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Articles 1 - 7 of 7
Full-Text Articles in Engineering
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Faculty Publications
The long-term oxidation behavior of HfB2 and of HfB2-20 vol.% SiC was studied. Test samples of each material were oxidized at 1500 °C in air using a box furnace. The exposure times were 0, 0.5, 1, 2, 3, 6, 9, 12, 15, 30, 45 and 90 h. Weight gain, oxide scale composition and oxide scale thickness were characterized for both materials. Crystal structure of the surface scales was analyzed using x-ray diffraction. Oxide scales were further characterized via scanning electron microscopy with energy dispersive spectroscopy analysis. For HfB2 the oxide scale consists predominantly of porous HfO …
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
Faculty Publications
High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …
Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 1000°C In Air And In Silicic Acid-Saturated Steam, Brian G. Kroeger
Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 1000°C In Air And In Silicic Acid-Saturated Steam, Brian G. Kroeger
Theses and Dissertations
Advanced SiC/SiC ceramic matrix composites (CMCs) are being considered for a variety of applications. Of interest is their ability to withstand exposure to high temperature in an aggressive oxidizing environment. The presence of steam creates such an environment. As steam traverses across a SiC/SiC composite and through cracks in the SiC matrix, it becomes saturated with silicic acid, Si(OH)4. It is essential to understand the long-term impacts and durability of SiC/SiC CMCs that have been exposed to such a demanding environment. The present research investigated creep of Hi-Nicalon™ S SiC fibers at 1000°C in air and in silicic …
Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria
Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria
Theses and Dissertations
Ultra high temperature ceramics (UHTCs) are leading candidates for aerospace structural applications in high temperature environments, including the leading edges of hypersonic aircraft and thermal protection systems for atmospheric re-entry vehicles. Before UHTCs can be used in such applications, their structural integrity and environmental durability must be assured, which requires a thorough understanding and characterization of their creep and oxidation behavior at relevant service temperatures.
Fatigue Behavior Of An Advanced Sic/Sic Composite With An Oxidation Inhibited Matrix At 1200°C In Air And In Steam, Jacob Delapasse
Fatigue Behavior Of An Advanced Sic/Sic Composite With An Oxidation Inhibited Matrix At 1200°C In Air And In Steam, Jacob Delapasse
Theses and Dissertations
The fatigue behavior of an advanced Silicon Carbide/Silicon Carbide (SiC/SiC) ceramic matrix composite (CMC) with oxidation inhibited matrix was investigated at 1200˚C in laboratory air and in steam environments. The composite consisted of an oxidation inhibited SiC matrix reinforced with Hi-Nicalon fibers coated with pyrolytic carbon (PyC) with a boron carbide overlay woven into eight-harness-satin (8HS) weave plies. Tensile stress-strain behavior and tensile properties were evaluated at 1200˚C. Tension-tension fatigue tests were conducted in both laboratory air and in steam at 1200˚C at frequencies of 0.1 Hz, 1.0 Hz, and 10 Hz. The tension-tension fatigue tests had a ratio of …
Effects Of Frequency And Environment On Fatigue Behavior Of An Oxide-Oxide Ceramic Matrix Composite At 1200°C, Griffin Hetrick
Effects Of Frequency And Environment On Fatigue Behavior Of An Oxide-Oxide Ceramic Matrix Composite At 1200°C, Griffin Hetrick
Theses and Dissertations
Advances in aeronautical engineering in the 21st century depend upon materials that can perform well in extreme environments such as high temperatures and oxidizing conditions. Nextel™720/Alumina (N720/A) is an oxide/oxide ceramic matrix composite with a porous alumina matrix that has been identified as a candidate material for such applications. This research investigated the effects of frequency on fatigue response of N720/A at 1200°C in both air and steam environment. Prior investigation of this material by Eber [8] in 2005 studied fatigue behavior at 1200°C in air and in steam environments at the frequency of 1.0 Hz. The current research focused …
A Risk Analysis Of Remediation Technologies For A Doe Facility, Helene A. Wilson
A Risk Analysis Of Remediation Technologies For A Doe Facility, Helene A. Wilson
Theses and Dissertations
The Department of Energy is responsible for selecting a remediation technology to clean up the Waste Area Group (WAG) 6 site at the Paducah Gaseous Diffusion Plant (PGDP) in Kentucky. WAG 6 is contaminated with an uncertain amount of trichloroethylene (TCE) and technetium-99 (Tc-99). Selecting a remediation technology involves a certain degree of risk because many of these technologies are new or proven only for a specific type of contaminant or a particular set of site conditions. Differences between contaminant type and site conditions are enough to make the performance of a remediation technology uncertain. This research identifies the technological …