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Articles 1 - 18 of 18
Full-Text Articles in Engineering
Analytical Heat Transfer Modeling Of The Microwave Heating Process: A Focus On Carbon Black, Craig Offutt
Analytical Heat Transfer Modeling Of The Microwave Heating Process: A Focus On Carbon Black, Craig Offutt
Graduate Theses, Dissertations, and Problem Reports
Electronic waste (e-waste) has become a significant environmental issue due to the rapid advancement of technology, increasing demand for electronic devices, and shorter lifespan of electronics. One critical step in processing the e-waste involves ball milling as a means of preparing the recycling e-waste for the recovery of critical materials. Ball milling is a technique that involves the mechanical crushing and grinding of electronic waste to reduce its size and improve its reactivity during recovery. Our focused recovery technique is based on a microwave recovery technique of these critical materials from e-waste. The size and distribution of the e-waste with …
Modeling, Fabrication, And Characterization Of Rf-Based Passive Wireless Sensors Composed Of Refractory Semiconducting Ceramics For High Temperature Applications, Kavin Sivaneri Varadharajan Idhaiam
Modeling, Fabrication, And Characterization Of Rf-Based Passive Wireless Sensors Composed Of Refractory Semiconducting Ceramics For High Temperature Applications, Kavin Sivaneri Varadharajan Idhaiam
Graduate Theses, Dissertations, and Problem Reports
Real-time health monitoring of high temperature systems (>500oC) in harsh environments is necessary to prevent catastrophic events caused by structural failures, varying pressure, and chemical reactions. Conventional solid-state temperature sensors such as resistance temperature detectors (RTDs) and thermocouples are restricted by their operating environments, sensor dimensions and often require external power sources for their operation. The current work presents the research and development of RF-based passive wireless sensing technology targeting high temperatures and harsh environmental conditions. Passive wireless devices are generally classified as near-field and far-field devices based on the interrogation distance. Near-field sensors are placed at …
Exploring Dft+U Parameter Space With A Bayesian Calibration Assisted By Markov Chain Monte Carlo Sampling, Pedram Tavadze, Reese Boucher, Guillermo Avendaño-Franco, Keenan X. Kocan, Sobhit Singh, Viviana Dovale-Farelo, Wilfredo Ibarra-Hernández, Matthew B. Johnson, David S. Mebane, Aldo H. Romero
Exploring Dft+U Parameter Space With A Bayesian Calibration Assisted By Markov Chain Monte Carlo Sampling, Pedram Tavadze, Reese Boucher, Guillermo Avendaño-Franco, Keenan X. Kocan, Sobhit Singh, Viviana Dovale-Farelo, Wilfredo Ibarra-Hernández, Matthew B. Johnson, David S. Mebane, Aldo H. Romero
Faculty & Staff Scholarship
The density-functional theory is widely used to predict the physical properties of materials. However, it usually fails for strongly correlated materials. A popular solution is to use the Hubbard correction to treat strongly correlated electronic states. Unfortunately, the values of the Hubbard U and J parameters are initially unknown, and they can vary from one material to another. In this semi-empirical study, we explore the U and J parameter space of a group of iron-based compounds to simultaneously improve the prediction of physical properties (volume, magnetic moment, and bandgap). We used a Bayesian calibration assisted by Markov chain Monte Carlo …
Development Of Synthetic Coal Char Simulant For Microwave Conversion Studies: A Computationally-Driven Approach, Kevin A. Hager
Development Of Synthetic Coal Char Simulant For Microwave Conversion Studies: A Computationally-Driven Approach, Kevin A. Hager
Graduate Theses, Dissertations, and Problem Reports
Recent experimental demonstration of new reaction windows for coal char/methane reactions that are less energy-intensive, provides innovation for modular reactors. However, the correlation of the exact mechanism for the enhancement of these reaction windows is not certain. This study investigates the simplification of these experimental studies by developing a well-characterized coal char simulant. The approach involves using a computational approach to screen macroscopic composition to replicate the dielectric and compositional response of actual char. This study is focused on PRB coal char. A discrete element method (DEM) technique was used to simulate the packing of coal chars to give the …
Recovery Of Phosphorus From Florida Phosphatic Waste Clay, Amir Eskanlou
Recovery Of Phosphorus From Florida Phosphatic Waste Clay, Amir Eskanlou
Graduate Theses, Dissertations, and Problem Reports
