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Full-Text Articles in Engineering

Engineering Advanced Material Properties For Polymeric Materials Through Miscible And Immiscible Additives, Chinmay M. Saraf Jun 2021

Engineering Advanced Material Properties For Polymeric Materials Through Miscible And Immiscible Additives, Chinmay M. Saraf

Doctoral Dissertations

This dissertation focuses on engineering polymeric formulations using strategically selected additives or novel processes to achieve advanced material properties. The first chapter reviews the state-of-the-art impact modification and discusses micro-mechanics associated with soft particle toughening of polymeric materials. We present an analytical solution to elucidate the effect of concentration of rubbery domains on matrix yielding and energy absorption. Soft particle toughening relies on particle size, interparticle spacing, and concentration of rubbery phase. The second chapter demonstrates developing impact modified stereolithography (SLA) resins for the superior energy absorption of the SLA printed thermosets. SLA resins are engineered using additives that remain …


The Effects Of Glass Fiber Fillers On Epoxy Resin Performance, Ashton Robert Reinhold, Manuel Jose Aguirre Ii Jun 2021

The Effects Of Glass Fiber Fillers On Epoxy Resin Performance, Ashton Robert Reinhold, Manuel Jose Aguirre Ii

Materials Engineering

Premature failure of filtration members in biochemical processing is a costly issue for manufacturers. This research aims to determine whether or not the premature failure due to thermal fatigue in medical filtration devices can be mitigated by glass fiber addition. The study was conducted to identify the effects of e-glass fiber filler content in an epoxy matrix on the mechanical and thermal properties of the epoxy system. The epoxy was evaluated over a filler content of 0-50wt% in level increments of 12.5wt% and temperatures ranging from ambient to 160°C in increments of 15°C. Cylindrical and tensile bar specimens were prepared …


Atomic Oxygen Resistant Low Earth Orbit Stable Polymer Matrix Composites Employing Phenylphosphine Oxide Epoxy-Amines, Witold Fuchs May 2021

Atomic Oxygen Resistant Low Earth Orbit Stable Polymer Matrix Composites Employing Phenylphosphine Oxide Epoxy-Amines, Witold Fuchs

Dissertations

Atomic oxygen (AO) attacks polymer matrix composites (PMC’s) on the surfaces of spacecraft in low earth orbit (LEO) and threatens safe spacecraft operation and service life. Incorporating phenylphosphine oxide (PPO) groups into polymer chains offers a self-regenerating method of protection from AO but remains poorly understood. Herein, epoxies containing PPO groups were synthesized with increasing concentrations of phosphorus [P] from 0 to 8 wt % to investigate their AO resistance. Measurements confirmed the exposure of these materials to AO produces a passivation phosphate (POx) layer on the surface of the sample and the efficacy of the resultant layer was directly …