFFFs). However, fluorinated compounds are extremely harmful for the environment due …


Tunable Filtration Of Particles During Dip-Coating, Connor Copeland Sep 2022

Tunable Filtration Of Particles During Dip-Coating, Connor Copeland

All Theses

When a solid substrate is withdrawn from a liquid bath a thin coating is deposited whose thickness is given by the Landau-Levich-Derjaguin (LLD) law. We perform an experimental study of dip coating of particle suspensions showing that particles of a given size can become entrained in the meniscus by the competition between viscous and surface tension forces. This is called capillary filtration and can be used as a tunable dynamic filter. For single particle suspensions, filtration can be in terms of either clumps or single particles, with the relevant entrainment points depending upon the rheology of the working fluid, either …