This MS thesis examines the recovery of phosphorus (P) from Florida waste clay (WC). A comprehensive literature review revealed that: (i)-The most important values being lost to WC are P and rare earth elements (REEs). For the recovery of these values from WC, two crucial attempts are the removal of extremely fine-sized clays, followed by the recovery of phosphate content, which can pave the path for the recovery of REEs; (ii)-Any scientific/ technological solution should, at the same time, be economically and environmentally attractive to the industry. As such, moving from mostly chemical separation processes to the primarily physical/ physicochemical …
Subsurface Analytics: Contribution Of Artificial Intelligence And Machine Learning To Reservoir Engineering, Reservoir Modeling, And Reservoir Management, Shahab D. Mohaghegh
Subsurface Analytics: Contribution Of Artificial Intelligence And Machine Learning To Reservoir Engineering, Reservoir Modeling, And Reservoir Management, Shahab D. Mohaghegh
Faculty & Staff Scholarship
Subsurface Analytics is a new technology that changes the way reservoir simulation and modeling is performed. Instead of starting with the construction of mathematical equations to model the physics of the fluid flow through porous media and then modification of the geological models in order to achieve history match, Subsurface Analytics that is a completely AI-based reservoir simulation and modeling technology takes a completely different approach. In AI-based reservoir modeling, field measurements form the foundation of the reservoir model. Using data-driven, pattern recognition technologies; the physics of the fluid flow through porous media is modeled through discovering the best, most …
Effects Of Oxygen Modification On The Structural And Magnetic Properties Of Highly Epitaxial La0.7sr0.3mno3 (Lsmo) Thin Films, Shalini Kumari, Navid Mottaghi, Chih-Yeh Huang, Robbyn Trappen, Ghadendra Bhandari, Saeed Yousefi, Guerau Cabrera, Mohindar S. Seehra, Mikel B. Holcomb
Effects Of Oxygen Modification On The Structural And Magnetic Properties Of Highly Epitaxial La0.7sr0.3mno3 (Lsmo) Thin Films, Shalini Kumari, Navid Mottaghi, Chih-Yeh Huang, Robbyn Trappen, Ghadendra Bhandari, Saeed Yousefi, Guerau Cabrera, Mohindar S. Seehra, Mikel B. Holcomb
Faculty & Staff Scholarship
La0.7Sr0.3MnO3, a strong semi-metallic ferromagnet having robust spin polarization and magnetic transition temperature (TC) well above 300 K, has attracted significant attention as a possible candidate for a wide range of memory, spintronic, and multifunctional devices. Since varying the oxygen partial pressure during growth is likely to change the structural and other physical functionalities of La0.7Sr0.3MnO3 (LSMO) films, here we report detailed investigations on structure, along with magnetic behavior of LSMO films with same thickness (~30 nm) but synthesized at various oxygen partial pressures: 10, 30, 50, 100, 150, 200 and 250 mTorr. The observation of only ( …
Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves
Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves
Graduate Theses, Dissertations, and Problem Reports
Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …
Investigation Of Phonon Polaritons In An Hbn Gan Heterostructure, Catherine G. O'Hearn
Investigation Of Phonon Polaritons In An Hbn Gan Heterostructure, Catherine G. O'Hearn
Graduate Theses, Dissertations, and Problem Reports
There have been many great advances in the generation and manipulation of optics in the visible and near infrared (IR) range over the past decade. This is largely due to plasmonic enhancement, which has led to new technology in biosensing and molecule detection, solid-state lighting, and solar energy harvesting. The field of plasmonics uses quanta of plasma oscillations, plasmons, formed from the interaction between electromagnetic radiation and free electrons to enhance optical near field magnitudes. However, there is still a large region of the electromagnetic spectrum, covering the mid-infrared (MIR) and terahertz (THz) regions, ranging from 3 μm to 1 …
Robust Topological Phase In Proximitized Core–Shell Nanowires Coupled To Multiple Superconductors, Tudor D. Stanescu, Anna Stitek, Andrei Manolescu
Robust Topological Phase In Proximitized Core–Shell Nanowires Coupled To Multiple Superconductors, Tudor D. Stanescu, Anna Stitek, Andrei Manolescu
Faculty & Staff Scholarship
We consider core–shell nanowires with prismatic geometry contacted with two or more superconductors in the presence of a mag- netic field applied parallel to the wire. In this geometry, the lowest energy states are localized on the outer edges of the shell, which strongly inhibits the orbital effects of the longitudinal magnetic field that are detrimental to Majorana physics. Using a tight-binding model of coupled parallel chains, we calculate the topological phase diagram of the hybrid system in the presence of non-vanishing transverse potentials and finite relative phases between the parent superconductors. We show that having finite relative phases strongly …
Insights Into The Magnetic Dead Layer In La0.7sr0.3mno3 Thin Films From Temperature, Magnetic Field And Thickness Dependence Of Their Magnetization, N. Mottaghi, M.S. Seehra, R. Trappen, S. Kumari, Chih-Yeh Huang, S. Yousefi, G.B. Cabrera, A.H. Romero, M.B. Holcomb
Insights Into The Magnetic Dead Layer In La0.7sr0.3mno3 Thin Films From Temperature, Magnetic Field And Thickness Dependence Of Their Magnetization, N. Mottaghi, M.S. Seehra, R. Trappen, S. Kumari, Chih-Yeh Huang, S. Yousefi, G.B. Cabrera, A.H. Romero, M.B. Holcomb
Faculty & Staff Scholarship
Experimental investigations of the magnetic dead layer in 7.6 nm thick film of La0.7Sr0.3MnO3 (LSMO) are reported. The dc magnetization (M) measurements for a sample cooled to T = 5 K in applied field H = 0 reveal the presence of negative remanent magnetization (NRM) in the M vs. H (magnetic field) measurements as well as in the M vs. T measurements in H = 50 Oe and 100 Oe. The M vs. T data in ZFC (zero-field-cooled) and FC (field-cooled) protocols are used to determine the blocking temperature TB in different H. Isothermal hysteresis loops at differ- ent T …
Graphene Nanoplatelets-Sericin Surface-Modified Gum Alloy For Improved Biological Response, Valentina Mitran, Valentina Dinca, Raluca Ion, Vasile D. Cojocaru, Patricia Neacsu, Cerasela Zoica Dinu, Laurentiu Rusen, Simona Brajnicov, Anca Bonciu, Maria Dinescu, Doina Raducanu, Ioan Dan
Graphene Nanoplatelets-Sericin Surface-Modified Gum Alloy For Improved Biological Response, Valentina Mitran, Valentina Dinca, Raluca Ion, Vasile D. Cojocaru, Patricia Neacsu, Cerasela Zoica Dinu, Laurentiu Rusen, Simona Brajnicov, Anca Bonciu, Maria Dinescu, Doina Raducanu, Ioan Dan
Faculty & Staff Scholarship
In this study a “Gum Metal” titanium-based alloy, Ti-31.7Nb-6.21Zr-1.4Fe-0.16O, was synthesized by melting and characterized in order to evaluate its potential for biomedical applications. The results showed that the newly developed alloy presents a very high strength, high plasticity and a low Young's modulus relative to titanium alloys currently used in medicine. For further bone implant applications, the newly synthesized alloy was surface modified with graphene nanoplatelets (GNP), sericin (SS) and graphene nanoplatelets/sericine (GNP–SS) composite films via Matrix Assisted Pulsed Laser Evaporation (MAPLE) technique. The characterization of each specimen was monitored by scanning electron microscopy (SEM), atomic force microscopy (AFM), …
Induced Ferromagnetism In Multilayered Graphene In Proximity With Cofe2o4, Himanshu Verma, Dereje Seifu, Shashi P. Karna, Haiping Hong, Mohindar S. Seehra
Induced Ferromagnetism In Multilayered Graphene In Proximity With Cofe2o4, Himanshu Verma, Dereje Seifu, Shashi P. Karna, Haiping Hong, Mohindar S. Seehra
Faculty & Staff Scholarship
Composites of anisotropic diamagnetic multilayer Graphene (MLG) and ferrimagnetic CoFe2O4 (CFO) nanoparticles (NPs) were synthesized through a one-step sonication process in the presence of a surfactant. The samples were characterized at ambi- ent using x-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), Raman spectroscopy, magnetic force microscopy (MFM) and magnetometry (vibrating sample magnetometer). An induced ferromagnetism was observed in MLG with saturation magnetization MS = 18 emu/g(MLG). This induced ferromagnetism is attributed to ferrimagnetic CFO uniformly distributed on the surface of diamagnetic MLG. SEM images confirm uniform dense distribu- tion of CFO nanoparticles on MLG. MFM images …
Single-Site Catalyst Promoters Accelerate Metal- Catalyzed Nitroarene Hydrogenation, Liang Wang, Erjia Guan, Jian Zhang, Junhao Yang, Yihan Zhu, Yu Han, Ming Yang, Cheng Cen, Gang Fu, Bruce C. Gates, Feng-Shou Xiao
Single-Site Catalyst Promoters Accelerate Metal- Catalyzed Nitroarene Hydrogenation, Liang Wang, Erjia Guan, Jian Zhang, Junhao Yang, Yihan Zhu, Yu Han, Ming Yang, Cheng Cen, Gang Fu, Bruce C. Gates, Feng-Shou Xiao
Faculty & Staff Scholarship
Atomically dispersed supported metal catalysts are drawing wide attention because of the opportunities they offer for new catalytic properties combined with efficient use of the metals. We extend this class of materials to catalysts that incorporate atomically dispersed metal atoms as promoters. The catalysts are used for the challenging nitroarene hydro- genation and found to have both high activity and selectivity. The promoters are single-site Sn on TiO2 supports that incorporate metal nanoparticle catalysts. Represented as M/Sn- TiO2 (M = Au, Ru, Pt, Ni), these catalysts decidedly outperform the unpromoted supported metals, even for hydrogenation of nitroarenes substituted with various …
Cavitons And Spontaneous Hot Flow Anomalies In A Hybrid-Vlasov Global Magnetospheric Simulation, Xochitl Blanco-Cano, Markus Battarbee, Lucile Turc, Andrew P. Dimmock, Emilia K.J. Kilpua, Sanni Hoilijoki, Urs Ganse, David G. Sibeck, Paul A. Cassak, Robert C. Fear, Riku Jarvinen, Liisa Juusola, Yann Pfau-Kempf, Rami Vainio, Minna Palmroth
Cavitons And Spontaneous Hot Flow Anomalies In A Hybrid-Vlasov Global Magnetospheric Simulation, Xochitl Blanco-Cano, Markus Battarbee, Lucile Turc, Andrew P. Dimmock, Emilia K.J. Kilpua, Sanni Hoilijoki, Urs Ganse, David G. Sibeck, Paul A. Cassak, Robert C. Fear, Riku Jarvinen, Liisa Juusola, Yann Pfau-Kempf, Rami Vainio, Minna Palmroth
Faculty & Staff Scholarship
Abstract. In this paper we present the first identification of foreshock cavitons and the formation of spontaneous hot flow anomalies (SHFAs) with the Vlasiator global magne- tospheric hybrid-Vlasov simulation code. In agreement with previous studies we show that cavitons evolve into SHFAs. In the presented run, this occurs very near the bow shock. We report on SHFAs surviving the shock crossing into the down- stream region and show that the interaction of SHFAs with the bow shock can lead to the formation of a magnetosheath cavity, previously identified in observations and simulations. We report on the first identification of long-term …
Electrostatic Potential And Valence Modulation In La0.7sr0.3mno3 Thin Films, Robbyn Trappen, A. C. Garcia- Castro, Vu Thanh Tra, Chih-Yeh Huang, Wilfredo Ibarra-Hernandez, James Fitch, Sobhit Singh, Jingling Zhou, Guerau Cabrera, Ying-Hao Chu, James M. Lebeau, Aldo H. Romero, Mikel B. Holcomb
Electrostatic Potential And Valence Modulation In La0.7sr0.3mno3 Thin Films, Robbyn Trappen, A. C. Garcia- Castro, Vu Thanh Tra, Chih-Yeh Huang, Wilfredo Ibarra-Hernandez, James Fitch, Sobhit Singh, Jingling Zhou, Guerau Cabrera, Ying-Hao Chu, James M. Lebeau, Aldo H. Romero, Mikel B. Holcomb
Faculty & Staff Scholarship
The Mn valence in thin film La0.7Sr0.3MnO3 was studied as a function of film thickness in the range of 1–16 unit cells with a combination of non-destructive bulk and surface sensitive X-ray absorption spectroscopy techniques. Using a layer-by-layer valence model, it was found that while the bulk averaged valence hovers around its expected value of 3.3, a significant deviation occurs within several unit cells of the surface and interface. These results were supported by first principles calculations. The surface valence increases to up to Mn3.7+, whereas the interface valence reduces down to Mn2.5+. The change in valence from the expected …
Learning Local, Quenched Disorder In Plasticity And Other Crackling Noise Phenomena, Stefanos Papanikolaou
Learning Local, Quenched Disorder In Plasticity And Other Crackling Noise Phenomena, Stefanos Papanikolaou
Faculty & Staff Scholarship
When far from equilibrium, many-body systems display behavior that strongly depends on the initial conditions. A characteristic such example is the phenomenon of plasticity of crystalline and amorphous materials that strongly depends on the material history. In plasticity modeling, the history is captured by a quenched, local and disordered flow stress distribution. While it is this disorder that causes avalanches that are commonly observed during nanoscale plastic deformation, the functional form and scaling properties have remained elusive. In this paper, a generic formalism is developed for deriving local disorder distributions from field- response (e.g., stress/strain) timeseries in models of crackling …
Plasmon-Enhanced Optical Sensing By Engineering Metallic Nanostructures, Peng Zheng
Plasmon-Enhanced Optical Sensing By Engineering Metallic Nanostructures, Peng Zheng
Graduate Theses, Dissertations, and Problem Reports
The world’s booming population projected to reach 10 billion by 2050 causes enormous stresses on environmental safety, food supply, and healthcare, which in return threatens human civilizations. One of the most promising solutions lies at innovating point-of-care (POC) sensing technologies to conduct detection of environmental hazards, monitoring of food safety, and early diagnosis of diseases in a timely and accurate manner. The discovery of surface-enhanced spectroscopy in the 1970s has significantly stimulated research on light-matter interaction which gives rise to enhanced optical phenomena such as surface-enhanced Raman scattering (SERS), plasmon-enhanced fluorescence (PEF), and particularly, they have found enormous applications in …